Method for producing impregnated fiber structures

Patent metadata

Field	Value
Publication number	US-10611889-B2
Application number	US-201515501034-A
Country	US
Kind code	B2
Filing date	Jul 29, 2015
Priority date	Aug 1, 2014
Publication date	Apr 7, 2020
Grant date	Apr 7, 2020

Abstract

The invention relates to a process for the production of saturated fiber structures. The process includes (a) introduction of a fiber structure onto a conveyor belt; (b) application of a solution including monomer and optionally including activator, and optionally including catalyst in at least one line to the fiber structure; (c) passage of the fiber structure with the solution through at least one roll pair in which pressure is exerted on the fiber structure; and (d) cooling of the saturated fiber structure, so that the monomer solidifies.

First claim

The invention claimed is:

1. A process for the production of saturated fiber structures, the process comprising:
(a) placing a fiber structure onto a conveyor belt and moving the fiber structure on the conveyor belt in a direction of transport,
(b) applying a liquid mixture comprising a molten monomer to the fiber structure in a plurality of lines, each of the plurality of lines having an undulating or zigzag shape, wherein:
the plurality of lines comprises an even number of lines and the plurality of lines are applied with axial symmetry to the fiber structure with respect to an axis running in the direction of transport of the fiber structure, or
the plurality of lines comprises at least two lines and the lines intersect with each other,
(c) exerting pressure on the fiber structure with the applied liquid mixture by passing the fiber structure with the applied liquid mixture through a roll pair, to obtain a saturated fiber structure, wherein the roll pair comprises a pair of rolls, and
(d) cooling the saturated fiber structure, so that the molten monomer solidifies.

2. The process according to claim 1 , wherein the liquid mixture comprising the molten monomer is applied to the fiber structure in a plurality of lines in step (b) by using nozzles which have an aperture diameter of at most 5 mm.

3. The process according to claim 1 , wherein a distance between a location where the liquid mixture is applied to the fiber structure in step (b) and the roll pair through which the fiber structure is passed in step (c) is at most 3 m.

4. The process according to claim 1 , wherein the liquid mixture comprising the molten monomer has a viscosity in the range from 5 to 500 mPa·s.

5. The process according to claim 1 , wherein the fiber structure has a thickness and the distance between the rolls of the roll pair is from 1 to 1.5 times the thickness of the fiber structure.

6. The process according to claim 1 , wherein the fiber structure is moved on the conveyor belt at a transport velocity and the liquid mixture comprising the molten monomer is applied with a total flow rate, wherein the total flow rate and the transport velocity are selected in such a way that after passage of the fiber structure with the applied liquid mixture through the roll pair a content of fibers in the saturated fiber structure is from 20 to 70% by volume.

7. The process according to claim 1 , wherein the monomer is a lactam.

8. The process according to claim 7 , wherein the lactam is selected from the group consisting of caprolactam, piperidone, pyrrolidone, lauryllactam, and a mixture of these.

9. The process according to claim 7 , wherein the liquid mixture further comprises at least one lactone monomer, the at least one lactone monomer being provided in an amount of up to 50% by volume of the monomers in the liquid mixture.

10. The process according to claim 9 , wherein the at least one lactone monomer comprises caprolactone.

11. The process according to claim 7 , wherein the liquid mixture has a temperature in the range from 80 to 120° C. when applied in step (b), and the roll pair has a temperature of at most 100° C.

12. The process according to claim 1 , wherein the fiber structure is selected from the group consisting of a woven fabric, laid scrim, nonwoven, knitted fabric, braided fabric, and rovings.

13. The process according to claim 1 , wherein the fiber structure comprises fibers selected from the group consisting of glass fibers, carbon fibers, aramid fibers, steel fibers, potassium titanate fibers, basalt fibers, ceramic fibers, and mixtures thereof.

14. The process according to claim 1 , wherein the liquid mixture comprising the molten monomer further comprises at least one of an activator and a catalyst.

Assignees

• Basf Se
• Volkswagen Ag

Inventors

• Desbois Philippe
• Wollny Andreas
• Ehleben Max
• Bitterlich Maurice
• Zeuner Katja

Classifications

• B29K2105/0002

  monomers or prepolymers · CPC title

• B32B37/1292

  selectively, e.g. in stripes, in patterns (B32B37/0076 takes precedence) · CPC title

• B32B5/02

  characterised by structural features of a {fibrous or filamentary} layer {(layer formed of metallic wires B32B15/02; layer formed of natural mineral fibres B32B19/02; layer formed of wood fibres B32B21/02)} · CPC title

• B32B2262/101

  Glass fibres · CPC title

• B29B15/122 Primary

  with a matrix in liquid form, e.g. as melt, solution or latex · CPC title