Production system for composite porous solid articles

Patent metadata

Field	Value
Publication number	US-10625213-B2
Application number	US-201615567173-A
Country	US
Kind code	B2
Filing date	Apr 12, 2016
Priority date	Apr 17, 2015
Publication date	Apr 21, 2020
Grant date	Apr 21, 2020

Abstract

A production system for manufacturing composite porous solid articles is provided wherein the color of such articles is monitored to confirm that the articles, which are produced by heating and compressing mixtures of poly(vinylidene fluoride) binder powder (such as Kyblock® resin from Arkema) and activated carbon powder, are fully cured. Adjustments to the processing conditions are made when a region of the article appears blue (indicative of incomplete curing).

First claim

What is claimed is:

1. A production system for making composite porous solid articles, wherein the production system comprises the steps of:
a) heating and optionally compressing a first portion of a mixture of a poly(vinylidene fluoride) binder powder and activated carbon powder under a first set of processing conditions to form a first composite porous solid article;
b) inspecting the first composite porous solid article to determine if the first composite porous solid article is completely black in color; and
c-1) if the first composite porous solid article is completely black in color, heating and compressing a second portion of the mixture under the first set of processing conditions to form a second composite porous solid article; or
c-2) if the first composite porous solid article is not completely black in color, selecting a second set of processing conditions different from the first set of processing conditions and heating and forming a second portion of the mixture under the second set of processing conditions to form a second composite porous solid article.

2. The production system of claim 1 , wherein the heating and compressing of the first portion and the second portion of the mixture is performed by compression molding the mixture.

3. The production system of claim 1 , wherein the heating of the formulation is performed without added compression.

4. The production system of claim 1 , wherein the heating and compressing of the first portion and the second portion of the mixture is performed by extruding the mixture.

5. The production system of claim 1 , wherein step c-2) is performed and the second set of processing conditions differs from the first set of processing conditions in that heating and compressing the second portion of the mixture is performed at a higher temperature.

6. The production system of claim 1 , wherein the first composite porous solid article and the second composite porous solid article are each in the form of a solid or hollow cylinder.

7. The production system of claim 1 , wherein the first composite porous solid article and the second composite porous solid article are each in the form of a sheet.

8. The production system of claim 1 , wherein the poly(vinylidene fluoride) binder powder has an average particle size of less than 20 micrometers.

9. The production system of claim 1 , wherein the poly(vinylidene fluoride) binder comprises between about 3 and about 30 percent by weight of the first composite porous solid article and the second composite porous solid article.

10. The production system of claim 1 , wherein the mixture of PVDF powder and activated carbon further comprises active functional particles.

11. The production system of claim 1 , wherein the activated carbon powder has an average particle size of 20 micrometers and greater.

12. The production system of claim 1 , wherein step c-2) is performed and wherein the production system comprises additional steps of inspecting the second composite porous solid article to determine if the second composite porous solid article is completely black in color and, if the second composite porous solid article is completely black in color, heating and compressing a third portion of the mixture under the second set of processing conditions to form a third composite porous solid article, or, if the second composite porous solid article is not completely black in color, selecting a third set of processing conditions different from the first set and second set of processing conditions and heating and forming a third portion of the mixture under the third set of processing conditions to form a third composite porous solid article.

13. The production system of claim 1 , wherein the first composite porous article exhibits at least one region which is blue in color.

14. The production system of claim 1 , wherein the mixture of the poly(vinylidene fluoride) binder powder and activated carbon powder is blue in color prior to being exposed to heat and compression.

Assignees

• Arkema Inc

Inventors

• Stabler Sean M
• Koslow Evan E

Classifications

• B01D69/148

  Organic/inorganic mixed matrix membranes · CPC title

• B01D2323/10

  Specific pressure applied · CPC title

• B01D69/08

  Hollow fibre membranes (manufacture of hollow fibres D01D5/24, D01F1/08) · CPC title

• B01J20/3078

  Thermal treatment, e.g. calcining or pyrolizing · CPC title

• B01J20/14

  Diatomaceous earth · CPC title