Anaerobic aluminum-water electrochemical cell

Patent metadata

Field	Value
Publication number	US-10608307-B2
Application number	US-201816057257-A
Country	US
Kind code	B2
Filing date	Aug 7, 2018
Priority date	Dec 4, 2012
Publication date	Mar 31, 2020
Grant date	Mar 31, 2020

Abstract

Provided a method for generating an electrical current. The method includes: introducing water between the anode and at least one cathode of an electrochemical cell, to form an electrolyte; anaerobically oxidizing aluminum or an aluminum alloy; and electrochemically reducing water at the at least one cathode. The electrochemical cell includes: a plurality of electrode stacks, each electrode stack comprising an anode including the aluminum or aluminum alloy, and at least one cathode configured to be electrically coupled to the anode; one or more physical separators between each electrode stack adjacent to the cathode; a housing configured to hold the electrode stacks, the electrolyte, and the physical separators; and a water injection port. When the cell is in operation, the hydroxyaluminate concentration of the electrolyte in the cell is maintained between at least 20% to at most 750% of the saturation concentration.

First claim

The invention claimed is:

1. A method for generating an electrical current using an electrochemical cell, the method comprising: providing the electrochemical cell, the electrochemical cell comprising: a plurality of electrode stacks, each electrode stack comprising an a solid aluminum or aluminum alloy anode, in the form of a plate, the plate having a first side and a second side opposite to the first side, and at least one cathode disposed directly next to the first side of the plate and at least one cathode disposed directly next to the second side of the plate, wherein the cathode on the first side and the cathode on the second side are configured to be electrically coupled to the anode; one or more physical separators, between each one of the electrode stacks positioned between the cathode on the first side of one electrode stack and the cathode on the second side of an adjacent electrode stack; a housing configured to hold the electrode stacks, an electrolyte, and the physical separators; and a water injection port, in the housing, configured to introduce water into the housing; introducing the water between the anode and the at least one cathode on the first side and between the anode and the at least one cathode on the second side in each electrode stack, to form the electrolyte by mixing with hydroxyaluminate either prior to or after entering the housing; anaerobically oxidizing the aluminum or an aluminum alloy anode; electrochemically reducing the water at the at least one cathode; and, operating the electrochemical cell such that hydroxyaluminate concentration of the electrolyte in the electrochemical cell is maintained between 20% to 750% of the a saturation concentration.

2. The method according to claim 1 , wherein the electrolyte hydroxyaluminate concentration is maintained between about 30% to about 500% of the saturation concentration.

3. The method according to claim 1 , wherein the electrolyte hydoxyaluminate concentration is maintained between about 50% to about 250% of the saturation concentration.

4. The method according to claim 1 , wherein substantially no aluminum hydroxide precipitate is formed by homogeneous precipitation.

5. The method according to claim 1 , wherein the electrolyte includes a hydroxide base at a concentration of about 0.1 M to 3 M.

6. The method according to claim 1 , wherein the electrolyte includes a hydroxide base at a concentration of about 0.25 M to about 2.5 M.

7. The method according to claim 1 , wherein the water includes sodium chloride.

8. The method according to claim 1 , wherein the aluminum has a purity of at least 99.95 wt %.

9. The method according to claim 1 , wherein the aluminum has a purity of at least 99.99 wt %.

10. The method according to claim 1 , wherein the aluminum or aluminum alloy is substantially free of tin and boron.

11. The method according to claim 1 , wherein the cathode is in the form of a solid plate.

12. The method according to claim 1 , wherein the cathode is in the form of a sponge.

13. The method according to claim 1 , wherein the cathode includes a nickel-molybdenum alloy.

14. The method according to claim 1 , the cathode having a surface characterized by an electrochemical roughness factor of at least 5.

15. The method according to claim 1 , the cathode having a surface characterized by an electrochemical roughness factor of at least 10.

16. The method according to claim 1 , substantially free of aerobic oxidation of the aluminum or aluminum alloy.

17. The method of according to claim 1 , further comprising: providing a waste separation system, in fluid communication with the housing, configured to receive the electrolyte and aluminum hydroxide waste from the electrochemical cell and to separate the aluminum hydroxide waste from the electrolyte, and providing a fuel injector, in fluid communication with the waste separation system and the water injection port, configured to receive the electrolyte from the waste separation system and to provide the electrolyte to the water injection port.

18. The method according to claim 17 , wherein the fuel injector is further configured to receive the water from a water supply.

19. The method according to claim 1 , wherein the hydroxyaluminate concentration of the electrolyte in the cell is between 20% to about 150% of the saturation concentration.

Assignees

• Massachusetts Inst Technology

Inventors

• Mckay Ian Salmon
• Macdonald Ruaridh R
• Milnes Thomas B

Classifications

• H01M12/02

  Details (of electrodes H01M4/00; of non-active parts H01M50/00) · CPC title

• H01M4/9041

  Metals or alloys (H01M4/92 takes precedence) · CPC title

• H01M4/463 Primary

  Aluminium based · CPC title

• H01M2004/8689

  Positive electrodes · CPC title

• H01M2300/0014

  Alkaline electrolytes · CPC title