Dispersing additive for asphaltenes and its uses

Patent metadata

Field	Value
Publication number	US-10611972-B2
Application number	US-201615565660-A
Country	US
Kind code	B2
Filing date	Apr 7, 2016
Priority date	Apr 10, 2015
Publication date	Apr 7, 2020
Grant date	Apr 7, 2020

Abstract

Use of an alkylphenol-aldehyde resin modified by at least one alkylamine in a composition of crude oils or in a product derived from a composition of crude oils as dispersing additive for asphaltenes. Process for the treatment of a composition of crude oils or a derived product which makes it possible to prevent the precipitation of asphaltenes, in particular in crude oils and the products which result therefrom by refining and/or extraction processes. Bituminous compositions including an alkylphenol-aldehyde resin modified by at least one alkylamine.

First claim

The invention claimed is:

1. Method for dispersing asphaltenes and/or for at least one of preventing, delaying, stopping, and reducing the precipitation of asphaltenes comprised in a composition of crude oils, in a hydrocarbon fraction of crude oils comprising asphaltenes, or in a product selected from the group consisting of bituminous binders, bituminous mixes, and asphalts and comprising asphaltenes, said method comprising adding to said composition, said hydrocarbon fraction, or said product at least one modified alkylphenol-aldehyde resin, the modified alkylphenol-aldehyde resin being obtained by a Mannich reaction of an alkylphenol-aldehyde condensation resin with
at least one aldehyde and/or one ketone having from 1 to 8 carbon atoms;
and at least one hydrocarbon compound having at least one alkylamine group having between 1 and 30 carbon atoms,
the alkylphenol-aldehyde condensation resin being itself obtained by condensation
of at least one alkylphenol substituted by at least one linear or branched alkyl group having from 1 to 30 carbon atoms,
with at least one aldehyde and/or one ketone having from 1 to 8 carbon atoms.

2. Method according to claim 1 , wherein the composition of crude oils, the hydrocarbon fraction of crude oils comprising asphaltenes, or the product selected from the group consisting of bituminous binders, bituminous mixes, and asphalts and comprising asphaltenes is subjected to one or more of the following conditions:
a rise in pressure,
a rise in temperature,
a mixing with at least one other fluid.

3. Method according to claim 1 , wherein the modified alkylphenol-aldehyde resin is obtained from p-nonylphenol, formaldehyde and at least one hydrocarbon compound having at least one alkylmonoamine or alkylpolyamine group.

4. Method according to claim 1 , wherein the modified alkylphenol-aldehyde resin added to said composition, said hydrocarbon fraction, or said product is diluted in a solvent.

5. Method according to claim 1 , executed in an equipment selected from the group consisting of a tank, a refining plant, a pipeline, a drilling well, an item of transportation equipment, and a filter.

6. Method according to claim 1 , applied to a product derived from a composition of crude oils selected from the group consisting of bituminous binders, bituminous mixes and asphalts.

7. Method according to claim 1 , for reducing a preparation temperature and/or a processing temperature of the bituminous binder and/or for reducing a manufacturing, processing and/or compacting temperature during preparation of a bituminous mix and/or for reducing a manufacturing and/or a processing temperature during preparation of an asphalt.

8. Composition comprising asphaltenes chosen from: bitumen compositions, bituminous binders, bituminous mixes and asphalts,
the said composition comprising at least one modified alkylphenol-aldehyde resin capable of being obtained by a Mannich reaction of an alkylphenol-aldehyde condensation resin with
at least one aldehyde and/or one ketone having from 1 to 8 carbon atoms;
and at least one hydrocarbon compound having at least one alkylamine group having between 1 and 30 carbon atoms,

the said alkylphenol-aldehyde condensation resin being itself capable of being obtained by condensation
of at least one alkylphenol substituted by at least one linear or branched alkyl group having from 1 to 30 carbon atoms,
with at least one aldehyde and/or one ketone having from 1 to 8 carbon atoms.

