Optical alignment film composition, optical alignment film, optical laminate, and image display device

Patent metadata

Field	Value
Publication number	US-10620481-B2
Application number	US-201815957367-A
Country	US
Kind code	B2
Filing date	Apr 19, 2018
Priority date	Oct 23, 2015
Publication date	Apr 14, 2020
Grant date	Apr 14, 2020

Abstract

According to the invention, provided are an optical alignment film composition with which an optical alignment film having excellent aligning properties can be produced, and an optical alignment film, an optical laminate, and an image display device produced using the optical alignment film composition. An optical alignment film composition according to the invention contains a polymer A which has a constitutional unit a1 including a cinnamate group and a low-molecular-weight compound B which has a cinnamate group and has a lower molecular weight than the polymer A.

First claim

What is claimed is:

1. An optical alignment film composition comprising:
a polymer A which has a constitutional unit a1 including a cinnamate group; and
a low-molecular-weight compound B which has a cinnamate group and has a lower molecular weight than the polymer A,
wherein the low-molecular-weight compound B is a compound represented by Formula (B1),

here, in Formula (B1), a represents an integer of 0 to 5, R 1 represents a chain or cyclic alkyl group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, or an aryl group having 6 to 20 carbon atoms which may have a substituent, and R 2 represents a branched-chain alkyl group having 1 to 20 carbon atoms, and in a case where a is 2 or greater, a plurality of R 1 's may be the same as or different from each other.

2. The optical alignment film composition according to claim 1 ,
wherein the low-molecular-weight compound B has a molecular weight of 200 to 500.

3. The optical alignment film composition according to claim 1 ,
wherein the content of the low-molecular-weight compound B is 10 to 500 mass % with respect to the mass of the constitutional unit a1 of the polymer A.

4. The optical alignment film composition according to claim 1 ,
wherein the compound represented by Formula (B1) is isopropyl-p-methoxycinnamate, isoamyl-p-methoxycinnamate, 2-ethylhexyl-p-methoxycinnamate, 2-ethoxyethyl-p-methoxycinnamate, or 2-hexyldecanyl-p-methoxycinnamate.

5. The optical alignment film composition according to claim 1 ,
wherein the polymer A further has a constitutional unit a2 including a crosslinkable group.

6. The optical alignment film composition according to claim 1 , further comprising:
a crosslinking agent C having a crosslinkable group.

7. An optical alignment film which is produced using the optical alignment film composition according to claim 1 , comprising:
at least one selected from the group consisting of a cyclobutane ring provided by dimerization of the cinnamate groups of the polymer A and the low-molecular-weight compound B included in the optical alignment film composition and a structure provided by isomerization of the cinnamate groups.

8. An optical laminate comprising:
the optical alignment film according to claim 7 ; and
an optical anisotropic layer which is provided on the optical alignment film and contains a liquid crystal compound.

9. The optical laminate according to claim 8 , comprising, in order:
a support;
the optical alignment film; and
the optical anisotropic layer.

10. The optical laminate according to claim 9 ,
wherein a glass transition temperature of the support is 100° C. or lower.

11. The optical laminate according to claim 9 ,
wherein the support is a polarizer.

12. The optical laminate according to claim 9 , further comprising:
a resin layer between the support and the optical alignment film,
wherein the resin layer contains a compound having a partial structure represented by Formula (X)

13. The optical laminate according to claim 12 , further comprising:
another optical anisotropic layer which is different from the optical anisotropic layer between the resin layer and the optical alignment film.

14. The optical laminate according to claim 13 ,
wherein another optical anisotropic layer contains a liquid crystal compound.

15. An optical laminate which is produced by laminating the optical laminate according to claim 9 on a polarizer and by peeling off the support in the optical laminate,
wherein the optical anisotropic layer and the polarizer are laminated.

16. An image display device comprising:
the optical laminate according to claim 8 .

17. The image display device according to claim 16 , comprising, in order:
a polarizer;
an adhesive layer or a pressure sensitive adhesive layer;
an optical anisotropic layer;
an optical alignment film;
an adhesive layer or a pressure sensitive adhesive layer; and
a display element,
wherein no support is provided between the optical alignment film and the display element.

18. The optical alignment film composition according to claim 2 ,
wherein the content of the low-molecular-weight compound B is 10 to 500 mass % with respect to the mass of the constitutional unit a1 of the polymer A.

19. The optical alignment film composition according to claim 6 ,
wherein the crosslinking agent C is a compound having two or more epoxy groups or oxetanyl groups in the molecule.

20. The optical alignment film composition according to claim 19 ,
wherein the crosslinking agent C has a molecular weight of 100 to 500.

Assignees

• Fujifilm Corp

Inventors

• Wakita Taku
• Muramatsu Ayako
• Moriya Chie
• Takada Yoshiaki
• Ishiguro Makoto

Classifications

• G02F1/133711 Primary

  by organic films, e.g. polymeric films · CPC title

• C09D133/14

  of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen · CPC title

• G02F1/133788

  by light irradiation, e.g. linearly polarised light photo-polymerisation · CPC title

• C08L101/08

  Carboxyl groups · CPC title

• C08F8/14

  Esterification · CPC title