Method of mixing rubber composition and system for mixing rubber composition

Patent metadata

Field	Value
Publication number	US-10618017-B2
Application number	US-201515501809-A
Country	US
Kind code	B2
Filing date	Jul 21, 2015
Priority date	Aug 5, 2014
Publication date	Apr 14, 2020
Grant date	Apr 14, 2020

Abstract

A method of mixing a rubber composition includes a carbon introduction step and a uniform dispersion step. In the carbon introduction step, on the basis of a deviation between a rate of temperature increase of the rubber mixture (R) and a target value, at least one of a ram pressure (Pr) and a rotational speed (N) of the mixing rotor (2) is PID controlled so that the ultimate temperature of the rubber mixture (R) at the conclusion of the step is within a tolerance range. In the uniform dispersion step, the ram pressure (Pr) or the rotational speed (N) of the mixing rotor (2) is adjusted to reduce a deviation between a value based on successively detected data associated with a predetermined control target and a target value.

First claim

The invention claimed is:

1. A method of mixing a rubber composition, comprising the steps of:
introducing carbon into a raw rubber by mixing the raw rubber and the carbon with a sealed mixer via a plurality of steps of a carbon introduction step; and
uniformly dispersing the introduced carbon throughout the raw rubber via a plurality of steps of a uniform dispersion step, wherein
in one of the steps of the carbon introduction step, once an integrated amount of power needed to drive a mixing rotor of the sealed mixer in rotation reaches a target integrated amount of power preset for the one of the steps of the carbon introduction step, a next step of the carbon introduction step is initiated, and
in one of the steps of the uniform dispersion step, once an integrated amount of power needed to drive the mixing rotor in rotation reaches a target integrated amount of power preset for the one of the steps of the uniform dispersion step, a next step of the uniform dispersion step is initiated, and in one of the steps of the uniform dispersion step, a ram pressure of the sealed mixer or a rotational speed of the mixing rotor is adjusted to reduce a deviation between a value based on successively detected data associated with a predetermined control target and a target value based on preset detected data, to produce a rubber composition containing the mixed raw rubber and the carbon; wherein
in the carbon introduction step, a temperature of a rubber mixture containing the raw rubber and the carbon is successively detected and a rate of temperature increase is calculated, and
on a basis of a deviation between the calculated rate of temperature increase and a preset target rate of temperature increase, at least one of the ram pressure and the rotational speed of the mixing rotor is PID controlled so that an ultimate temperature of the rubber mixture at a conclusion of the carbon introduction step is within a preset tolerance range.

2. The method of mixing a rubber composition according to claim 1 , wherein as data for the calculated rate of temperature increase, averaged data obtained from a moving average over a predetermined averaging period of time of data sampled in predetermined periods is used.

3. The method of mixing a rubber composition according to claim 2 , wherein the mixing rotor includes two mixing rotors disposed in an opposing manner, and the predetermined period for sampling is set on a basis of a rotational speed N (rpm) of at least one of the mixing rotors.

4. The method of mixing a rubber composition according to claim 3 , wherein the predetermined period T is set by Expression (1) below, where N 1 and N 2 are the rotational speeds N (rpm) of the two mixing rotors (N 1 ≥N 2 ), and T (ms) is the predetermined period;
T ≤(5/3)· N 2  (1).

5. The method of mixing a rubber composition according to claim 3 , wherein the averaging period of time for sampling is set on a basis of form, the rotational speed N (rpm), and rotational speed ratio of the two mixing rotors.

6. The method of mixing a rubber composition according to claim 5 , wherein the rotational speeds N (rpm) of the two mixing rotors are equal, and the averaging period of time Ts is set by Expression (2) below, where s (rotation) is a rotation amount of the mixing rotors needed for blades of the mixing rotors to return to a same mutual circumferential positional relationship with their surroundings;
Ts=s ·(60 /N )  (2).

