Method for manufacturing perovskite nanocrystal particle light emitting body where organic ligand is substituted, nanocrystal particle light emitting body manufactured thereby, and light emitting device using same

Patent metadata

Field	Value
Publication number	US-10626326-B2
Application number	US-201515524476-A
Country	US
Kind code	B2
Filing date	Nov 6, 2015
Priority date	Nov 6, 2014
Publication date	Apr 21, 2020
Grant date	Apr 21, 2020

Abstract

Provided are a method for manufacturing a perovskite particle light-emitter where an organic ligand is substituted, a light-emitter manufactured thereby, and a light emitting device using the same. A method for manufacturing an hybrid perovskite particle light-emitter where an organic ligand is substituted may comprise the steps of: preparing a solution including an hybrid perovskite particle light-emitter, wherein the hybrid perovskite particle light-emitter comprises an halide perovskite nanocrystal structure and a plurality of first organic ligands surrounding the perovskite nanocrystal structure; and adding, to the solution, a second organic ligand which is shorter than the first organic ligands or includes a phenyl group or a fluorine group, thereby substitutes the first organic ligands with the second organic ligand. Thus, since energy transfer or charge injection into the nanocrystal structure increases through ligand substitution, it is possible to further increase light emitting efficiency and increase durability and stability by means of a hydrophobic ligand.

First claim

The invention claimed is:

1. A method for manufacturing a hybrid perovskite particle light-emitter, in which halide perovskite nanocrystal and a substituted organic ligand are included, the method comprising:
preparing a solution comprising the hybrid perovskite particle light-emitter including an halide perovskite nanocrystal structure and a plurality of first organic ligands surrounding a surface of the halide perovskite nanocrystal; and
substituting at least one of the first organic ligands with a second organic ligand, which has a length less than that of each of the first organic ligands;
wherein the second organic ligand comprises an element having affinity higher than that of the first organic ligands.

2. The method of claim 1 , wherein the hybrid perovskite particle has a size of 1 nm to 900 nm.

3. The method of claim 1 , wherein the hybrid perovskite particle has bandgap energy determined by the crystal structure without depending on a particle size.

4. The method of claim 1 , wherein the preparing of the solution comprising the hybrid perovskite particle light-emitter comprises:
preparing a first solution in which hybrid perovskite is dissolved in a polar solvent and a second solution in which an alkyl halide surfactant is dissolved in a non-polar solvent; and
mixing the first solution with the second solution to form the hybrid perovskite particle light-emitter.

5. The method of claim 4 , wherein the hybrid perovskite comprises a structure of ABX 3 , A 2 BX 4 , ABX 4 , A n BX 2+n , A 2 BB′X 6 , or A n−1 Pb n X 3n+1 (where n is an integer between 2 to 6), and the A is an organic ammonium material, the B or B′ is a metal material, and the X is a halogen element.

6. The method of claim 5 , wherein the A is (CH 3 NH 3 ) n , ((C x H 2x+1 ) n NH 2 )(CH 2 NH 3 ) n , (R(NH 3 ) 2 , (C n H 2n+1 NH 3 ) 2 , CF 3 NH 3 , (CF 3 NH 3 ) n , ((C x F 2x+1 ) n NH 2 )(CF 2 NH 3 ) n , ((C x F 2x−1 ) n NH 3 ), metal, (CH(NH 2 ) 2 ), C x H 2x−1 (C(NH 2 ) 2 ), (C n F 2n+1 NH 3 ) or derivative thereof (where n is an integer equal to or greater than 1, and x is an integer equal to or greater than 1),
the B or B′ is a divalent transition metal, a rare earth metal, an alkali earth metal, Pb, Sn, Ge, Ga, In, Al, Sb, Bi, Po, or a combination thereof, and
the X is Cl, Br, I, or a combination thereof.

7. A hybrid perovskite particle light-emitter, in which an organic ligand is substituted, manufactured by the manufacturing method of claim 1 .

8. The hybrid perovskite particle light-emitter of claim 7 , wherein the hybrid perovskite particle light-emitter, in which an organic or inorganic ligand is substituted, is dispersible in an organic solvent or materials.

9. The hybrid perovskite particle light-emitter of claim 8 , wherein the organic solvent comprises a polar solvent and a non-polar solvent,
the polar solvent comprises dimethylformamide, gamma butyrolactone, N-methylpyrrolidone, dimethylsulfoxide or isopropyl alcohol, and
the non-polar solvent comprises dichloroethylene, trichlorethylene, chloroform, chlorobenzene, dichlorobenzene, styrene, xylene, toluene, or cyclohexene.

10. A light emitting device comprising:
a first electrode;
a second electrode; and
a light emitting layer disposed between the first electrode and the second electrode and comprising the hybrid perovskite particle light-emitter, in which the organic ligand is substituted, of claim 7 .

11. A solar cell comprising:
a first electrode;
a second electrode; and
a photoactive layer disposed between the first electrode and the second electrode and comprising the hybrid perovskite particle light-emitter, in which the organic ligand is substituted, of claim 7 .

12. The method of claim 1 , wherein each of the first organic ligands and the second organic ligand comprises alkyl halide, organic ammonium, or surfactant.

13. The method of claim 1 , wherein halogen atom of second organic ligand has affinity higher than that of a halogen atom of the first organic ligands with respect to a center metal of the perovskite nanocrystal structure.

Assignees

• Postech Acad Ind Found

Inventors

• Lee Tae-Woo
• Im Sanghyuk
• Kim Young-Hoon
• Cho Himchan

Classifications

• C09K11/06 Primary

  containing organic luminescent materials · CPC title

• C09K2211/188

  of other metals not provided for in one of the previous groups · CPC title

• H01G9/2004

  characterised by the electrolyte, e.g. comprising an organic electrolyte · CPC title

• C09K11/025

  non-luminescent particle coatings or suspension media · CPC title

• H01L51/5032

  Electricity · mapped topic