Method for producing a material composite composed of metal and plastic to form a plastic-metal hybrid component

Patent metadata

Field	Value
Publication number	US-10618207-B2
Application number	US-201515317986-A
Country	US
Kind code	B2
Filing date	May 4, 2015
Priority date	Jun 11, 2014
Publication date	Apr 14, 2020
Grant date	Apr 14, 2020

Abstract

The invention relates to a method for producing a material composite composed of metal and plastic to form a plastic-metal hybrid component, in which method, to improve the adhesion of the metal surface and at least one plastic component, stochastically random macroscopic and/or microscopic undercuts are made by means of short-pulse laser radiation in the metal surface in order to roughen it, these undercuts each being filled at least partially with the at least one plastic component in an injection moulding process such that said plastic component engages into the macroscopic and/or microscopic undercuts, wherein, following the roughening of the metal surface and before and/or during the injection moulding process for the at least one plastic component, at least the roughened surface of the metal is heated to a temperature which, during processing, lies in the range of room temperature up to 100° C. above the processing temperature of the plastic.

First claim

The invention claimed is:

1. A method for producing a material composite composed of metal and plastic to form a plastic-metal hybrid component, wherein, to improve the adhesion of the metal surface and at least one plastic component, macroscopic undercuts with microscopic undercuts having stochastically random roughness shapes are introduced by means of short-pulse laser radiation into the metal surface in order to roughen it, said undercuts each being filled at least partially with the at least one plastic component in an injection moulding process, such that said plastic component engages in the random undercuts, wherein, following the roughening of the metal surface before and/or during the injection moulding process for the at least one plastic component, at least the roughened surface of the metal is heated to a temperature which, during processing, lies in the range from room temperature up to 100° C. above the processing temperature of the at least one plastic component, wherein the at least one plastic component is compounded with additives to increase its bonding strength to the roughened and heated metal surface.

2. The method according to claim 1 , wherein the temperature to which the roughened surface of the metal is heated lies in the range from 100° C. below up to the processing temperature of the at least one plastic component.

3. The method according to claim 1 , wherein the heating of the roughened metal surface of the metal takes place to a temperature which is higher than the glass transition temperature.

4. The method according to claim 1 , wherein the temperature to which at least the roughened metal surface of the metal is heated is selected dependent on parameters such as process duration, viscosity of the melt and fineness and depth of the roughening of the metal surface.

5. The method according to claim 1 , wherein, to generate the macroscopic undercuts of the metal surface by means of the short-pulse laser radiation, use is made of a scanner with an adapted focal length of the scanner optics and a beam guide.

6. The method according to claim 5 , wherein the scanner is continuously moved at a predetermined speed relative to the metal surface to be roughened and its movement is superimposed with an axial movement of a robot, wherein the scanner optics at the same time guides the laser beam in a continuous loop over the metal surface in its working field and a uniform roughening (structuring) is generated continuously with a continuous relative movement on the entire metal surface.

7. The method according to claim 1 , wherein the heating of the metal takes place inside the injection moulding tool.

8. The method according to claim 1 , wherein the heating of the metal takes place outside the injection moulding tool in a furnace.

9. The method according to claim 1 , wherein the heating of the metal takes place inductively.

10. The method according to claim 1 , wherein the heating of the metal takes place by variable temperature regulation.

11. The method according to claim 1 , wherein the heating of the metal takes place by means of water, oil or gas in an internal high-pressure forming process.

12. The method according to claim 1 , wherein thermoplastics are used for the at least one plastic component.

13. The method according to claim 12 , wherein thermoplastic polymers such as polyamides, polyesters, polyacetals, polybutylene terephthalate and polyolefins such as polypropylene or polyethylene or mixtures thereof or polyamides such as polyamide 6 or polyamide 6.6 or polyphenylene oxide or polyether imide are selected as thermoplastics.

14. The method according to claim 1 , wherein thermosetting plastics are used for the at least one plastic component.

15. The method according to claim 1 , wherein elastomers or elastomer-like plastics are used for the at least one plastic component.

