Membrane made of a blend of UHMW polyolefins

Patent metadata

Field	Value
Publication number	US-10615388-B2
Application number	US-38661206-A
Country	US
Kind code	B2
Filing date	Mar 22, 2006
Priority date	Mar 22, 2006
Publication date	Apr 7, 2020
Grant date	Apr 7, 2020

Abstract

A membrane is a microporous sheet made of a blend of a first ultra high molecular weight polyolefin and a second ultra high molecular weight polyolefin. Each polyolefin has a molecular weight, both of those molecular weights are greater than 1 million, and one molecular weight is greater than the other. Additionally, the intrinsic viscosity (IV) of the membrane may be greater than or equal to 6.3.

First claim

We claim:

1. A membrane comprises:
an extruded, wet processed microporous sheet consisting essentially of a first ultra high molecular weight polyethylene having a first molecular weight, as measured by intrinsic viscosity (IV), in a range of 7<IV<15 and a second ultra high molecular weight polyethylene having a second molecular weight, as measured by intrinsic viscosity (IV), in a range of IV>15, said first molecular weight and said second molecular weight being greater than 1 million and being different from one another, the microporous sheet having a thickness in a range of 10-25 microns and interconnected spherical and/or elliptical pores, and characteristics selected from the group consisting of: a porosity between 25 and 85%; a puncture strength of greater than 300 gr-force/mil (25 microns); a MacMullin Number between 6-15; a Gurley Number of less than 60 sec/10 cc/mil; and combinations thereof.

2. The membrane of claim 1 where said microporous sheet having a porosity ranging from 32 to 58%.

3. The membrane of claim 1 where said microporous sheet having an average pore size between 0.01 to 0.5 microns.

4. The membrane of claim 1 where said microporous sheet further consisting of a viscoelastic lubricant (VEL), said VEL being selected from the group consisting of: fatty acid esters, ethoxylated fatty acid esters, glycol esters, PEG esters, glycerol esters, ethoxylated esters, sorbitol esters, ethoxylated sorbitol esters, aromatic ethoxylates, alcohol ethoxylates, mercaptan ethoxylates, modified ethoxylates, amide surfactants, phosphate esters, phosphonate esters, phosphite esters, alkyl sulfates, fatty acid ethers, alkyl ether sulfates, alkylaryl ether sulfates, sulfonates, naphthalene sulfonates, sulfosuccinates, sulfonated esters, sulfonated amides, alkyl ether carboxylates, alkylaryl ether carboxylates, quaternary amines, amino quaternary amines, ethoxylated amines, imidazoline derivatives, betaines, sultaines, aminopropionate, catechol derivatives, saturated fatty acids, unsaturated fatty acids, and combinations thereof.

5. The membrane of claim 1 wherein the microporous sheet further comprises a third polyolefin with a molecular weight of less than 0.5×10 6 .

6. The membrane of claim 1 wherein said sheet being made of a solution including said first ultra high molecular weight polyethylene, said second ultra high molecular weight polyethylene, and a hydrocarbon liquid or some other substance which is at least partially extracted by a volatile solvent.

7. A battery separator comprising the membrane of claim 1 .

8. A membrane comprises an extruded, wet processed microporous sheet being made of a solution of a first ultra high molecular weight polyethylene having a first molecular weight, as measured by intrinsic viscosity (IV), in a range of 7<IV<15 and a second ultra high molecular weight polyethylene having a second molecular weight, as measured by intrinsic viscosity (IV), in a range of IV>15, said first molecular weight and said second molecular weight being greater than 1 million and being different from one another, the microporous sheet having a thickness in a range of 10-25 microns, an average pore size consisting of a range of 0.01-0.5 microns, and interconnected spherical and/or elliptical pores, and characteristics selected from the group consisting of: a porosity between 25 and 85%; a puncture strength of greater than 300 gr-force/mil (25 microns); a MacMullin Number between 6-15; a Gurley Number of less than 60 sec/10 cc/mil; and combinations thereof.

