Composite material as electrode for sodium ion batteries, production method therefor, and all-solid-state sodium battery
US-2017005337-A1 · Jan 5, 2017 · US
US10622673B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10622673-B2 |
| Application number | US-201615742538-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jul 27, 2016 |
| Priority date | Aug 10, 2015 |
| Publication date | Apr 14, 2020 |
| Grant date | Apr 14, 2020 |
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Provided is a thin beta-alumina-based solid electrolyte sheet having a high ion conduction value. The solid electrolyte sheet containing β-alumina and/or β″-alumina and having a thickness of 1 mm or less and a voidage of 20% or less.
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The invention claimed is: 1. A solid electrolyte sheet containing β-alumina and/or β″-alumina and having a thickness of 1 mm or less and a voidage of 20% or less, wherein the solid electrolyte sheet includes, in % by mole, 65 to 98% Al 2 O 3 , 2 to 20% Na 2 O, 0.3 to 10% of at least one of MgO and Li 2 O, and 1 to 15% ZrO 2 . 2. The solid electrolyte sheet according to claim 1 , having an ion conduction value of 1 S to 6.5 S. 3. A solid electrolyte sheet containing p-alumina and/or β″-alumina and having a thickness of 1 mm or less and a voidage of 20% or less, wherein the solid electrolyte sheet includes, in % by mole, 65 to 98% Al 2 O 3 2 to 20% Na 2 O, 0.3 to 10% of at least one of MgO and Li 2 O, and 0.01 to 5% Y 2 O 3 . 4. The solid electrolyte sheet according to claim 1 , wherein the solid electrolyte sheet is for use in a sodium ion all-solid-state secondary cell. 5. A sodium ion all-solid-state secondary cell including the solid electrolyte sheet according to claim 4 , a positive electrode layer formed on one side of the solid electrolyte sheet, and a negative electrode layer formed on the other side of the solid electrolyte sheet. 6. A solid electrolyte sheet containing β-alumina and/or β″-alumina and having a thickness of 1 mm or less and an ion conduction value of 1 S to 6.5 S, wherein the solid electrolyte sheet includes, in % by mole, 65 to 98% Al 2 O 3 , 2 to 20% Na 2 O, 0.3 to 10% of at least one of MgO and Li 2 O, and 1 to 15% ZrO 2 . 7. A solid electrolyte sheet containing p-alumina and/or β″-alumina and having a thickness of 1 mm or less and an ion conduction value of 1 S to 6.5 S, wherein the solid electrolyte sheet includes, in % by mole, 65 to 98% Al 2 O 3 2 to 20% Na 2 O, 0.3 to 10% of at least one of MgO and Li 2 O, and 0.01 to 5% Y 2 O 3 . 8. A solid electrolyte sheet containing β-alumina and/or β″-alumina and having a thickness of 1 mm or less and a voidage of 20% or less, wherein the solid electrolyte sheet includes, in % by mole, 65 to 98% Al 2 O 3 , 2 to 20% Na 2 O, 0.3 to 15% of at least one of MgO and Li 2 O, and 1 to 15% ZrO 2 or 0.01 to 5% Y 2 O 3 . 9. A solid electrolyte sheet containing β-alumina and/or β″-alumina and having a thickness of 1 mm or less and an ion conduction value of 1 S to 6.5 S, wherein the solid electrolyte sheet includes, in % by mole, 65 to 98% Al 2 O 3 , 2 to 20% Na 2 O, 0.3 to 15% of at least one of MgO and Li 2 O, and 1 to 15% ZrO 2 or 0.01 to 5% Y 2 O 3 .
Mixing details · CPC title
obtaining ceramic films, e.g. by using temporary supports · CPC title
Density · CPC title
Alkali metal oxides or oxide-forming salts thereof · CPC title
Oxides · CPC title
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