16. The method according to claim 1 , wherein the injection moulding process with the at least one plastic component takes place under an at least partial vacuum.

17. The method according to claim 1 , wherein the at least one plastic component is compounded with fillers and reinforcing materials.

18. The method according to claim 17 , wherein, as fillers and reinforcing materials, use is made of those that reduce the length expansion coefficient of the at least one plastic component.

19. The method according to claim 1 , wherein glass fibres, carbon fibres, aramide fibres or natural fibres of flax, hemp or sisal are used as fibres for reinforcing the at least one plastic component.

20. The method according to claim 19 , wherein fibres with a fibre length of less than 1 mm or less than 0.4 mm or short glass fibres are used.

21. The method according to claim 19 , wherein fibres with a fibre length in the range from 1 mm to 30 mm or long glass fibres are used.

22. The method according to claim 19 , wherein, as reinforcing materials, use is made of polymer-based reinforcing systems such aramide fibres, which have a negative thermal expansion coefficient along the fibre orientation.

23. The method according to claim 1 , wherein, when use is made of steel, aluminium or other metals and highly reinforced thermoplastic plastic is used as a plastic component, the roughened steel surface is heated before the injection moulding process with the highly reinforced thermoplastic plastic to a temperature in the range from 100° C. below up to melt temperature in processing.

24. The method according to claim 1 , wherein an aluminium workpiece is used as the metal of the material composite, wherein, after roughening of the aluminium surface, the aluminium workpiece is formed under conditions of internal high pressure into an aluminium component before the injection moulding with the at least one plastic component and the arising forming heat of the aluminium is used for heating the roughened aluminium surface for the injection moulding process with the at least one plastic component, said process taking place directly in the same tool.

25. The method according to claim 1 , wherein the production of the material composite of the plastic-metal hybrid component is simulated numerically depending on the process parameters: heating at least of the roughened surface of the metal to a temperature, process duration of the injection moulding, temperature-dependent viscosity of the melt and fineness and depth of the roughening (structuring) of the metal surface.

26. A method for producing a material composite composed of metal and plastic to form a plastic-metal hybrid component, wherein, to improve the adhesion of the metal surface and at least one plastic component, stochastically random macroscopic and/or microscopic undercuts are introduced by means of short-pulse laser radiation into the metal surface in order to roughen it, said undercuts each being filled at least partially with the at least one plastic component in an injection moulding process, such that said plastic component engages in the macroscopic and/or microscopic undercuts, wherein, following the roughening of the metal surface before and/or during the injection moulding process for the at least one plastic component, at least the roughened surface of the metal is heated to a temperature which, during processing, lies in the range from room temperature up to 100° C. above the processing temperature of the at least one plastic component, wherein the at least one plastic component i

Assignees

• Inpro Innovationsgesellschaft Fuer Fortgeschrittene Produktionssysteme In Der Fahrzeugindustrie Mbh
• Albis Plastic Gmbh
• Allod Werkstoff Gmbh & Co Kg
• Audi Ag
• Basf Se
• Neue Mat Fuerth Gmbh
• Sabic Innovative Plastics B V
• Trumpf Laser & Systemtechnik Gmbh
• Daimler Ag
• Trumpf Laser—und Systemtechnik GmbH

Inventors

• Kose Kim
• Ohnimus Stephan
• Minkow Michael
• Ott Harald
• Näck Alexander
• Gaugler Jan
• Klink Holger
• Eggers Fred
• Hoffmann Leo
• Doggen Gerardus
• Faisst Birgit

Classifications

• B23K2103/04

  Steel {or steel} alloys · CPC title

• B29K2705/00

  Use of metals, their alloys or their compounds, for preformed parts, e.g. for inserts · CPC title

• B29K2705/12

  Iron · CPC title

• B23K26/082

  Scanning systems, i.e. devices involving movement of the laser beam relative to the laser head · CPC title

• B23K26/352

  for surface treatment · CPC title