Method for controlled release and making of a cement additive in a wellbore

Patent metadata

Field	Value
Publication number	US-10619085-B2
Application number	US-201816230391-A
Country	US
Kind code	B2
Filing date	Dec 21, 2018
Priority date	Jan 2, 2018
Publication date	Apr 14, 2020
Grant date	Apr 14, 2020

Abstract

Embodiments provide a method for controlled release of a cement additive for use in a wellbore. The method includes the steps of mixing an aramide capsule with a cement slurry to form an additive-containing slurry, and introducing the additive-containing slurry into the wellbore. The aramide capsule is formed by interfacial polymerization where an aramide polymer forms a semi-permeable membrane encapsulating the cement additive.

First claim

What is claimed is:

1. A method for controlled release of a cement additive for use in a wellbore, the method comprising the steps of:
mixing an aramide capsule with a cement slurry to form an additive-containing slurry, where the aramide capsule is formed by the steps of:
mixing a continuous solvent and a surfactant to produce a continuous phase;
mixing a dispersed solvent, a dispersed monomer, and the cement additive to produce a dispersed phase, where the dispersed solvent and the continuous solvent are immiscible;
mixing the continuous phase and the dispersed phase to form a mixture having an emulsion such that the dispersed phase is dispersed as droplets in the continuous phase, where an interface defines the droplets of the dispersed phase dispersed in the continuous phase;
adding a crosslinker to the mixture;
allowing an aramide polymer to form on the interface of the droplets, such that the aramide polymer forms a semi-permeable membrane around a core, where the core contains the dispersed phase, such that the semi-permeable membrane around the core forms the aramide capsule;
allowing the aramide capsule to settle from the mixture; and
separating the aramide capsule from the mixture using a separation method; and

introducing the additive-containing slurry into the wellbore.

2. The method of claim 1 , further comprising the steps of:
allowing the cement additive to permeate from the core through the semi-permeable membrane to the cement slurry; and
allowing the cement additive to have a beneficial interaction with the cement slurry.

3. The method of claim 1 , further comprising the steps of:
allowing the additive-containing slurry to set to form a hardened cement, where the aramide capsule is embedded in the hardened cement;
allowing the cement additive to permeate from the core through the semi-permeable membrane to the hardened cement; and
allowing the cement additive to have a beneficial interaction with the hardened cement.

4. The method of claim 3 , where the hardened cement has an unconfined compression strength ranging from about 3,000 psi to about 3,400 psi.

5. The method of claim 1 , further comprising the steps of:
allowing the additive-containing slurry to set to form a hardened cement, where the aramide capsule is embedded in the hardened cement;
allowing the semi-permeable membrane to burst such that the cement additive is released from the aramide capsule and migrates through the hardened cement; and
allowing the cement additive to have a beneficial interaction with the hardened cement.

6. The method of claim 5 , where the hardened cement has an unconfined compression strength ranging from about 3,000 psi to about 3,400 psi.

7. The method of claim 1 , where the dispersed solvent is selected from the group consisting of water, ethanol, methanol, and combinations of the same.

8. The method of claim 1 , where the dispersed monomer comprises an amine group.

9. The method of claim 8 , where the where the dispersed monomer is selected from the group consisting of ethylenediamine, meta-phenylenediamine, para-phenylenediamine, hexamethylenediamine, and combinations of the same.

10. The method of claim 1 , where the continuous solvent is selected from the group consisting of oil, mineral oil, cyclohexane, chloroform, and combinations of the same.

11. The method of claim 1 , where the crosslinker is selected from the group consisting of 1,3,5-benzenetricarbonyl trichloride, sebacoyl chloride, and combinations of the same.

12. The method of claim 1 , where the cement additive is water-soluble and is selected from the group consisting of sealing reagents, anti-gas migration additives, high-temperature retarders, fluid-loss additives, accelerators, superplasticizers, and combinations of the same.

13. The method of claim 1 , where the aramide polymer of the aramide capsule is present in the additive-containing slurry at a concentration of at least about 3% by weight of cement.

Assignees

• Saudi Arabian Oil Co

Inventors

• Contreras Elizabeth Q

Classifications

• C09K8/487 Primary

  Fluid loss control additives; Additives for reducing or preventing circulation loss · CPC title

• C04B20/1037

  obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds · CPC title

• C04B24/287

  Polyamides · CPC title

• C09K8/493

  Additives for reducing or preventing gas migration · CPC title

• C04B2103/0062

  Cross-linked polymers · CPC title