Methods of forming structures and fissile fuel materials by additive manufacturing

Patent metadata

Field	Value
Publication number	US-10614923-B2
Application number	US-201715653258-A
Country	US
Kind code	B2
Filing date	Jul 18, 2017
Priority date	Jul 19, 2016
Publication date	Apr 7, 2020
Grant date	Apr 7, 2020

Abstract

A method of forming one or more structures by additive manufacturing comprises introducing a first layer of a powder mixture comprising graphite and a fuel on a surface of a substrate. The first layer is at least partially compacted and then exposed to laser radiation to form a first layer of material comprising the fuel dispersed within a graphite matrix material. At least a second layer of the powder mixture is provided over the first layer of material and exposed to laser radiation to form inter-granular bonds between the second layer and the first layer. Related structures and methods of forming one or more structures are also disclosed.

First claim

What is claimed is:

1. A method of forming a fissile fuel structure by additive manufacturing, the method comprising:
introducing a first layer of a powder mixture comprising graphite and a fuel on a surface of a substrate, the powder mixture comprising a higher weight percent of graphite than of the fuel;
at least partially compacting the first layer;
exposing the first layer of the powder mixture to laser radiation to form a first layer of material comprising the fuel dispersed within a graphite matrix material;
forming a second layer of the powder mixture over the first layer of material; and
exposing the second layer of the powder mixture to laser radiation to form a second layer of material comprising the fuel dispersed within a graphite matrix material and to form inter-granular bonds between the second layer and the first layer.

2. The method of claim 1 , further comprising selecting the powder mixture such that graphite constitutes between about 97.0 weight percent and about 99.9 weight percent of the powder mixture.

3. The method of claim 1 , further comprising selecting the powder mixture to comprise graphite and a uranium-containing material.

4. The method of claim 1 , further comprising selecting the powder mixture to consist essentially of graphite and a uranium oxide.

5. The method of claim 1 , further comprising selecting the fuel to comprise uranium oxide particles coated with graphite.

6. The method of claim 1 , further comprising selecting the powder mixture to comprise a graphite to total carbon ratio of about 1.0:1.0.

7. The method of claim 1 , wherein exposing the first layer and the second layer of the powder mixture to laser radiation comprises exposing at least one of the first layer and the second layer to defocused laser radiation.

8. The method of claim 1 , further comprising selecting the fuel to comprise uranium silicide, uranium carbide, or a combination thereof.

9. The method of claim 1 , further comprising providing a powder of a cladding material substantially around a circumference of at least one of the first layer of the powder mixture and the second layer of the powder mixture and exposing the powder of the cladding material to laser radiation.

10. The method of claim 1 , wherein exposing the first layer and the second layer of the powder mixture to laser radiation comprises exposing the first layer and the second layer to the laser radiation in an inert atmosphere.

11. The method of claim 1 , further comprising moving the substrate away from the laser prior to forming the second layer of the powder mixture over the first layer of material.

12. The method of claim 1 , wherein introducing a first layer of a powder mixture comprising graphite and a fuel on a surface of a substrate comprises forming the first layer of the powder mixture to a thickness between about 0.1 mm and about 5.0 mm.

13. The method of claim 1 , further comprising providing a dopant to the powder mixture at a concentration between about 1 ppb and about 1,000 ppb.

14. The method of claim 1 , wherein exposing the first layer to laser radiation comprises exposing the first layer to laser radiation after at least partially compacting the first layer of the powder mixture.

15. The method of claim 1 , further comprising heating the substrate prior to introducing the first layer of the powder mixture on the surface of the substrate.

16. A method of forming a structure, the method comprising:
providing a substrate within an enclosure;
disposing a powder on the substrate, disposing the powder on the substrate comprising forming a powder layer comprising a varying composition at different cross-sectional locations of the powder layer on the substrate;
exposing the powder on the substrate to defocused laser radiation to form a first layer of a structure;
disposing additional powder over the first layer; and
exposing the additional powder over the first layer to defocused laser radiation.

17. The method of claim 16 , further comprising selecting the powder to comprise a matrix material and at least another material.

18. The method of claim 17 , further comprising selecting the matrix material to comprise graphite.

19. The method of claim 18 , further comprising selecting the at least another material to comprise particles of a uranium-containing material coated with graphite.

20. The method of claim 17 , further comprising selecting the powder to comprise a carbon to uranium ratio between about 700:1 and about 10,000:1.

21. The method of claim 16 , further comprising adding at least one dopant selected from the group consisting of nanotubes and zirconium to the powder.

22. The method of claim 16 , wherein disposing a powder on the substrate comprises disposing the powder on the substrate from a single powder delivery nozzle.

23. The method of claim 16 , wherein disposing a powder on the substrate comprises disposing a matrix material from a first powder delivery nozzle and disposing at least another material from a second powder delivery nozzle on the substrate.

24. The method of claim 16 , further comprising selecting a duration of time that the powder is exposed to the defocused laser radiation based on one or more of a particle size of the powder, a composition of the powder, or a spot size of the defocused laser radiation.

25. The method of claim 16 , wherein forming a powder layer comprising a varying composition at different cross-sectional locations of the powder layer comprises forming a first composition at internal locations of the powder layer and a second composition around a circumference of the first composition.

26. The method of claim 25 , further comprising selecting the first composition to comprise a fuel material and selecting the second composition to comprise a cladding material.

27. The method of claim 1 , wherein introducing a first layer of a powder mixture comprising graphite and a fuel on a surface of a substrate comprises introducing, on the surface of the substrate, a first layer of a powder mixture comprising graphite, a fuel, and at least one dopant selected from the group consisting of nanotubes, titanium, vanadium, chromium, iron, cobalt, nickel, copper, zinc, palladium, silver, tin, hafnium, tantalum, tungsten, platinum, gold, or lead.

28. The method of claim 1 , further comprising forming a third layer of a powder mixture over the second layer, the third layer of the powder mixture comprising one of a metal and a ceramic material.

29. The method of claim 1 , wherein exposing the first layer of the powder mixture to laser radiation comprises exposing the first layer of the powder to defocused laser radiation having a spot size between about 1 mm and about 10 mm.

30. The method of claim 1 , wherein exposing the second layer of the powder mixture to laser radiation to form a second layer of material comprising the fuel dispersed within a graphite matrix material and to form inter-granular bonds between the second layer and the first layer comprises forming the fissile fuel structure to have a porosity between about 0.01 and about 0.05.

31. The method of claim 1 , wherein introducing a first layer of a powder mixture comprising graphite and a fuel on a surface of a substrate comprises introducing, on the surface of the substrate, a first layer of a powder mixture having a

Assignees

• Battelle Energy Alliance Llc

Inventors

• Van Rooyen Isabella J
• Morrell Sean R

Classifications

• G21C3/62

  Ceramic fuel · CPC title

• B33Y10/00

  Processes of additive manufacturing · CPC title

• B29C64/268

  using laser beams; using electron beams [EB] · CPC title

• G21C21/02 Primary

  Manufacture of fuel elements or breeder elements contained in non-active casings · CPC title

• B28B1/001

  Rapid manufacturing of 3D objects by additive depositing, agglomerating or laminating of material (selective deposition modelling of metallic powder B22F10/00; rapid manufacturing of 3D objects in general and in particular of plastics B29C64/00) · CPC title