Lithium ion battery including lithium ion-exchanged zeolite particles

Patent metadata

Field	Value
Publication number	US-10615461-B2
Application number	US-201715447355-A
Country	US
Kind code	B2
Filing date	Mar 2, 2017
Priority date	Mar 2, 2017
Publication date	Apr 7, 2020
Grant date	Apr 7, 2020

Abstract

An electrochemical cell of a secondary lithium ion battery includes lithium ion-exchanged zeolite particles or “lithiated zeolite particles” positioned along at least a portion of a lithium ion transport path through the electrochemical cell. The lithiated zeolite particles may be positioned within the lithium ion transport path through the electrochemical cell, for example, by being distributed throughout an electrolyte disposed between confronting anterior surfaces of a negative electrode and a positive electrode. Additionally or alternatively, the lithiated zeolite particles may be positioned within the lithium ion transport path through the electrochemical cell by being distributed throughout or deposited as a coating layer on the negative electrode, the positive electrode, and/or a porous separator sandwiched between the confronting anterior surfaces of the negative and positive electrodes.

First claim

What is claimed is:

1. An electrochemical cell for a secondary lithium ion battery comprising:
a negative electrode;
a positive electrode spaced apart from the negative electrode;
an electrolyte infiltrating the negative electrode and the positive electrode and disposed between confronting anterior surfaces of the negative electrode and the positive electrode;
a lithium ion transport path extending through the negative electrode, the positive electrode, and the electrolyte; and
lithiated zeolite particles positioned along at least a portion of the lithium ion transport path,
wherein the electrolyte comprises a liquid electrolyte solution including a lithium salt dissolved in a nonaqueous, aprotic organic solvent,
wherein at least a portion of the lithiated zeolite particles are suspended in or mixed with the liquid electrolyte solution, and
wherein the lithiated zeolite particles comprise particles of a dehydrated zeolite material exhibiting an Si:Al ratio of greater than 5:1 and having a framework type selected from the group consisting of: ASV, BEA, CFI, CON, DDR, DOH, DON, ESV, EUO, FER, GON, IFR, ISV, ITE, LEV, MEL, MEP, MFI, MFS, MSO, MTF, MTN, MTT, MTW, MWW, NON, NES, RSN, RTE, RTH, RUT, SFE, SFF, SGT, SOD, STF, STT, TER, TON, VET, VNI, and VSV, and wherein the lithiated zeolite particles are formulated to trap or inhibit movement of at least one of water molecules, hydrogen ions, hydrofluoric acid, or transition metal ions.

2. The electrochemical cell set forth in claim 1 including a porous separator disposed between the confronting anterior surfaces of the negative electrode and the positive electrode and infiltrated with the liquid electrolyte solution.

3. The electrochemical cell set forth in claim 2 wherein the porous separator comprises at least one polyolefin selected from the group consisting of polyethylene (PE), polypropylene (PP), polyamide (PA), poly(tetrafluoroethylene) (PTFE), polyvinylidine fluoride (PVdF), or poly(vinyl chloride) (PVC).

4. The electrochemical cell set forth in claim 2 wherein the porous separator includes a first side that faces toward the negative electrode and an opposite second side that faces toward the positive electrode, and wherein at least a portion of the lithiated zeolite particles are applied to the first side or the second side of the porous separator in the form of a coating layer.

5. The electrochemical cell set forth in claim 4 wherein the coating layer formed on the first side or the second side of the porous separator has a thickness of less than 5 micrometers.

6. The electrochemical cell set forth in claim 2 wherein the separator has a layered structure and comprises a first layer and a second layer adjacent the first layer, wherein the first layer and the second layer are laminated together, and wherein at least a portion of the lithiated zeolite particles are distributed along an interface between confronting surfaces of the first and second layers.

7. The electrochemical cell set forth in claim 1 wherein at least a portion of the lithiated zeolite particles are distributed throughout the negative electrode, the positive electrode, or both the negative and positive electrodes, wherein the negative electrode and the positive electrode each comprise a lithium ion intercalation host material, and wherein at least a portion of the lithiated zeolite particles are mixed with the lithium ion intercalation host material of the negative electrode, the positive electrode, or both the negative and positive electrodes.

8. The electrochemical cell set forth in claim 1 wherein at least a portion of the lithiated zeolite particles are coated in the form of a coating layer on the anterior surface of the negative electrode, on the anterior surface of the positive electrode, or on both the anterior surfaces of the negative and positive electrodes.

9. The electrochemical cell set forth in claim 1 including a negative electrode current collector adjacent the negative electrode and a positive electrode current collector adjacent the positive electrode, wherein at least a portion of the lithiated zeolite particles are coated in the form of a coating layer on a surface of the negative electrode current collector or the positive electrode current collector, or on surfaces of both the negative and positive electrode current collectors.

10. A secondary lithium ion battery including a plurality of the electrochemical cells set forth in claim 1 , wherein the electrochemical cells are connected in a series or parallel arrangement.

11. The electrochemical cell set forth in claim 1 wherein the lithiated zeolite particles have a mean particle diameter in the range of 5 nanometers to 10 micrometers.

12. The electrochemical cell set forth in claim 1 wherein the lithiated zeolite particles constitute, by weight, 1% to 10% of the liquid electrolyte solution.

13. The electrochemical cell set forth in claim 1 wherein the lithium salt comprises at least one of LiClO 4 , LiAlCl 4 , LiI, LiBr, LiSCN, LiBF 4 , LiB(C 6 H 5 ) 4 , LiAsF 6 , LiCF 3 SO 3 , LiN(CF 3 SO 2 ) 2 , or LiPF 6 , and wherein the nonaqueous, aprotic organic solvent comprises at least one of a cyclic carbonate, an acyclic carbonate, an aliphatic carboxylic ester, a γ-lactone, an acyclic ether, or a cyclic ether.

14. The electrochemical cell set forth in claim 1 wherein the lithiated zeolite particles comprise particles of a dehydrated zeolite material classified under framework type code MFI, and wherein the dehydrated zeolite material comprises ZSM-5.

Assignees

• Gm Global Tech Operations Llc

Inventors

• Xiao Xingcheng
• Zeng Sherman H
• Cai Mei
• Verbrugge Mark W

Classifications

• H01M10/0565

  Polymeric materials, e.g. gel-type or solid-type · CPC title

• H01M2300/0082

  Organic polymers · CPC title

• H01M10/0568

  characterised by the solutes · CPC title

• H01M2300/0028

  characterised by the solvent · CPC title

• H01M10/0525 Primary

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title