9. The membrane of claim 8 wherein the membrane having an intrinsic viscosity greater than or equal to 6.3.

10. The membrane of claim 9 wherein said intrinsic viscosity being greater than or equal to 7.7.

11. The membrane of claim 8 wherein the microporous sheet further consisting of a viscoelastic lubricant (VEL), said VEL being selected from the group consisting of: fatty acid esters, ethoxylated fatty acid esters, glycol esters, PEG esters, glycerol esters, ethoxylated esters, sorbitol esters, ethoxylated sorbitol esters, aromatic ethoxylates, alcohol ethoxylates, mercaptan ethoxylates, modified ethoxylates, amide surfactants, phosphate esters, phosphonate esters, phosphite esters, alkyl sulfates, fatty acid ethers, alkyl ether sulfates, alkylaryl ether sulfates, sulfonates, naphthalene sulfonates, sulfosuccinates, sulfonated esters, sulfonated amides, alkyl ether carboxylates, alkylaryl ether carboxylates, quaternary amines, amino quaternary amines, ethoxylated amines, imidazoline derivatives, betaines, sultaines, aminopropionate, catechol derivatives, saturated fatty acids, unsaturated fatty acids, and combinations thereof.

12. The membrane of claim 8 wherein said solution also includes a hydrocarbon liquid or some other substance which is at least partially extracted by a volatile solvent.

13. The membrane of claim 8 wherein the microporous sheet further comprises a third polyolefin with a molecular weight of less than 0.5×10 6 .

14. A battery separator comprising the membrane of claim 8 .

15. A lithium battery comprising: a membrane of an extruded, wet processed microporous sheet being made of a solution of a first ultra high molecular weight polyethylene having a first molecular weight, as measured by intrinsic viscosity (IV), in a range of 7<IV<15 and a second ultra high molecular weight polyethylene having a second molecular weight, as measured by intrinsic viscosity (IV), in a range of IV>15, said first molecular weight and said second molecular weight being greater than 1 million and being different from one another, the microporous sheet having a thickness in a range of 10-25 microns, an average pore size consisting of a range of 0.01-0.5 microns, interconnected spherical and/or elliptical pores, and characteristics selected from the group consisting of: a porosity between 25 and 85%; a puncture strength of greater than 300 gr-force/mil (25 microns); a MacMullin Number between 6-15; a Gurley Number of less than 60 sec/10 cc/mil; and combinations thereof.

16. The membrane of claim 15 wherein the microporous sheet further comprises a third polyolefin with a molecular weight of less than 0.5×10 6 .

17. A lithium battery comprising: a membrane of an extruded, wet processed microporous sheet consisting essentially of a first ultra high molecular weight polyethylene having a first molecular weight, as measured by intrinsic viscosity (IV), in a range of 7<IV<15 and a second ultra high molecular weight polyethylene having a second molecular weight, as measured by intrinsic viscosity (IV), in a range of IV>15, said first molecular weight and said second molecular weight being greater than 1 million and being different from one another, the microporous sheet having a thickness in a range of 10-25 microns, interconnected spherical and/or elliptical pores, and characteristics selected from the group consisting of: a porosity between 25 and 85%; a puncture strength of greater than 300 gr-force/mil (25 microns); a MacMullin Number between 6-15; a Gurley Number of less than 60 sec/10 cc/mil; and combinations thereof.

18. The membrane of claim 17 wherein the microporous sheet further comprises a third polyolefin with a molecular weight of less than 0.5×10 6 .

Assignees

• Simmons Donald K
• Yaritz Joseph G
• Celgard Llc

Inventors

• Simmons Donald K
• Yaritz Joseph G

Classifications

• B29K2023/0683

  UHMWPE, i.e. ultra high molecular weight polyethylene · CPC title

• B29C48/00

  Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor (extrusion blow-moulding B29C49/04) · CPC title

• B29L2031/755

  Membranes, diaphragms · CPC title

• B29C48/08

  flexible, e.g. films · CPC title

• H01M10/0565

  Polymeric materials, e.g. gel-type or solid-type · CPC title