Inclined bed reactor permitting a small quantity of catalyst to be employed

Patent metadata

Field	Value
Publication number	US-10618022-B2
Application number	US-201615555260-A
Country	US
Kind code	B2
Filing date	Mar 2, 2016
Priority date	Mar 4, 2015
Publication date	Apr 14, 2020
Grant date	Apr 14, 2020

Abstract

The present invention describes a type of inclined bed reactor which permits a small quantity of catalyst to be employed. Application of the reactor to a regenerative reforming process.

First claim

The invention claimed is:

1. A reactor with an inclined gravitational flow of catalyst and with a transverse flow of feed, said reactor by comprising an outer conical wall ( 1 ) and an inner conical wall ( 2 ) substantially parallel to each other, the two conical walls being inclined at an angle alpha with respect to the vertical, the point of the cone optionally being directed towards the top or towards the bottom, and the catalyst being introduced into a distribution zone ( 4 ) via one or more introduction legs ( 8 ) and collected from the outlet of an inclined catalytic zone ( 3 ) via one or more evacuation legs ( 9 ), the outer ( 1 ) and inner ( 2 ) conical walls, the introduction legs ( 8 ), and the evacuation legs ( 9 ) being enclosed in a shell ( 5 ) comprising an upper hemispherical portion ( 10 ), a central cylindrical portion ( 11 ) and a lower hemispherical portion ( 12 ) and the feed being admitted into the interior of the shell ( 5 ) via an inlet pipe ( 6 ) located at the top of the upper hemispherical portion ( 10 ), and reaction effluents being evacuated via a lower pipe ( 7 ) located at the lower portion of the lower hemispherical portion ( 12 ).

2. The inclined gravitational flow reactor according to claim 1 , in which the distance separating the outer ( 1 ) and inner ( 2 ) conical walls is 50 to 200 mm.

3. The inclined gravitational flow reactor according to claim 1 , in which the angle alpha of inclination of the inclined catalytic reaction zone ( 3 ) is in the range 0° (excluded) to 70°, this angle alpha being with respect to the vertical.

4. The inclined gravitational flow reactor according to claim 1 , in which the height-to-diameter ratio is in the range 1 to 30, the height being defined as the sum of the heights of the distribution zone ( 4 ) and the inclined catalytic zone ( 3 ), and the diameter as that of the distribution zone ( 4 ).

5. The inclined gravitational flow reactor according to claim 1 , in which the distance separating the two conical walls defining the thickness of the inclined catalytic zone ( 3 ) does not vary by more than 1 cm between the upper portion and the lower portion of said catalytic zone.

6. The inclined gravitational flow reactor according to claim 1 , in which the catalyst distribution zone ( 4 ) is a vertical cylindrical zone with height H in the range 200 to 1500 mm.

7. A process for the catalytic reforming of a gasoline type cut using the reactor according to claim 1 , in which:
the feed enters the shell ( 5 ) by means of the inlet pipe ( 6 ) located approximately at the top of the upper hemispherical portion of the shell ( 5 ),
the feed passes through the inclined catalytic zone ( 3 ) and the effluents resulting from the catalytic reaction are collected in the lower pipe ( 7 ) located approximately at the center of the lower hemispherical portion of the shell ( 5 ),
the catalyst is admitted into the distribution zone ( 4 ) via the introduction legs ( 8 ), flows under gravity through the inclined catalytic zone ( 3 ) and is then evacuated via the central outlet leg or legs ( 9 ).

8. The process for the catalytic reforming of a gasoline type cut according to claim 7 , in which the HSV (ratio of the mass flow rate of feed to the weight of catalyst) is more than 50 h −1 .

9. The process for the catalytic reforming of a gasoline type cut according to claim 7 , in which the feed has a paraffins content of up to 70% by weight.

10. The process for the catalytic reforming of a gasoline type cut according to claim 7 , in which the feed is entirely paraffinic.

11. The process for the catalytic reforming of a gasoline type cut according to claim 7 , conducted at operating conditions as follows:
an inlet temperature for each reactor in the range 480° C. to 550° C.,
a pressure for each reactor in the range 0.9 to 0.5 MPa (1 MPa=10 6 Pa).

12. The process for the catalytic reforming of a gasoline type cut, in which a reactor is placed at the head of the a series of reactors in which catalytic reforming occurs, said reactor placed at the head of the series having a inclined gravitational flow of catalyst and with a transverse flow of feed, said reactor being constituted by an outer conical wall ( 1 ) and an inner conical wall ( 2 ) substantially parallel to each other, the two conical walls being inclined at an angle alpha with respect to the vertical, the point of the cone possibly being directed towards the top or towards the bottom, and the catalyst being introduced into the distribution zone ( 4 ) via one or more introduction legs ( 8 ) and collected from the outlet of the inclined catalytic zone ( 3 ) via one or more evacuation legs ( 9 ), the outer ( 1 ) and inner ( 2 ) conical walls, the introduction legs ( 8 ), and the evacuation legs ( 9 ) is enclosed in a shell ( 5 ) comprising an upper hemispherical portion ( 10 ), a central cylindrical portion ( 11 ) and a lower hemispherical portion ( 12 ) and the feed being admitted into the interior of the shell ( 5 ) via an admission inlet pipe ( 6 ) located at the top of the upper hemispherical portion ( 10 ), and the reaction effluents being evacuated via a lower pipe ( 7 ) located at the lower portion of the lower hemispherical portion ( 12 ).

Assignees

• Ifp Energies Now

Inventors

• Fernandes Joana
• Gornay Julien
• Pagot Alexandre
• Lambert Fabian
• Martin Pierre-Yves
• Pierre Christophe
• Sala Francois

Classifications

• B01J2219/1946

  conical · CPC title

• C10G35/04

  Catalytic reforming · CPC title

• B01J8/12 Primary

  moved by gravity in a downward flow · CPC title

• B01J2219/185

  vertical · CPC title

• B01J19/24

  Stationary reactors without moving elements inside (B01J19/08, B01J19/26 take precedence; with stationary particles B01J8/02) · CPC title