High load bearing capacity nylon staple fiber and nylon blended yarns and fabrics made therefrom

Patent metadata

Field	Value
Publication number	US-10619272-B2
Application number	US-201815958250-A
Country	US
Kind code	B2
Filing date	Apr 20, 2018
Priority date	Oct 10, 2008
Publication date	Apr 14, 2020
Grant date	Apr 14, 2020

Abstract

The nylon staple fibers so prepared can be blended with other fibers such as cotton staple fibers to produce nylon/cotton (NYCO) yarns which are also of desirably high strength.

First claim

The invention claimed is:

1. A process for preparing nylon staple fibers having a load-bearing capacity of greater than 3.2 to 5.0 grams per denier measured as tenacity (T 7 ) at 7% elongation, said process comprising the steps of melt-spinning nylon polymer into filaments, quenching said filaments and forming one or more tows from a multiplicity of said quenched filaments, subjecting said tow(s) to drawing and annealing, and converting said drawn and annealed tow(s) into staple fibers suitable for forming into spun yarn comprising;
A) the nylon polymer melt spun into filaments has a formic acid relative viscosity (RV) of from 45 to 100;
B) said nylon polymer filaments are spun, quenched and formed into tows with both positional uniformity and uniformity of quenching conditions which are sufficient to permit use of draw ratios that provide the desired eventual staple fiber T 7 tenacity greater than 3.2 to 5.0 grams per denier;
C) the drawing and annealing of the tow(s) is carried out in a two-stage continuous operation conducted at a total effective draw ratio of from 2.3 to 5.0, said operation comprising a first drawing stage carried out at a temperature of from 80° C. to 125° C. wherein from 85% to 97.5% of the drawing of the tow(s) occurs and a second annealing and drawing stage wherein said tow(s) is/are subjected to an annealing temperature of from 145° C. to 205° C.; said operation being followed by a cooling step wherein said drawn and annealed tow(s) is/are cooled to a temperature of less than 80° C.; and
D) the tow(s) is/are maintained under a controlled tension throughout said two stage continuous operation.

2. A process according to claim 1 wherein said staple fibers have a denier per filament of from 1.0 to 3.0 and a tenacity at break of at least 6.0 grams per denier.

3. A process according to claim 1 , wherein the relative viscosity (RV) of the nylon polymer ranges from 45 to 65.

4. A process according to claim 1 , wherein said staple fibers have a denier per filament of from 1.6 to 1.8, a tenacity at break of greater than 6.8 grams per denier, and a load-bearing capacity of from 3.3 to 4.5 grams per denier measured as tenacity (T 7 ) at 7% elongation.

5. A process according to claim 4 wherein said drawing and annealing of said multifilament tow is conducted at a total effective draw ratio of from 3.12 to 3.40.

6. A process according to claim 1 wherein said staple fibers have a denier per filament of from 2.3 to 2.7, a tenacity at break of from greater than 6.8 grams per denier, and a load-bearing capacity of from 3.3 to 5.0 grams per denier measured as tenacity (T 7 ) at 7% elongation.

7. A process according to claim 6 wherein said drawing and annealing of said multifilament tow is conducted at a total effective draw ratio of from 3.5 to 4.0.

8. A process according to claim 1 wherein said nylon polymer has an RV of from 50 to 60.

9. A process according to claim 1 wherein said first drawing stage is carried out at a temperature of from 80° C. to 125° C., and said second annealing and drawing stage is carried out at a temperature of from 165° C. to 205° C.

10. A process according to claim 1 wherein said nylon polymer is selected from the group consisting of polyhexamethylene adipamide (nylon 6,6) and polycaproamide (nylon 6).

11. Nylon staple fibers prepared by a process according to claim 1 .

Assignees

• Invista North America Sarl

Inventors

• Bloom Douglas A

Classifications

• D10B2331/02

  polyamides (D10B2331/08 takes precedence) · CPC title

• D01D5/26 Primary

  Formation of staple fibres (by flash-spinning D01D5/11) · CPC title

• D02G3/442

  Cut or abrasion resistant yarns or threads · CPC title

• Y10T442/30

  Woven fabric [i.e., woven strand or strip material] · CPC title

• D03D1/0041

  Cut or abrasion resistant · CPC title