Complex oxide, method for producing same, and exhaust gas purification catalyst

Patent metadata

Field	Value
Publication number	US-10610852-B2
Application number	US-201214119270-A
Country	US
Kind code	B2
Filing date	May 28, 2012
Priority date	Jun 1, 2011
Publication date	Apr 7, 2020
Grant date	Apr 7, 2020

Abstract

Provided are: a complex oxide that exhibits high redox ability even at low temperatures, has excellent heat resistance, and stably retains these characteristics even on repeated oxidation and reduction at high temperature; a method for producing the same; and an exhaust gas purification catalyst. The inventive complex oxide contains Ce; rare earth metal element other than Ce, including Y; Al and/or Zr; and Si; such that the Ce, and said other elements other than Ce and Si, are present in a mass ratio of 85:15-99:1, calculated as oxides; and has a characteristic such that when it is subjected to temperature-programmed reduction (TPR) measurement in a 10% hydrogen-90% argon atmosphere at from 50° C. to 900° C. with the temperature increasing at a rate of 10° C./min, followed by oxidation treatment at 500° C. for 0.5 hours, and then temperature-programmed reduction measurement is performed again, its calculated reduction rate at and below 400° C. is at least 2.0%.

First claim

The invention claimed is:

1. A complex oxide containing:
cerium oxide;
at least one oxide of a rare earth metal element other than cerium;
at least one oxide of an element selected from aluminum and zirconium; and
silicon oxide;
such that cerium, and other elements other than cerium and silicon, are present in a mass ratio of between 85:15 and 99:1, calculated as oxides;
wherein the complex oxide has, subsequent to reduction in a 10% hydrogen-90% argon atmosphere between 50° C. and 900° C. with temperature increasing at 10° C./min, followed by oxidation at 500° C. for 0.5 hours, a reduction rate at and below 400° C. of at least 2.0% as measured by temperature-programmed reduction (TPR) in a 10% hydrogen-90% argon atmosphere between 50° C. and 900° C. with temperature increasing at 10° C./min.

2. The complex oxide claimed in claim 1 , wherein the specific surface area of the complex oxide according to the BET method is at least 30 m 2 /g subsequent to three cycles of the reduction and oxidation treatments.

3. The complex oxide claimed in claim 1 , comprising 2.5-20 parts by mass of silicon, calculated as SiO 2 , per total 100 parts by mass of said other elements other than silicon, calculated as oxides.

4. The complex oxide claimed in claim 1 , where said reduction rate at and below 400° C. is at least 2.8%.

5. The complex oxide claimed in claim 4 , where said specific surface area according to the BET method is at least 35 m 2 /g.

6. A method for producing the complex oxide of claim 1 , comprising:
heating a cerium solution wherein at least 90 mol % of cerium ions are tetravalent, such that the temperature is maintained above 60° C., to form a cerium suspension;
adding at least one precursor of an oxide of a rare earth metal element other than cerium, and at least one precursor of an oxide of at least one element selected from aluminum and zirconium to the cerium suspension;
heating the cerium suspension containing said precursors, such that the temperature is maintained above 100° C.;
adding precipitant to the heated suspension to form a precipitate;
calcining the precipitate to form an oxide;
impregnating the oxide with a silicon oxide precursor solution to form an impregnated oxide;
firing the impregnated oxide to form a fired substance;
reducing the fired substance to form a reduced substance; and
oxidizing the reduced substance to form the complex oxide.

7. A method for producing the complex oxide of claim 1 , comprising:
heating a cerium solution wherein at least 90 mol % of cerium ions are tetravalent, such that the temperature is maintained above 60° C., to form a cerium suspension;
adding at least one silicon oxide precursor, at least one precursor of an oxide of a rare earth metal element other than cerium, and at least one precursor of an oxide of at least one element selected from aluminum and zirconium to the cerium suspension;
heating the cerium suspension containing said precursors, such that the temperature is maintained above 100° C.;
adding precipitant to the heated suspension to form a precipitate;
calcining the precipitate to form a calcined substance;
reducing the calcined substance to form a reduced substance; and
oxidizing the reduced substance to form the complex oxide.

8. The method claimed in claim 6 , where the cerium concentration in the cerium solution is 5-100 g/L, calculated as CeO 2 .

9. The method claimed in claim 6 , where the reduction is performed at 150-500° C.

10. The method claimed in claim 6 , where the oxidation is performed at 200-800° C.

11. The method claimed in claim 6 , wherein the precursor of an oxide of a rare earth metal element other than cerium comprises at least one element selected from yttrium, lanthanum, praseodymium and neodymium.

12. The method claimed in claim 7 , where the cerium concentration in the cerium solution is 5-100 g/L, calculated as CeO 2 .

13. The method claimed in claim 7 , where the reduction is performed at 150-500° C.

14. The method claimed in claim 7 , where the oxidation is performed at 200-800° C.

15. The method claimed in claim 7 , wherein the precursor of an oxide of a rare earth metal element other than cerium comprises at least one element selected from yttrium, lanthanum, praseodymium and neodymium.

16. The complex oxide claimed in claim 1 , wherein the rare earth metal element other than cerium comprises at least one element selected from yttrium, lanthanum, praseodymium and neodymium.

17. The complex oxide claimed in claim 1 , wherein the rare earth metal element other than cerium comprises at least one element selected from lanthanum and praseodymium.

18. An exhaust gas purification catalyst comprising the complex oxide of claim 1 .

19. An exhaust gas purification catalyst comprising the complex oxide of claim 16 .

20. An exhaust gas purification catalyst comprising the complex oxide of claim 17 .

Assignees

• Ohtake Naotaka
• MITSUOKA Keiichiro
• Yokota Kazuhiko
• Rhodia Operations

Inventors

• Ohtake Naotaka
• MITSUOKA Keiichiro
• Yokota Kazuhiko

Classifications

• B01D2255/40

  Mixed oxides · CPC title

• B01J21/066

  Zirconium or hafnium; Oxides or hydroxides thereof · CPC title

• B01D2255/407

  Zr-Ce mixed oxides · CPC title

• C01P2006/12

  Surface area · CPC title

• B01D2255/20715

  Zirconium · CPC title