Ionic liquid reactor with hydrocyclones

Patent metadata

Field	Value
Publication number	US-10618858-B2
Application number	US-201615217918-A
Country	US
Kind code	B2
Filing date	Jul 22, 2016
Priority date	Jul 24, 2015
Publication date	Apr 14, 2020
Grant date	Apr 14, 2020

Abstract

A method of alkylating a hydrocarbon stream including: providing a feed stream that includes hydrocarbons and ionic liquid catalyst; passing the feed stream through a low efficiency mixer to create a mixed stream, whereby the low efficiency mixer creates droplets within the feed stream that are primarily within a predetermined size range; passing the mixed stream and an olefin stream into a reactor; performing an alkylation reaction within the reactor, thereby forming a reacted stream; and separating the reacted stream into a settled ionic liquid catalyst stream and a hydrocarbon stream through the use of at least one hydrocyclone.

First claim

The invention claimed is:

1. A method of alkylating a hydrocarbon stream comprising:
providing a reactor and a feed stream that includes paraffinic or aromatic hydrocarbons and ionic liquid catalyst;
combining the feed stream with a mixing chamber recycle stream from a mixing chamber of the reactor to form a combined stream;
passing the combined stream through a low efficiency mixer to create a mixed stream, wherein said low efficiency mixer includes a pump which creates droplets within said combined stream that are within a predetermined size range;
passing the mixed stream and an olefin stream into the reactor, wherein the reactor has a top and a bottom, and wherein the mixed stream and the olefin stream enter the reactor at the bottom of the reactor;
performing an alkylation reaction within the reactor, thereby forming a reacted stream; and
separating the reacted stream into a settled ionic liquid catalyst stream and a hydrocarbon stream through the use of at least one hydrocyclone, wherein the hydrocarbon stream exits the reactor at the top of the reactor.

2. The method according to claim 1 , further comprising cooling the recycle stream prior to entering the low efficiency mixer.

3. The method according to claim 1 , further comprising measuring droplet size of the ionic liquid catalyst within the mixing chamber, and regulating the speed of the low efficiency mixer and the flow rate of the recycle stream based on the droplet size measured in the previous step.

4. The method according to claim 1 , further comprising cooling the mixed stream after passing through the low efficiency mixer but prior to passing into the reactor.

5. The method according to claim 1 , further comprising:
passing the settled ionic liquid catalyst stream from the at least one hydrocyclone to a surge drum;
providing a make-up ionic liquid stream to the surge drum; and
combining a stream from the surge drum with the feed stream within a pre-mixer.

6. The method according to claim 1 , wherein the ionic liquid catalyst stream includes a phosphonium based ionic liquid catalyst.

7. The method according to claim 1 , wherein the feed stream includes isobutane.

8. The method according to claim 1 , wherein the step of passing an olefin stream into the reactor comprises passing multiple olefin streams into a riser of the reactor at multiple different elevations.

9. The method according to claim 1 , wherein the olefin stream includes molecules having from 3 to 8 carbon atoms.

10. The method according to claim 1 , further comprising a step of pre-mixing the hydrocarbons and the ionic liquid catalyst within a pre-mixer to form the feed stream, wherein the pre-mixing step is performed before the step of combining the feed stream with a mixing chamber recycle stream.

11. The method according to claim 1 , wherein the reactor is an upflow reactor.

12. The method according to claim 1 , wherein the alkylation reaction is performed within the temperature range of about 5° C. to about 150° C.

13. The method according to claim 1 , wherein the alkylation reaction is performed within the temperature range of about 30° C. to about 130° C.

14. The method according to claim 1 , wherein the alkylation reaction is performed within the temperature range of about 10° C. to about 27° C.

Assignees

• Uop Llc

Inventors

• Leeton Eric

Classifications

• C07C2/60 Primary

  with halides · CPC title

• C07C2531/02

  containing organic compounds or metal hydrides · CPC title

• C07C9/16

  Branched-chain hydrocarbons · CPC title