Coated articles having high kNOx/kSOx ratios for selective catalytic reduction

Patent metadata

Field	Value
Publication number	US-10618000-B2
Application number	US-201715694051-A
Country	US
Kind code	B2
Filing date	Sep 1, 2017
Priority date	Jun 2, 2014
Publication date	Apr 14, 2020
Grant date	Apr 14, 2020

Abstract

Articles comprising a catalyst film comprising VOx, MoO3 or WO3, and TiO2 deposited on a substrate are disclosed. The articles are useful for selective catalytic reduction (SCR) of NOx in exhaust gases. Methods for producing such articles deposit a catalyst film on the substrate to form a coated substrate, which is then calcined. When used in an SCR process, the coated articles have enhanced activity for NOx conversion, reduced activity for SOx conversion, or both. Light-weight, coated articles having high catalyst loads can be fabricated at the same or reduced dimensions when compared with laminated articles, and increased kNOx/kSOx ratios are available even from coated articles having relatively thin catalyst films. The articles should have particular value for power plant operations, where coal and high-sulfur fuels are commonly used and controlling sulfur trioxide generation is critical.

First claim

We claim:

1. A method of producing an article for catalyzing the conversion of nitrogen oxides in a gas containing nitrogen oxides (NOx) and a reductant, which article comprising:
(i) a substrate; and
(ii) a catalyst film deposited on the substrate, wherein the catalyst film comprises VO x , MoO 3 or WO 3 , and TiO 2 ,

the method comprising forming the catalyst film on the substrate by:
(a) spray coating the substrate with a washcoat suspension comprising:
(A) (i) VO x or a VO x precursor,
(ii) MoO 3 , a MoO 3 precursor, WO 3 , a WO 3 precursor or a mixture thereof, and
(iii) TiO 2 or a TiO 2 precursor,

(B) an additive; and
(C) water,

wherein a solids content in the washcoat suspension is within the range of from 30 to 40 wt. % and the water in the washcoat suspension is within the range of from 60 to 70 wt. %, each relative to the total weight of the washcoat suspension; and
(b) calcining the coated substrate;
wherein the catalyst film comprises catalysts solids comprising:
VO x , in a range of from 0.5 to 2 wt. %;
MoO 3 , WO 3 , or a mixture thereof, in a range of from 1 to 10 wt. %; and
TiO 2 , in a range of from 88 to 98 wt. %,
each wt. % of the catalyst solids being relative to the total weight of the catalyst film.

2. The method according to claim 1 , wherein the substrate is a used catalyst on the substrate and the method comprises the additional step preceding step (a) of removing particulates from the substrate and the used catalyst on the substrate.

3. The method according to claim 1 , wherein the catalyst film has a thickness of from about 20 μm to about 500 μm.

4. The method according to claim 1 , wherein the substrate is a monolith or a plate.

5. The method according to claim 1 , wherein the substrate is perforated.

6. The method according to claim 1 , wherein the substrate comprises steel.

7. The method according to claim 1 , wherein calcining the coated substrate is performed at a temperature within the range of from 400° C. to 1200° C.

8. The method according to claim 1 , wherein the additive is selected from the group consisting of glass particles, alumina, silica, silica-aluminas, ceramics, molecular sieves, zeolites, clays, inorganic oxides, minerals and polymers.

9. The method according to claim 1 , wherein the catalyst film comprises catalyst solids in a range of from 50 to 99 wt. % of the catalyst film and the additives in a range of from 1 to 50 wt. % of the catalyst film.

10. An article obtained according to the method of claim 1 , wherein the article also catalyzes the conversion of SO x in a gas containing the NO x and the SO x and the conversions of NO x and SO x occur at rates kNO x and kSO x , respectively, and the ratio of kNO x /kSO x is in a range of from 0.22 to 0.35.

11. A process for selectively reducing nitrogen oxides in a gaseous mixture, the process comprising contacting a gaseous mixture comprising nitrogen oxides with a reductant in the presence of the article of claim 10 .

12. The process of claim 11 , wherein the step of contacting a gaseous mixture comprising nitrogen oxides with a reductant is performed at a temperature within the range of from 100° C. to 650° C.

13. The method of claim 1 , wherein the catalyst film has a thickness of from about 50 μm to about 150 μm.

14. The process of claim 11 , wherein the reductant is ammonia.

15. The article of claim 10 , wherein the ratio of kNO x /kSO x is in a range of from 0.222 to 0.30.

16. The method of claim 1 , wherein the substrate is heated before spray coating the substrate with the washcoat suspension.

Assignees

• Johnson Matthey Plc

Inventors

• Andersen Paul Joseph
• Brandmair Maria
• Clave Silvia Alcove
• Foo Rodney
• Gomersall Bruce
• Nash Michael
• Wagland Alison Mary

Classifications

• B01D2255/9202

  Linear dimensions · CPC title

• B01D53/8628 Primary

  Processes characterised by a specific catalyst · CPC title

• B01D53/88

  Handling or mounting catalysts · CPC title

• B01J37/0244

  Coatings comprising several layers · CPC title

• B01J37/0215

  Coating · CPC title