Multi-product liquefaction method and system

Patent metadata

Field	Value
Publication number	US-10619917-B2
Application number	US-201715703321-A
Country	US
Kind code	B2
Filing date	Sep 13, 2017
Priority date	Sep 13, 2017
Publication date	Apr 14, 2020
Grant date	Apr 14, 2020

Abstract

A liquefaction system is capable of sequentially or simultaneously liquefying multiple feed streams of hydrocarbons having different normal bubble points with minimal flash. The liquefying heat exchanger has separate circuits for handling multiple feed streams. The feed stream with the lowest normal boiling point is sub-cooled sufficiently to suppress most of the flash. Feed streams with relatively high normal boiling points are cooled to substantially the same temperature, then blended with bypass streams to maintain each product near its normal bubble point. The system can also liquefy one stream at a time by using a dedicated circuit or by allocating the same feed to multiple circuits.

First claim

The invention claimed is:

1. A method for cooling and liquefying at least two feed streams in a coil-wound heat exchanger, the method comprising:
(a) introducing that at least two feed streams into a warm end of the coil-wound heat exchanger, the at least two feed streams comprising a first feed stream having a first normal bubble point and a second feed stream having a second normal bubble point that is lower than the first normal bubble point;
(b) cooling by indirect heat exchange in the con-wound heat exchanger at least a first portion of each of the first feed stream and the second feed stream against a refrigerant to form at least two cooled feed streams comprising a first cooled feed stream and a second cooled feed stream;
(c) withdrawing the at least two cooled feed streams from a cold end of the coil-would heat exchanger at substantially the same withdrawal temperature;
(d) providing at least two product streams, each of the at least two product streams being downstream from and in fluid flow communication with one of the at least two cooled feed streams, each of the at least two product streams being maintained within a predetermined product stream temperature range of a predetermined product stream temperature, the at least two product streams comprising a first product stream and a second product stream, the predetermined product stream temperature for the first product stream being the first predetermined product stream temperature and the predetermined product stream temperature of the second product stream being the second predetermined product stream temperature;
(e) withdrawing a first bypass stream from the first feed stream upstream from the cold end of the coil-wound heat exchanger; and
(f) forming the first product stream by mixing the first cooled feed stream with the first bypass stream, the first predetermined product stream temperature being warmer than the withdrawal temperature of the first cooled feed stream.

2. The method of claim 1 , wherein each of the at least two feed streams comprises a hydrocarbon fluid.

3. The method of claim 1 , wherein step (e) comprises:
(e) withdrawing a first bypass stream from the first feed stream upstream from the warm end of the coil-wound heat exchanger.

4. The method of claim 1 , further comprising:
(g) phase separating the second cooled feed stream into a second flash vapor stream and the second product stream, the predetermined product stream temperature of the second product stream being lower than the withdrawal temperature of the second cooled feed stream.

5. The method of claim 4 , further comprising:
(h) compressing and cooling the second flash vapor stream to form a compressed second flash gas stream; and
(i) mixing the compressed second flash vapor stream with the second feed stream upstream from the coil-wound heat exchanger.

6. The method of claim 5 , further comprising:
(j) warming the second flash vapor stream by indirect heat exchange against the first bypass stream.

7. The method of claim 1 , further comprising:
(k) storing the second product stream in a second storage tank at a second storage pressure;
wherein the predetermined product stream temperature of the second product stream is a temperature at which no more than 10 mole % of the second product stream vaporizes at the second storage pressure.

8. The method of claim 1 , wherein the at least two feed streams further comprise a third feed stream having third volatility that is higher than the first volatility and lower than the second volatility, the at least two cooled feed streams further comprise a third cooled feed stream, the at least two product streams further comprise a third product stream.

9. The method of claim 8 , wherein step (d) further comprises providing the third product stream having a predetermined product stream temperature that is the same as the withdrawal temperature of the third cooled feed stream.

10. The method of claim 1 , further comprising:
(l) separating impurities from the second feed stream downstream from the second cooled feed stream in a phase separator to produce a second vapor stream containing the impurities and the second product stream.

11. The method of claim 1 , wherein the predetermined product stream temperature range for each of the at least two product streams is 4 degrees C.

Assignees

• Air Prod & Chem

Inventors

• Brussol Laurent Marc
• Holzer David Joseph
• Vovard Sylvain
• Shnitser Russell
• Brostow Adam Adrian
• Roberts Mark Julian

Classifications

• F25J1/0237

  integrating refrigeration provided for liquefaction and purification/treatment of the gas to be liquefied, e.g. heavy hydrocarbon removal from natural gas (details related to rectification F25J3/02; details related to partial condensation F25J3/06; working-up natural gas C10L3/10) · CPC title

• F25J2215/02

  Mixing or blending of fluids to yield a certain product · CPC title

• F25J1/0264

  Arrangement of heat exchanger cores in parallel with different functions, e.g. different cooling streams (F25J1/0272 takes precedence) · CPC title

• F25J2215/62

  Ethane or ethylene · CPC title

• F25J1/0219

  in combination with an internal quasi-closed refrigeration loop, e.g. using a deep flash recycle loop · CPC title