Composite with improved mechanical properties and molded article including the same

Patent metadata

Field	Value
Publication number	US-10626252-B2
Application number	US-201816141712-A
Country	US
Kind code	B2
Filing date	Sep 25, 2018
Priority date	Aug 29, 2014
Publication date	Apr 21, 2020
Grant date	Apr 21, 2020

Abstract

The present invention provides a composite obtained by processing a resin composition including a thermoplastic resin, multi-walled carbon nanotubes. The multi-walled carbon nanotubes have an average diameter of 10 nm-3 nm and an Id/Ig of 0.6 or more. The walls of the multi-walled carbon nanotubes consist of 10 or more layers of graphene. The rate of residual length of the carbon nanotubes present in the composite is 40% or more. The composite has improved mechanical properties without deterioration of conductivity. Due to these advantages, the composite can be used to manufacture various molded articles.

First claim

The invention claimed is:

1. A composite obtained by processing a resin composition comprising a thermoplastic resin, multi-walled carbon nanotubes, wherein the average diameter of the multi-walled carbon nanotubes is 10 nm-30 nm, the walls of the multi-walled carbon nanotubes consist of 10 or more layers of graphene, the I d /I g of the multi-walled carbon nanotubes is 0.6 or more,
wherein the rate of residual length of the carbon nanotubes present in the composite is 40% to 99%, the rate of residual length being defined by Equation 1:
Rate of residual length (%)=(Content of≥500 nm long carbon nanotubes in the composite)/(Content of all carbon nanotubes in the composite)×100.

2. The composite according to claim 1 , further comprising a reinforcing material.

3. The composite according to claim 2 , wherein the reinforcing material has a fibrous shape.

4. The composite according to claim 2 , wherein the reinforcing material is selected from carbon fibers, glass fibers, milled glass fibers, aramid fibers, alumina fibers, silicon carbide fibers, ceramic fibers, asbestos fibers, gypsum fibers, metal fibers, and mixtures thereof.

5. The composite according to claim 2 , wherein the reinforcing material is present in an amount of 0.1 to 50 parts by weight, based on 100 parts by weight of the thermoplastic resin.

6. The composite according to claim 1 , wherein the walls of the multi-walled carbon nanotubes consist of 10 to 50 graphene layers.

7. The composite according to claim 1 , wherein the composite has a tensile strength of 83 MPa or more.

8. The composite according to claim 1 , wherein the composite has a tensile modulus of 3.3 GPa or more.

9. The composite according to claim 1 , wherein the composite has a surface resistivity of 1.0×10 9 Ω/sq. or less.

10. The composite according to claim 1 , wherein the multi-walled carbon nanotubes are of a bundle type or non-bundle type.

11. The composite according to claim 1 , wherein the multi-walled carbon nanotubes are present in an amount of 0.1 to 10 parts by weight, based on 100 parts by weight of the thermoplastic resin.

12. The composite according to claim 1 , wherein the multi-walled carbon nanotubes present in the composite has an average length of 0.5 μm to 50 μm.

13. The composite according to claim 1 , further comprising a carbonaceous conductive additive.

14. The composite according to claim 13 , wherein the carbonaceous conductive additive is selected from carbon black, graphene, fullerenes, and carbon nanofibers.

15. The composite according to claim 13 , wherein the carbonaceous conductive additive is present in an amount of 0.1 to 30 parts by weight, based on 100 parts by weight of the thermoplastic resin.

16. The composite according to claim 1 , wherein the processing is extrusion.

17. A molded article comprising the composite according to claim 1 .

18. The molded article according to claim 17 , wherein the processing is extrusion, injection molding or a combination thereof.

19. The molded article according to claim 17 , wherein the molded article is an antistatic article, an electrical/electronic product housing or an electrical/electronic part.

Assignees

• Lg Chemical Ltd

Inventors

• Choi Yeonsik
• Lee Sumin
• CHOI GiDae
• Yun Changhun

Classifications

• C08K7/24

  inorganic · CPC title

• C08K3/042

  Graphene or derivatives, e.g. graphene oxides · CPC title

• C08K2201/003

  Additives being defined by their diameter · CPC title

• C08J5/04

  Reinforcing macromolecular compounds with loose or coherent fibrous material · CPC title

• C08K7/00

  Use of ingredients characterised by shape · CPC title