7. The method of mixing a rubber composition according to claim 5 , wherein the rotational speed N of the two mixing rotors are different speeds N 1 and N 2 (N 1 ≠N 2 ), and the averaging period of time Ts is set by Expression (3), where v is a rotational speed ratio N 2 /N 1 of a relatively great rotational speed over a relatively low rotational speed, Ts (s) is the averaging period of time, and s (rotation) is a rotation amount of the mixing rotors needed for blades of the mixing rotors to return to a same mutual circumferential positional relationship with their surroundings when the rotational speed N (rpm) of the mixing rotors is equal;
Ts=s ·(1/( v− 1))·(60/ N 2 )  (3).

8. The method of mixing a rubber composition according to claim 2 , wherein a predetermined period for sampling is from 10 to 100 Hz.

9. The method of mixing a rubber composition according to claim 2 , wherein the averaging period of time is from 0.1 to 10 seconds.

10. The method of mixing a rubber composition according to claim 1 , wherein the predetermined control target is an amount of variation over time of a temperature of a mixing chamber of the mixer or a current value needed to drive the mixing rotor in rotation, and the ram pressure or the rotational speed of the mixing rotor is adjusted to reduce a deviation between a measurement value of the control target and a target value.

11. The method of mixing a rubber composition according to claim 1 , wherein the target rate of temperature increase is set on a basis of a heat balance of the sealed mixer in the carbon introduction step.

12. The method of mixing a rubber composition according to claim 11 , wherein heat generated from the rubber mixture containing the raw rubber and the carbon upon the rubber mixture being mixed by the mixing rotor, heat absorbed by a cooling fluid for cooling the sealed mixer, and heat dissipated from the rubber mixture are taken into account for the heat balance.

13. A system for mixing a rubber composition, the system comprising:
a sealed mixer configured to mix raw rubber and carbon;
a control device configured to control mixing operations of the sealed mixer, wherein
a carbon introduction step, in which the carbon is introduced into the raw rubber, and a uniform dispersion step, in which the introduced carbon is uniformly dispersed throughout the raw rubber, each include a plurality of steps, and
control is performed in one of the steps of the carbon introduction step, so that once an integrated amount of power needed to drive a mixing rotor of the sealed mixer in rotation reaches a target integrated amount of power preset for the one of the steps of the carbon introduction step, a next step of the carbon introduction step is initiated, and
control is performed in one of the steps of the uniform dispersion step, so that once an integrated amount of power needed to drive the mixing rotor in rotation reaches a target integrated amount of power preset for the one of the steps of the uniform dispersion step, a next step of the uniform dispersion step is initiated, and control is performed in one of the steps of the uniform dispersion step, so that a ram pressure of the sealed mixer or a rotational speed of the mixing rotor is adjusted to reduce a deviation between a value based on successively detected data associated with a predetermined control target and a target value based on preset detected data, to produce a rubber composition containing the mixed raw rubber and the carbon; and
a temperature sensor configured to successively detect a temperature of a rubber mixture containing the raw rubber and the carbon in the carbon introduction step, wherein data detected by the temperature sensor is input into the control device and a rate of temperature increase of the rubber mixture is calculated, and
on a basis of a deviation between a calculated rate of temperature increase and a preset target rate of temperature increase, at least one of the ram pressure and the rotational speed of the mixing rotor is PID controlled so that an ultimate temperature of the rubber mixture at conclusion of the carbon introduction step is within a preset tolerance range.

14. The system for mixing a

Assignees

• Yokohama Rubber Co Ltd

Inventors

• Ozawa Osamu

Classifications

• B29B7/7495

  for mixing rubber · CPC title

• C08L9/02

  Copolymers with acrylonitrile · CPC title

• B29B7/186 Primary

  Rotors therefor · CPC title

• B29B7/286

  measuring properties of the mixture, e.g. temperature, density (B29B7/283 takes precedence) · CPC title

• B29B7/283

  measuring data of the driving system, e.g. torque, speed, power · CPC title