9. Composition according to claim 8 , wherein the modified alkylphenol-aldehyde resin is obtained from at least one alkylmonoamine or from at least one alkylpolyamine having at least one primary amine group.

10. Composition according to claim 9 , wherein the modified alkylphenol-aldehyde resin is obtained from at least one alkylmonoamine or from at least one alkylpolyamine which all the amine groups are primary amines.

11. Composition according to claim 8 , wherein the alkylamine is a fatty alkylmonoamine having from 12 to 24 carbon atoms.

12. Composition according to claim 8 , wherein the alkylamine is a fatty alkylpolyamine having from 12 to 24 carbon atoms.

13. Composition according to claim 8 which is a bituminous binder comprising from 0.1 to 5% by weight of modified alkylphenol-aldehyde resin, with respect to the total weight of binder.

14. Composition according to claim 8 , which is a bituminous mix comprising from 1 to 10% by weight of bituminous binder, wherein the modified alkylphenol-aldehyde resin is obtained from at least one alkylmonoamine or from at least one alkylpolyamine having at least one primary amine group, and from 90 to 99% by weight of aggregates, with respect to the total weight of the mix.

15. Composition according to claim 8 , which is an asphalt comprising from 1 to 20% by weight of bituminous binder, wherein the modified alkylphenol-aldehyde resin is obtained from at least one alkylmonoamine or from at least one alkylpolyamine having at least one primary amine group, and from 80 to 99% of fillers, with respect to the total weight of the asphalt.

16. Method according to claim 1 , for the treatment of the composition of crude oils, the hydrocarbon fraction of crude oils comprising asphaltenes, or the product selected from the group consisting of bituminous binders, bituminous mixes and asphalts and comprising asphaltenes, said method comprising at least:
(i) introducing at least one modified alkylphenol-aldehyde resin into the composition of crude oils, the hydrocarbon fraction of crude oils comprising asphaltenes, or the product selected from the group consisting of bituminous binders, bituminous mixes and asphalts and comprising asphaltenes,
(ii) a treatment stage selected from the group consisting of a rise in pressure, a rise in temperature, and a mixing with at least one other fluid,
the modified alkylphenol-aldehyde resin being obtained by a Mannich reaction of an alkylphenol-aldehyde condensation resin with
at least one aldehyde and/or one ketone having from 1 to 8 carbon atoms;
and at least one hydrocarbon compound having at least one alkylamine group having between 1 and 30 carbon atoms,

the alkylphenol-aldehyde condensation resin being itself obtained by condensation
of at least one alkylphenol substituted by at least one linear or branched alkyl group having from 1 to 30 carbon atoms,
with at least one aldehyde and/or one ketone having from 1 to 8 carbon atoms.

17. Method according to claim 16 , wherein the treatment is carried out at any stage from recovery of the crude oils from a reservoir up to refining and use of the hydrocarbon fractions, via transportation of these different products.

18. Method according to claim 16 for the preparation of a bituminous binder, wherein the treatment stage (ii) comprises mixing the bitumen and the modified alkylphenol-aldehyde resin at a temperature of between 100° C. and 170° C.

19. Method according to claim 16 for the preparation of a bituminous mix, wherein the treatment stage (ii) comprises mixing the bituminous binder and aggregates at a temperature between 100° C. and 150° C.

20. Method according to claim 16 for the preparation of an asphalt, wherein the treatment stage (ii) comprises mixing the bituminous binder and fillers, at a temperature of between 140° C. and 180° C.

Assignees

• Total Marketing Services

Inventors

• Tort Frédéric
• Passade-Boupat Nicolas
• Rondon Marianna
• QUINTERO Carlos

Classifications

• C08L2555/80

  Macromolecular constituents · CPC title

• C08G8/28

  Chemically modified polycondensates · CPC title

• C10G75/04 Primary

  by addition of antifouling agents · CPC title

• C09K8/524

  organic depositions, e.g. paraffins or asphaltenes · CPC title

• C04B24/302

  Phenol-formaldehyde condensation polymers · CPC title