Peroxide masterbatch

Patent metadata

Field	Value
Publication number	US-10626263-B2
Application number	US-201716463034-A
Country	US
Kind code	B2
Filing date	Nov 21, 2017
Priority date	Nov 25, 2016
Publication date	Apr 21, 2020
Grant date	Apr 21, 2020

Abstract

Peroxide masterbatch comprising: —15-55 wt % of one or more organic peroxides, —15-45 wt % of one or more copolymers of at least two different monomers, the first monomer being ethylene or propylene, the second monomer being a vinyl monomer comprising at least four carbon atoms and optionally heteroatoms, —6-70 wt % of at least two filler types—filler type 1 and filler type 2—each having a different BET surface area: (i) filler type 1 being present in the masterbatch in a concentration of 3-30 wt % and having a BET surface area of more than 100 m2/g; (ii) filler type 2 being present in the masterbatch in a concentration of 3-40 wt % and having a BET surface area of 100 m2/g or less; wherein the masterbatch has the form of extrudates.

First claim

The invention claimed is:

1. Peroxide masterbatch comprising:
15-55 wt % of one or more organic peroxides,
15-45 wt % of one or more copolymers of at least two different monomers, the first monomer being ethylene or propylene, the second monomer being a vinyl monomer comprising at least four carbon atoms and optionally heteroatoms,
6-70 wt % of at least two filler types—filler type 1 and filler type 2—each having a different BET surface area:
(i) filler type 1 being present in the masterbatch in a concentration of 3-30 wt % and having a BET surface area of more than 100 m 2 /g;
(ii) filler type 2 being present in the masterbatch in a concentration of 3-40 wt % and having a BET surface area of 100 m 2 /g or less;

wherein the masterbatch has the form of extrudates.

2. Peroxide masterbatch according to claim 1 comprising 30-52 wt % of one or more peroxides.

3. Peroxide masterbatch according to claim 1 comprising an organic peroxide is-selected from the group consisting of dicumyl peroxide, di(tert-butylperoxyisopropyl)benzene, 1,1-di(tert-butylperoxy)-3,3,5-tri-methylcyclohexane, butyl-4,4-di(tert-butylperoxy)valerate, 2,5-dimethyl-2,5-di(tert-butylperoxy)hexane, and tert-butyl peroxy-3,5,5-trimethylhexanoate.

4. Peroxide masterbatch according to claim 1 comprising a copolymer i& selected from ethylene-vinyl acetate copolymers, copolymers of (i) ethylene or propylene and (ii) 1-butene, 1-hexene, and/or 1-octene, copolymers of ethylene and acrylates, styrene ethylene butylene hydrogenated copolymers, and styrene ethylene propylene hydrogenated copolymers.

5. Peroxide masterbatch according to claim 4 wherein the copolymer comprises a copolymer of (i) ethylene or propylene and (ii) 1-butene and/or 1-octene.

6. Peroxide masterbatch according to claim 4 wherein the copolymer is an ethylene-vinyl acetate copolymer.

7. Peroxide masterbatch according to claim 1 comprising 3-15 wt % of filler type 1 and 10-30 wt % of filler type 2.

8. Peroxide masterbatch according to claim 1 wherein filler type 1 has a BET surface area of more than 150 m 2 /g.

9. Peroxide masterbatch according to claim 1 wherein filler type 1 is selected from carbon black, silica, and combinations thereof.

10. Peroxide masterbatch according to claim 1 wherein filler type 2 has a BET surface area below 10 m 2 /g.

11. Peroxide masterbatch according to claim 1 wherein filler type 2 is selected from calcium carbonate, barium sulphate, clay, and combinations thereof.

12. Process for the preparation of a peroxide masterbatch of claim 1 wherein the one or more organic peroxides, granules or pellets of the one or more copolymers, and the at least two filler types are added to an extruder and extruded at a temperature in the range 50-95° C.

13. Process according to claim 11 wherein the extrusion is conducted at a temperature in the range 70-85° C.

14. Process for crosslinking of an elastomer comprising the step of dispersing the peroxide masterbatch according to claim 1 in the elastomer to be crosslinked.

15. The process according to claim 4 , wherein the elastomer comprises EPM.

16. The process according to claim 4 , wherein the elastomer comprises EPDM.

Assignees

• Nouryon Chemicals Int Bv

Inventors

• Beek Waldo Joseph Elisabeth

Classifications

• C08L2310/00

  Masterbatches · CPC title

• C08K2201/014

  Additives containing two or more different additives of the same subgroup in C08K · CPC title

• C08K3/346

  Clay · CPC title

• C08K3/01

  characterized by their specific function · CPC title

• C08K2003/265

  Calcium, strontium or barium carbonate · CPC title