Coating compositions that transmit infrared radiation and exhibit color stability and related coating systems
US-9057835-B2 · Jun 16, 2015 · US
US10619053B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10619053-B2 |
| Application number | US-201715796101-A |
| Country | US |
| Kind code | B2 |
| Filing date | Oct 27, 2017 |
| Priority date | Oct 27, 2017 |
| Publication date | Apr 14, 2020 |
| Grant date | Apr 14, 2020 |
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A solar reflective coating composition includes: a film-forming resin; a plurality of near-IR transparent pigments dispersed in the film-forming resin, the plurality of near-IR transparent pigments including a first perylene pigment and a second perylene pigment different from the first perylene pigment; and a near-IR reflective pigment dispersed in the film-forming resin, the near-IR reflective pigment different from the first perylene pigment and the second perylene pigment. When formed into a cured coating over a substrate, the cured coating exhibits an off-white or grey color. The solar reflective coating composition is substantially free of carbon black. The present invention is also directed to a substrate having a surface at least partially coated with a solar reflective coating composition and a method of preparing a low weight aerospace component.
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The invention claimed is: 1. A solar reflective coating composition comprising: a film-forming resin; a plurality of near-IR transparent pigments dispersed in the film-forming resin, the plurality of near-IR transparent pigments comprising a first perylene pigment and a second perylene pigment different from the first perylene pigment; and a near-IR reflective pigment dispersed in the film-forming resin, the near-IR reflective pigment different from the first perylene pigment and the second perylene pigment, wherein, when formed into a cured coating over a substrate, the cured coating exhibits an off-white or grey color, and wherein the solar reflective coating composition is substantially free of carbon black, wherein the cured coating exhibits the off-white or grey color as defined by the following CIELAB values as measured using an integrating sphere with D65 Illumination, 10° observer with specular component included: a L* value ranging from 40 to 95; an a* value ranging from −2 to 2; and a b* value ranging from −6 to 6. 2. The coating composition of claim 1 , wherein the first perylene pigment comprises a green-shade perylene pigment and the second perylene pigment comprises a purple-shade perylene pigment. 3. The coating composition of claim 1 , wherein the near-IR reflective pigment comprises titanium dioxide. 4. The coating composition of claim 3 , wherein the titanium dioxide is dispersed in the film-forming resin in powder form. 5. The coating composition of claim 1 , wherein the cured coating exhibits a total solar reflectance of at least 45% as measured in accordance with ASTM E903-12. 6. The coating composition of claim 1 , wherein the cured coating fully hides the substrate at a dry film thickness of less than or equal to 2.5 mils, according to ASTM D6762. 7. A substrate comprising a surface at least partially coated with the solar reflective coating composition of claim 1 . 8. The substrate of claim 7 , wherein the substrate is an aerospace component. 9. The substrate of claim 8 , wherein the aerospace component comprises a carbon fiber reinforced polymer composite. 10. The substrate of claim 7 , wherein the solar reflective coating composition, when cured, is the sole coating layer on the substrate. 11. The substrate of claim 7 , wherein the solar reflective coating composition, when cured, has a dry film thickness of less than or equal to 2.5 mils. 12. The substrate of claim 7 , further comprising a basecoat layer underlying at least a portion of the solar reflective coating composition. 13. The substrate of claim 7 , wherein the near-IR reflective pigment comprises titanium dioxide. 14. The substrate of claim 13 , wherein the titanium dioxide is dispersed in the film-forming resin in powder form. 15. The substrate of claim 7 , wherein the first perylene pigment comprises a green-shade perylene pigment and the second perylene pigment comprises a purple-shade perylene pigment. 16. The substrate of claim 7 , wherein the solar reflective coating composition, when cured, exhibits a total solar reflectance of at least 45% as measured in accordance with ASTM E903-12. 17. A method of preparing a low weight aerospace component comprising: coating at least a portion of surface of an aerospace component with the coating composition of claim 1 ; and curing the solar reflective coating composition to form a solar reflective layer. 18. The method of claim 17 , wherein the solar reflective layer has a dry film thickness of less than or equal to 2.5 mils. 19. A vehicle comprising a surface at least partially coated with the solar reflective coating composition of claim 1 . 20. The vehicle of claim 19 , wherein the vehicle is an aircraft. 21. The coating composition of claim 1 , wherein the cured coating exhibits a L* value ranging from 55 to 95.
Organic pigments; Organic dyes · CPC title
Two or more polyesters of different physical or chemical nature (C08G18/44 takes precedence) · CPC title
condensed with carbocyclic rings · CPC title
the composition being defined by the absence of a certain additive · CPC title
Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain (based on polyester-amides C09D177/12; based on polyester-imides C09D179/08); Coating compositions based on derivatives of such polymers · CPC title
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