Curable composition, curable ink, method for forming two-dimensional or three-dimensional images, apparatus for forming two-dimensional or three-dimensional images, cured product, structural body, and processed product

Patent metadata

Field	Value
Publication number	US-10611920-B2
Application number	US-201715646718-A
Country	US
Kind code	B2
Filing date	Jul 11, 2017
Priority date	Jul 15, 2016
Publication date	Apr 7, 2020
Grant date	Apr 7, 2020

Abstract

A curable composition is provided. The curable composition comprises diethylene glycol dimethacrylate and a resin, and the following conditions (1) to (3) are satisfied:
(1) a mixed solution of 70 parts by mass of the diethylene glycol dimethacrylate and 30 parts by mass of the resin exhibits a viscosity 15 to 30 times that of the diethylene glycol dimethacrylate alone at 25° C.; (2) the mixed solution exhibits a spin-spin relaxation time of 240 ms or less measured by a CPMG method for pulse nuclear magnetic resonance analysis; and (3) the resin has a polystyrene or polyester structure.

First claim

The invention claimed is:

1. A curable composition, comprising:
diethylene glycol dimethacrylate; and
a resin having a polystyrene structure,

wherein:
the following conditions (1) to (2) are satisfied:
(1) a mixed solution of 70 parts by mass of the diethylene glycol dimethacrylate and 30 parts by mass of the resin exhibits a viscosity 15 to 30 times that of the diethylene glycol dimethacrylate alone at 25° C.; and
(2) the mixed solution exhibits a spin-spin relaxation time of 240 ms or less measured by a CPMG method for pulse nuclear magnetic resonance analysis;

the curable composition does not contain glycerol dimethacrylate; and
the curable composition does not contain an ethylene oxide-modified trimethylolpropane trimethacrylate.

2. The curable composition of claim 1 , further comprising:
a monofunctional acrylate or methacrylate having a cyclic ether structure.

3. The curable composition of claim 2 , wherein the monofunctional acrylate or methacrylate having a cyclic ether structure accounts for 10 to 30 parts by mass out of 100 parts mass of the diethylene glycol dimethacrylate, the resin, and the monofunctional acrylate or methacrylate having a cyclic ether structure in total.

4. The curable composition of claim 1 , wherein the resin accounts for 5 to 20 parts by mass out of 100 parts by mass of the diethylene glycol dimethacrylate and the resin in total.

5. The curable composition of claim 4 , wherein the resin accounts for 10 to 20 parts by mass out of 100 parts by mass of the diethylene glycol dimethacrylate and the resin in total.

6. The curable composition of claim 2 , wherein the resin accounts for 5 to 20 parts by mass out of 100 parts by mass of the diethylene glycol dimethacrylate, the resin, and the monofunctional acrylate or methacrylate having a cyclic ether structure in total.

7. The curable composition of claim 6 , wherein the resin accounts for 10 to 20 parts by mass out of 100 parts by mass of the diethylene glycol dimethacrylate, the resin, and the monofunctional acrylate or methacrylate having a cyclic ether structure in total.

8. The curable composition of claim 1 , further comprising:
a polymerization initiator.

9. A curable ink, comprising the curable composition of claim 1 .

10. An inkjet ink, comprising the curable ink of claim 9 .

11. A method for forming two-dimensional or three-dimensional images, the method comprising:
emitting an active energy ray to the curable composition of claim 1 .

12. The method for forming two-dimensional or three-dimensional images of claim 11 , further comprising:
discharging the curable composition,
wherein, in the emitting, the active energy ray is emitted to the curable composition discharged in the discharging.

13. The method for forming two-dimensional or three-dimensional images of claim 12 , wherein, in the discharging, the curable composition is discharged at a frequency of from 10 to 20 kHz.

14. An apparatus for forming two-dimensional or three-dimensional images, the apparatus comprising:
a storage storing the curable composition of claim 1 ; and
an emitter to emit an active energy ray.

15. A cured product produced by curing the curable composition of claim 1 .

16. A structural body, comprising:
a substrate; and
the cured product of claim 15 .

17. A processed product produced by processing the structural body of claim 16 .

18. The curable composition of claim 1 , wherein a mass ratio of the diethylene glycol dimethacrylate to the resin ranges from 50/20 to 95/5.

Assignees

• Matsushita Yuuki
• Iio Masato
• Ricoh Co Ltd

Inventors

• Matsushita Yuuki
• Iio Masato

Classifications

• B32B27/308

  comprising acrylic (co)polymers · CPC title

• C08F2/48

  by ultraviolet or visible light · CPC title

• C09D11/101 Primary

  Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing · CPC title

• B05C5/02

  {the liquid or other fluent material being discharged through an outlet orifice by pressure, e.g.} from an outlet device in contact or almost in contact, with the work · CPC title

• C09D11/30

  Inkjet printing inks · CPC title