Anaerobic aluminum-water electrochemical cell

Patent metadata

Field	Value
Publication number	US-10622690-B2
Application number	US-201816057166-A
Country	US
Kind code	B2
Filing date	Aug 7, 2018
Priority date	Dec 4, 2012
Publication date	Apr 14, 2020
Grant date	Apr 14, 2020

Abstract

Provided is a method for generating an electrical current. The method includes: introducing water between the anode and at least one cathode of an electrochemical cell, to form an electrolyte; anaerobically oxidizing aluminum or an aluminum alloy; and electrochemically reducing water at the at least one cathode. When the cell is in operation, the hydroxyaluminate (Al(OH) 4 − ) in the electrolyte reaches a concentration maximum and thereafter a concentration minimum. The concentration maximum is above 125% of the saturation concentration and below 2000% of the saturation concentration. The concentration minimum is below 125% of the saturation concentration and above 50% of the saturation concentration.

First claim

The invention claimed is:

1. A method for generating an electrical current using an electrochemical cell, the method comprising:
providing the electrochemical cell, the electrochemical cell comprising:
a plurality of electrode stacks, each electrode stack comprising a solid aluminum or aluminum alloy anode, in the form of a plate, the plate having a first side and a second side opposite to the first side, and at least one cathode disposed directly next to the first side of the plate and at least one cathode disposed directly next to the second side of the plate, wherein the cathode on the first side and the cathode on the second side are configured to be electrically coupled to the anode;
one or more physical separators, between each one of the electrode stacks, positioned between the cathode on the first side of one electrode stack and the cathode on the second side of an adjacent electrode stack;
a housing configured to hold the electrode stacks, an electrolyte, and the physical separators; and
a water injection port, in the housing, configured to introduce water into the housing, so that the water flows through the physical separators;

introducing water between the anode and at least one cathode on the first side and between the anode and the at least one cathode on the second side in each electrode stack, a hydroxide base and the water forming the electrolyte;
anaerobically oxidizing the aluminum or aluminum alloy anode;
electrochemically reducing the water at the at least one cathode;
operating the electrochemical cell such that hydroxyaluminate (Al(OH) 4 − ) in the electrolyte reaches a concentration maximum and thereafter a concentration minimum, wherein:
the concentration maximum is above 125% of a saturation concentration and below 2000% of the saturation concentration, and
the concentration minimum is below 125% of the saturation concentration and above 50% of the saturation concentration.

2. The method according to claim 1 , wherein the concentration maximum is above 150% of the saturation concentration and below 1500% of the saturation concentration.

3. The method according to claim 1 , where the concentration maximum is above 175% of the saturation concentration and below 1000% of the saturation concentration.

4. The method according to claim 1 , where the concentration maximum is above 200% of the saturation concentration and below 500% of the saturation concentration.

5. The method according to claim 1 , wherein the concentration minimum is below 125% of the saturation concentration and above 75% of the saturation concentration.

6. The method according to claim 1 , wherein the concentration minimum is below 100% of the saturation concentration and above 50% of the saturation concentration.

7. The method according to claim 1 , wherein substantially no aluminum hydroxide precipitate is formed by homogeneous precipitation.

8. The method according to claim 1 , wherein the electrolyte includes a hydroxide base at a concentration of between about 0.1 M to 3 M.

9. The method according to claim 1 , wherein the electrolyte includes a hydroxide base at a concentration of between about 0.25 M to about 2.5 M.

10. The method according to claim 1 , wherein the water includes sodium chloride.

11. The method according to claim 1 , wherein the aluminum has a purity of at least 99.95 wt %.

12. The method according to claim 1 , wherein the aluminum in the alloy has a purity of at least 99.99 wt %.

13. The method according to claim 1 , wherein the aluminum or aluminum alloy is substantially free of tin and boron.

14. The method according to claim 1 , wherein the cathode is in the form of a solid plate.

15. The method according to claim 1 , wherein the cathode is in the form of a sponge.

16. The method according to claim 1 , wherein the cathode includes a nickel-molybdenum alloy.

17. The method according to claim 1 , the cathode having a surface characterized by an electrochemical roughness factor of at least 5.

18. The method according to claim 1 , the cathode having a surface characterized by an electrochemical roughness factor of at least 10.

19. The method according to claim 1 , substantially free of aerobic oxidation of the aluminum or aluminum alloy.

20. The method of according to claim 1 , further comprising:
providing a waste separation system, in fluid communication with the housing, configured to receives the electrolyte and aluminum hydroxide waste from the electrochemical cell and to separates the aluminum hydroxide waste from the electrolyte, and
providing a fuel injector, in fluid communication with the waste separation system and the water injection port, configured to receives the electrolyte from the waste separation system and to provides the electrolyte to the water injection port.

21. The method according to claim 20 , wherein the fuel injector is further configured to receives water from a water supply.

Assignees

• Massachusetts Inst Technology

Inventors

• Mckay Ian Salmon
• Macdonald Ruaridh R
• Milnes Thomas B

Classifications

• H01M2300/0014

  Alkaline electrolytes · CPC title

• H01M12/02

  Details (of electrodes H01M4/00; of non-active parts H01M50/00) · CPC title

• H01M6/32

  activated through external addition of electrolyte or of electrolyte components · CPC title

• H01M4/0447

  of complete cells or cells stacks · CPC title

• H01M4/9041

  Metals or alloys (H01M4/92 takes precedence) · CPC title