Hybrid photochemical/plasma reactor devices

Patent metadata

Field	Value
Publication number	US-10625235-B2
Application number	US-201715728986-A
Country	US
Kind code	B2
Filing date	Oct 10, 2017
Priority date	Oct 10, 2016
Publication date	Apr 21, 2020
Grant date	Apr 21, 2020

Abstract

A method for generating a hybrid reaction flows feedstock gas that is also a plasma medium through microchannels. Plasma is generated with the plasma medium via excitation with a time-varying voltage. UV or VUV emissions are generated at a wavelength selected to break a chemical bond in the feedstock gas. The UV or VUV emissions are directed into the microchannels to interact with the plasma medium and generate a reaction product from the plasma medium. A hybrid reactor device includes a microchannel plasma array having inlets and outlets for respectively flowing gas feedstock into and reaction product out of the microchannel plasma array. A UV or VUV emission lamp has its emissions directed into microchannels of the microchannel plasma array. Electrodes ignite plasma in the microchannels and stimulating the UV or VUV emission lamp to generate UV or VUV emissions. One common or plural phased time-varying voltage sources drive the plasma array and the UV or VUV emission lamp.

First claim

The invention claimed is:

1. A method for generating a hybrid reaction, the method comprising steps of:
flowing feedstock gas that is also a plasma medium through microchannels;
generating microplasma with the plasma medium via excitation with a time-varying voltage;
generating UV or VUV emissions at a wavelength selected to break a chemical bond in the feedstock gas;
directing the UV or VUV emissions into the microchannels with a timing to coincide with presence of radicals produced in the microplasma to interact the radicals with the UV or VUV emissions and generate a reaction product of the radicals and the UV or VUV emissions.

2. The method of claim 1 , wherein the plasma medium includes a sensitizer having a chemical bond that can be broken by the UV or VUV emissions.

3. The method of claim 1 , wherein the wavelength is selected to break the chemical bond of the radicals generated in the microplasma.

4. The method of claim 1 , wherein said generating generates the UV of VUV emissions from a microcavity lamp comprising an array of microcavities.

5. The method of claim 4 , wherein the microchannels comprise an array of microchannels.

6. The method of claim 5 , wherein a width of the microchannels width is in the range of about 25 μm to about 800 μm.

7. The method of claim 6 , wherein a depth of the microchannels is about 30 μm to about 300 μm.

8. The method of claim 1 , wherein lamp emits photons at a wavelength of about 100 nm to about 307 nm.

9. The method of claim 1 , wherein the lamp emits photons at a wavelength of about 172 nm.

10. A hybrid reactor device comprising:
a microchannel plasma array including inlets and outlets for respectively flowing gas feedstock into and reaction product out of the microchannel plasma array;
a UV or VUV emission lamp having emissions directed into microchannels of the microchannel plasma array; and
electrodes for igniting microplasma in the microchannels and stimulating the UV or VUV emission lamp to generate UV or VUV emissions;
and a common or multiple phased time-varying voltage sources for driving the electrodes and the UV or VUV emission lamp in phase with a timing to match the generation of radicals produced by the microplasma with the arrival of the UV or VUV emissions.

11. The device of claim 10 , wherein the UV or VUV emission lamp comprises an array of microcavities arranged with respect to one or more arrays of electrodes to generate the UV or VUV emission.

12. The device of claim 10 , wherein said electrodes are powered by a common time-varying voltage source.

13. The device of claim 10 , wherein said microchannel plasma array and UV or VUV emission lamp are integrated together in a sandwich structure.

14. The device of claim 10 , wherein said electrodes comprise screen electrodes.

15. The device of claim 14 , wherein said screen electrodes have a UV or VUV transmission efficiency of between about 85-95%.

Assignees

• Univ Illinois

Inventors

• Eden James Gary
• Park Sung-Jin
• Shin Charles
• Mironov Andrey

Classifications

• C01B13/115

  characterised by the electrical circuits producing the electrical discharge · CPC title

• B01J2219/0807

  involving electrodes · CPC title

• B01J2219/0841

  Metal · CPC title

• B01J2219/0894

  Processes carried out in the presence of a plasma · CPC title

• B01J19/0093 Primary

  Microreactors, e.g. miniaturised or microfabricated reactors (laboratory containers with capillary fluid transport in microfabricated channels or chambers B01L3/5027) · CPC title