Homoallyl halide composition and method for storing homoallyl halide

Patent metadata

Field	Value
Publication number	US-10618860-B2
Application number	US-201615760405-A
Country	US
Kind code	B2
Filing date	Sep 13, 2016
Priority date	Sep 18, 2015
Publication date	Apr 14, 2020
Grant date	Apr 14, 2020

Abstract

There is provided a composition containing one or more basic compounds selected from the group consisting of tertiary amines, nitrogen-containing heterocyclic aromatic compounds, alkali metal carbonate salts, alkaline earth metal carbonate salts and alkali metal hydrogencarbonate salts, and a homoallyl halide.

First claim

The invention claimed is:

1. A composition, comprising:
at least one basic compound selected from the group consisting of a tertiary amine, a nitrogen-containing heterocyclic aromatic compound, an alkali metal carbonate salt, an alkaline earth metal carbonate salt and an alkali metal hydrogencarbonate salt; and
a homoallyl halide.

2. A composition, comprising:
at least one basic compound selected from the group consisting of an alkali metal carbonate salt and an alkaline earth metal carbonate salt; and
a homoallyl halide.

3. A method for storing a homoallyl halide, the method comprising allowing at least one basic compound selected from the group consisting of a tertiary amine, a nitrogen-containing heterocyclic aromatic compound, an alkali metal carbonate salt, an alkaline earth metal carbonate salt and an alkali metal hydrogencarbonate salt, to coexist with the homoallyl halide.

4. A method for producing a compound or a resin, the method comprising using the composition according to claim 1 as a raw material.

5. A method for producing a compound or a resin, the method comprising using the composition according to claim 2 as a raw material.

6. The composition of claim 1 , wherein a mass ratio of the at least one basic compound to the homoallyl halide is from 0.00001:1 to 0.3:1.

7. The composition of claim 1 , further comprising an organic solvent.

8. The composition of claim 2 , wherein a mass ratio of the at least one basic compound to the homoallyl halide is from 0.00001:1 to 0.3:1.

9. The composition of claim 2 , further comprising an organic solvent.

10. The composition of claim 7 , wherein the organic solvent is at least one selected from the group consisting of an aliphatic hydrocarbon, aromatic hydrocarbon, ether, and an aliphatic hydrocarbon halide.

11. The composition of claim 8 , wherein the organic solvent is at least one selected from the group consisting of an aliphatic hydrocarbon, aromatic hydrocarbon, ether, and an aliphatic hydrocarbon halide.

12. The composition of claim 7 , wherein a mass ratio of the organic solvent to the homoallyl halide is form the 0.1:1 to 50:1.

13. The composition of claim 8 , wherein a mass ratio of the organic solvent to the homoallyl halide is form the 0.1:1 to 50:1.

14. The composition of claim 1 , wherein the homoallyl halide is at least one selected from the group consisting of 3-butenyl chloride, 3-methyl-3-butenyl chloride, 2-methyl-3-butenyl chloride, 4-methyl-3-pentenyl chloride, 3-hexenyl chloride, 2-isopropenyl-5-methyl-4-hexenyl chloride, 3-butenyl bromide, 3-methyl-3-butenyl bromide, 2-methyl-3-butenyl bromide, 4-methyl-3-pentenyl bromide, 3-hexenyl bromide, 2-isopropenyl-5-methyl-4-hexenyl bromide, 3-butenyl iodide, 3-methyl-3-butenyl iodide, 2-methyl-3-butenyl iodide, 4-methyl-3-pentenyl iodide, 3-hexenyl iodide, 2-isopropenyl-5-methyl-4-hexenyl iodide, 3-butenyl fluoride, 3-methyl-3-butenyl fluoride, 2-methyl-3-butenyl fluoride, 4-methyl-3-pentenyl fluoride, 3-hexenyl fluoride, and 2-isopropenyl-5-methyl-4-hexenyl fluoride.

15. The composition of claim 2 , wherein the homoallyl halide is at least one selected from the group consisting of 3-butenyl chloride, 3-methyl-3-butenyl chloride, 2-methyl-3-butenyl chloride, 4-methyl-3-pentenyl chloride, 3-hexenyl chloride, 2-isopropenyl-5-methyl-4-hexenyl chloride, 3-butenyl bromide, 3-methyl-3-butenyl bromide, 2-methyl-3-butenyl bromide, 4-methyl-3-pentenyl bromide, 3-hexenyl bromide, 2-isopropenyl-5-methyl-4-hexenyl bromide, 3-butenyl iodide, 3-methyl-3-butenyl iodide, 2-methyl-3-butenyl iodide, 4-methyl-3-pentenyl iodide, 3-hexenyl iodide, 2-isopropenyl-5-methyl-4-hexenyl iodide, 3-butenyl fluoride, 3-methyl-3-butenyl fluoride, 2-methyl-3-butenyl fluoride, 4-methyl-3-pentenyl fluoride, 3-hexenyl fluoride, and 2-isopropenyl-5-methyl-4-hexenyl fluoride.

Assignees

• Kuraray Co

Inventors

• Sato Junko
• Ujita Katsuji
• Tsuruta Takuo
• Sugioka Takashi

Classifications

• C07C17/16

  of hydroxyl groups · CPC title

• C07C21/04

  Chloro-alkenes · CPC title

• C08F14/04

  Monomers containing two carbon atoms · CPC title

• C07C17/42 Primary

  Use of additives, e.g. for stabilisation · CPC title

• C08F14/14

  Monomers containing three or more carbon atoms · CPC title