Lithium manganese composite oxide, secondary battery, and electrical device

Patent metadata

Field	Value
Publication number	US-10608248-B2
Application number	US-201715856281-A
Country	US
Kind code	B2
Filing date	Dec 28, 2017
Priority date	Oct 4, 2013
Publication date	Mar 31, 2020
Grant date	Mar 31, 2020

Abstract

The volume density or weight density of lithium ions that can be received and released in and from a positive electrode active material is increased to achieve high capacity and high energy density of a secondary battery. In a lithium manganese composite oxide, each particle includes a first region including a crystal with a layered rock-salt crystal structure and a second region including a crystal with a spinel crystal structure. The second region is in contact with the outside of the first region. The lithium manganese composite oxide has high structural stability and high capacity.

First claim

What is claimed is:

1. A lithium manganese composite oxide comprising:
a particle comprising a first region including a crystal with a layered rock-salt structure and a second region including a crystal different from the layered rock-salt structure,
wherein the second region is in contact with the first region,
wherein the second region covers 10% or more of an entire outside surface of the first region,
wherein the layered rock-salt structure is represented by Li r Mn s−t M t O 3 ,
wherein 1.4≤r≤2, 0.7≤s<1.5, 0≤t<1.5, and s≥t are satisfied,
wherein an element M is silicon, phosphorus, or a metal element other than lithium and manganese, and
wherein in the first region Li is partially substituted by Mn or M.

2. A lithium manganese composite oxide comprising:
a crystal region different from a layered rock-salt structure on at least part of a surface of a particle including a crystal region with the layered rock-salt structure,
wherein the crystal region different from the layered rock-salt structure covers 10% or more of an entire surface of the particle,
wherein the layered rock-salt structure is represented by Li r Mn s−t M t O 3 ,
wherein 1.4≤r≤2, 0.7≤s<1.5, 0≤t<1.5, and s≥t are satisfied,
wherein an element M is silicon, phosphorus, or a metal element other than lithium and manganese, and
wherein in the crystal region with a layered rock-salt structure Li is partially substituted by Mn or M.

3. A lithium manganese composite oxide comprising:
a particle comprising a first region including a crystal with a layered rock-salt structure and a second region including a crystal different from the layered rock-salt structure,
wherein 10% or more of an entire outer surface of the particle is formed with a layered region having crystal different from the layered rock-salt structure,
wherein the layered rock-salt structure is represented by Li r Mn s−t M t O 3 ,
wherein 1.4≤r≤2, 0.7≤s<1.5, 0≤t<1.5, and s≥t are satisfied, and
wherein an element M is silicon, phosphorus, or a metal element other than lithium and manganese, and
wherein in the first region Li is partially substituted by Mn or M.

4. The lithium manganese composite oxide according to claim 1 , wherein the second region covers 30% or more of the entire outside surface of the first region.

5. A lithium-ion secondary battery comprising the lithium manganese composite oxide according to claim 1 as a positive electrode active material.

6. An electrical device comprising the lithium-ion secondary battery according to claim 5 .

7. The lithium manganese composite oxide according to claim 2 , wherein the crystal region different from the layered rock-salt structure covers 30% or more of the entire surface of the particle.

8. A lithium-ion secondary battery comprising the lithium manganese composite oxide according to claim 2 as a positive electrode active material.

9. An electrical device comprising the lithium-ion secondary battery according to claim 8 .

10. A lithium-ion secondary battery comprising the lithium manganese composite oxide according to claim 3 as a positive electrode active material.

11. An electrical device comprising the lithium-ion secondary battery according to claim 10 .

12. The lithium manganese composite oxide according to claim 3 , wherein a thickness of the layered region is greater than or equal to 1 nm.

Assignees

• Semiconductor Energy Lab

Inventors

• Kawakami Takahiro
• Ikenuma Tatsuya
• Seo Satoshi

Classifications

• H01M2220/30

  Batteries in portable systems, e.g. mobile phone, laptop · CPC title

• H01M2004/021

  Physical characteristics, e.g. porosity, surface area · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M2004/028

  Positive electrodes · CPC title

• H01M4/505

  of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy · CPC title