Masterbatch formulation and formation

Patent metadata

Field	Value
Publication number	US-10619014-B2
Application number	US-201615543043-A
Country	US
Kind code	B2
Filing date	Jan 19, 2016
Priority date	Jan 19, 2015
Publication date	Apr 14, 2020
Grant date	Apr 14, 2020

Abstract

A masterbatch may include a syndiotactic polypropylene and one or more additives. The one or more additives may be present in the masterbatch in an amount of at least 13 weight percent based on a total weight of the masterbatch. The masterbatch may be formed by mixing the one or more additives with the syndiotactic polypropylene. The masterbatch may be mixed with a resin to form a resin mixture.

First claim

What is claimed is:

1. A masterbatch comprising:
syndiotactic polypropylene; and
one or more additives comprising a metallic acrylate salt, wherein the metallic acrylate salt is present in an amount of 40 to 70 weight percent based on a total weight of the masterbatch, wherein the masterbatch has a die swell of between 0.8 and 0.9.

2. The masterbatch of claim 1 , wherein the one or more additives further comprises a pigment.

3. The masterbatch of claim 2 , wherein the pigment comprises carbon black.

4. The masterbatch of claim 1 , wherein the one or more additives further comprises a nucleator, a clarifier, a stabilizer, an ultra-violet screening agent, an oxidant, an anti-oxidant, an anti-static agent, an ultraviolet light absorbent, a fire retardant, a processing oil, a mold release agent, a coloring agent, a filler, or combinations thereof.

5. The masterbatch of claim 1 , wherein the metallic acrylate salt comprises zinc diacrylate, zinc dimethylacrylate, copper diacrylate, copper dimethylacrylate, or combinations thereof.

6. The masterbatch of claim 1 , wherein the one or more additives further comprise cyclohexanedicarboxylic acid, calcium salt, zinc stearate, zinc di-vinylacetate, zinc di-ethylfumarate, copper di-vinylacetate, copper diethylfumarate, aluminum triacrylate, aluminum trimethylacrylate, aluminum tri-vinylacetate, aluminum tri-ethylfumarate, zirconium tetraacrylate, zirconium tetramethylacrylate, zirconium tetra-vinylacetate, zirconium tetra-ethyl fumarate, or combinations thereof.

7. The masterbatch of claim 1 , wherein the syndiotactic polypropylene has a melt flow rate of from 1.0 to 3.0 g/10 min, as measured in accordance with ASTM D 1238 at 230° C. under a load of 2.16 kg.

8. The masterbatch of claim 1 , wherein the syndiotactic polypropylene has a melting point, as measured by DSC of from 115° C. to 175° C.

9. The masterbatch of claim 1 , wherein the syndiotactic polypropylene has a density of from 0.87 to 0.89 g/cc, as measured by ASTM D 1505.

10. The masterbatch of claim 1 , wherein the masterbatch has a MFR of between no flow and 0.2 g/10 min as measured by ASTM D 1238 at 230° C. under a load of 2.16 kg.

11. A method for preparing a masterbatch comprising: mixing one or more additives with a syndiotactic polypropylene to form a masterbatch, wherein the one or more additives comprise a metallic acrylate salt and the metallic acrylate salt is present in an amount of 40 to 70 weight percent based on a total weight of the masterbatch, wherein the masterbatch has a die swell of between 0.8 and 0.9.

12. The method of claim 11 , wherein the one or more additives further comprise a pigment.

13. The method of claim 12 , wherein the pigment comprises carbon black.

14. The method of claim 11 , wherein the one or more additives further comprise an organometallic salt, a nucleator, a clarifier, a stabilizer, an ultra-violet screening agent, an oxidant, an anti-oxidant, an anti-static agent, an ultraviolet light absorbent, a fire retardant, a processing oil, a mold release agent, a coloring agent, a filler, or combinations thereof.

15. The method of claim 11 , wherein the metallic acrylate salt is zinc diacrylate, zinc dimethylacrylate, copper diacrylate, copper dimethylacrylate, or combinations thereof.

16. The method of claim 11 , wherein the mixing of the one or more additives with the syndiotactic polypropylene to form the masterbatch is performed by extrusion of the one or more additives with the syndiotactic polypropylene.

17. A method of forming pellets comprising directly pelletizing the masterbatch prepared by the method of claim 11 after extrusion of the one or more additives with the syndiotactic polypropylene.

18. A method of forming a resin mixture, comprising mixing the masterbatch prepared by the method of claim 11 with a resin to form a resin mixture.

19. The method of claim 18 , wherein the resin is polypropylene or polyethylene.

Assignees

• Fina Technology

Inventors

• Li Fengkui
• Sun Likuo

Classifications

• C08L2310/00

  Masterbatches · CPC title

• C08J2323/12

  Polypropene · CPC title

• C08J3/22 Primary

  using masterbatch techniques · CPC title

• C08L23/12

  Polypropene · CPC title

• C08K5/098

  Metal salts of carboxylic acids · CPC title