Use of semi-aromatic copolyamide for transporting refrigerant fluid

Patent metadata

Field	Value
Publication number	US-10605385-B2
Application number	US-201414767530-A
Country	US
Kind code	B2
Filing date	Feb 13, 2014
Priority date	Feb 18, 2013
Publication date	Mar 31, 2020
Grant date	Mar 31, 2020

Abstract

The invention relates to the use of a layer consisting of a composition comprising a copolyamide of formula X/10.T/Y for transporting a heat transfer fluid in a vapor compression circuit, wherein: X represents either the residues of an aliphatic amino acid comprising between 8 and 18 carbon atoms, or a lactam, or the unit X 1 .X 2 representing the residues resulting from the condensation of an aliphatic diamine comprising between 6 and 18 carbon atoms and a (cyclo)aliphatic diacid comprising between 6 and 18 carbon atoms; 10.T represents the residues resulting from the condensation of a decanediamine and terephthalic acid; and Y represents the residues resulting from the condensation of an aliphatic diamine comprising between 9 and 14 carbon atoms and an aromatic diacid, Y being different from the unit 10.T; the molar proportion of 10.T units being higher than 0%.

First claim

The invention claimed is:

1. A vapor compression circuit element comprising at least one layer consisting of (1) 30% to 99% by mass of at least one copolyamide comprising units of the formula X, 10.T and Y and (2) at least one member selected from the group consisting of functionalized polyolefins, plasticizers, conversion aids, fillers, heat stabilizers, UV stabilizers, nucleating agents, dyes, pigments, mold release agents, flame retardants, surfactants, fluorescent whiteners, additional polymers, and antioxidants, wherein:
X represents alternatively the residues of an aliphatic amino acid comprising from 8 to 18 carbon atoms, or a lactam, or the unit X 1 .X 2 which represents the residues resulting from the condensation of an aliphatic diamine comprising from 6 to 18 carbon atoms and a (cyclo)aliphatic dicarboxylic acid comprising from 6 to 18 carbon atoms;
10.T represents the residues from the condensation of a decane diamine and terephthalic acid; and
Y represents the residues from the condensation of an aliphatic diamine comprising from 9 to 14 carbon atoms and an aromatic dicarboxylic acid, Y being different from the unit 10.T;
the molar proportion of units 10.T in the copolyamide is greater than 0%;
the molar proportion of the units Y relative to the total of units 10.T and Y is from 0% to 30%; and
the proportion of units X is from 0.4 to 0.8 mol per mole of semi-aromatic units 10.T and Y;
wherein the vapor compression circuit element is suitable for transporting a heat transfer fluid selected from the group consisting of hydrocarbon, hydrofluorocarbon, ether, hydrofluoroether, and fluoroolefin compounds.

2. The vapor compression circuit element as claimed in claim 1 , wherein the copolyamide is a copolyamide of formula X/10.T.

3. The vapor compression circuit element as claimed in claim 1 , wherein X represents either the residues of an aliphatic amino acid comprising from 10 to 12 carbon atoms or the unit X 1 .X 2 which represents the residues resulting from the condensation of an aliphatic diamine comprising from 6 to 12 carbon atoms and an aliphatic diacid comprising from 6 to 12 carbon atoms.

4. The vapor compression circuit element as claimed in claim 1 , wherein Y represents a unit 10.I, 9.T, 12.T, or 14.T.

5. The vapor compression circuit element as claimed in claim 1 , wherein the copolyamide is selected from the group consisting of copolyamides of formulae 11/10.T, 12/10.T, 6.10/10.T, 6.12/10.T, 10.6/10.T, 10.10/10.T, 10.12/10.T, 12.12/10.T, and 10.14/10.T.

6. The vapor compression circuit element as claimed in claim 1 , wherein the proportion of units X in the copolyamide is from 0.5 to 0.7 mol per mole of semi-aromatic units 10.T and Y.

7. The vapor compression circuit element as claimed in claim 1 , wherein the vapor compression circuit element is in contact with the heat transfer fluid and wherein the heat transfer fluid is a admixed with a lubricant.

8. The vapor compression circuit element as claimed in claim 1 , wherein the vapor compression circuit element belongs to a vapor compression circuit integrated in a device selected from the group consisting of mobile and stationary air conditioning devices, refrigeration devices, freezing devices, Rankine-cycle and heat-pump heating devices.

9. The vapor compression circuit element as claimed in claim 1 , wherein the vapor compression circuit element is a connection element or a pipe.

10. The vapor compression circuit element as claimed in claim 1 , wherein said layer is disposed on an inner surface of the element.

11. A vapor compression circuit element as claimed in claim 1 , wherein the vapor compression circuit element is a multilayer tube comprising in succession:
an inner layer consisting of the at least one copolyamide;
optionally, a first intermediate layer, composed of a first composition comprising an elastomeric material;
optionally, a second intermediate layer, composed of a reinforcing textile; and
an outer layer, composed of a second composition comprising an elastomeric material.

12. The vapor compression circuit element as claimed in claim 1 , wherein the vapor compression circuit element is an extruded article.

13. The vapor compression circuit element as claimed in claim 1 , wherein the copolyamide is PA 11/10.T.

14. The vapor compression circuit element as claimed in claim 1 , wherein the layer includes a functionalized polyolefin.

15. The vapor compression circuit element as claimed in claim 14 , wherein the layer comprises 10% to 40% by weight of the functionalized polyolefin.

16. The vapor compression circuit element as claimed in claim 14 , wherein the functionalized polyolefin is an alpha-olefin polymer comprising a reactive unit.

17. The vapor compression circuit element as claimed in claim 16 , wherein the reactive unit is a carboxylic acid function, anhydride function, or an epoxy function.

Assignees

• Arkema France

Inventors

• Blondel Philippe
• Brule Benoit
• Gamache Eric
• Meurice Pierrat Estelle

Classifications

• C08G69/36

  derived from amino acids, polyamines and polycarboxylic acids · CPC title

• B32B25/14

  comprising {synthetic rubber copolymers (B32B25/18 and B32B25/20 take precedence)} · CPC title

• C09K2205/126

  Unsaturated fluorinated hydrocarbons · CPC title

• B32B2307/308

  Heat stability · CPC title

• B29L2023/005

  Hoses, i.e. flexible · CPC title