Downhole electrochemical fluid sensor and method of using same

Patent metadata

Field	Value
Publication number	US-10605068-B2
Application number	US-201314109786-A
Country	US
Kind code	B2
Filing date	Dec 17, 2013
Priority date	Dec 17, 2013
Publication date	Mar 31, 2020
Grant date	Mar 31, 2020

Abstract

An electrochemical fluid sensor for a downhole production tool positionable in a wellbore penetrating a subterranean is provided. The wellbore has a downhole fluid therein. The electrochemical fluid sensor includes a sensor housing positionable in the downhole tool, a sensing solution positionable in the housing (the sensing solution including a mediator reactive to target chemicals), a gas permeable membrane to fluidly isolate the downhole fluid from the sensing solution (the gas permeable membrane permitting the passage of gas to the sensing solution), and a plurality of electrodes positioned about the housing a distance from the gas permeable membrane to measure reaction by the sensing solution whereby downhole parameters may be determined.

First claim

What is claimed is:

1. An electrochemical fluid sensor for a downhole tool positionable in a wellbore penetrating a subterranean formation, the wellbore having a downhole fluid therein, the electrochemical fluid sensor comprising:
a sensing portion positionable in the downhole tool, the sensing portion comprising:
a sensor body;
a plurality of electrodes positioned within the sensor body; and
part of a mediator flowline to circulate a sensing solution about the plurality of electrodes, the sensing solution comprising a mediator reactive to target chemicals; and

a fluid portion positionable outside the downhole tool and connected to the sensing portion, the fluid portion comprising:
part of the mediator flowline; and
a gas permeable membrane to fluidly isolate the downhole fluid from the sensing solution, the gas permeable membrane permitting a passage of gas to the sensing solution; and

wherein the plurality of electrodes measures a change in an electrical current based on electrochemical reaction by the sensing solution whereby concentration of the target chemicals may be determined based on the measured change.

2. The electrochemical fluid sensor of claim 1 , wherein the plurality of electrodes comprises at least one of a working electrode, a counter electrode, or a reference electrode.

3. The electrochemical fluid sensor of claim 1 , wherein the mediator comprises an electrocatalytic mediator.

4. The electrochemical fluid sensor of claim 3 , wherein the mediator comprises ferrocene.

5. A system for sensing downhole parameters of a downhole fluid in a wellbore penetrating a subterranean formation, the system comprising:
a downhole tool deployable into the wellbore; and
an electrochemical fluid sensor comprising:
a sensing portion in the downhole tool, comprising:
a sensor body;
a plurality of electrodes positioned within the sensor body; and
part of a mediator flowline to circulate a sensing solution about the plurality of electrodes, the sensing solution comprising a mediator reactive to target chemicals; and

a fluid portion positionable outside the downhole tool and connected to the sensing portion, the fluid portion comprising:
part of the mediator flowline; and
a gas permeable membrane positioned in the housing to fluidly isolate the downhole fluid from the sensing solution, the gas permeable membrane permitting a passage of gas to the sensing solution; and

wherein the plurality of electrodes measures a change in an electrical current based on electrochemical reaction by the sensing solution whereby concentration of the downhole parameters of the target chemicals may be determined based on the measured change.

6. The system of claim 5 , wherein the downhole tool is one of a wireline tool, a production tool, a coiled tubing tool, a logging tool, or a combination thereof.

7. The system of claim 5 , wherein the downhole tool has a recess to receive the electrochemical fluid sensor therein.

8. The system of claim 7 , wherein the recess is positioned about an outer side surface of the downhole tool.

9. The system of claim 7 , wherein the recess is positioned about a top side surface of the downhole tool.

10. The system of claim 5 , wherein the downhole tool has an arm extendable therefrom and wherein at least the fluid portion of the electrochemical fluid sensor is positionable in the arm.

11. The system of claim 5 , wherein the electrochemical fluid sensor is positionable in the downhole tool perpendicular to fluid flow.

12. The system of claim 5 , wherein the electrochemical fluid sensor is positionable in the downhole tool parallel to fluid flow.

Assignees

• Schlumberger Technology Corp

Inventors

• Pirolli Laurent
• Oddie Gary Martin
• Meredith Andrew
• Lawrence Nathan S
• Mcguinness Kay
• Collins John

Classifications

• G01N33/0044

  Sulphides, e.g. H2S · CPC title

• G01N27/4045

  for gases other than oxygen · CPC title

• Y10T436/184

  Only hydrogen sulfide · CPC title

• E21B47/00 Primary

  Survey of boreholes or wells (monitoring pressure or flow of drilling fluid E21B21/08) · CPC title

• E21B47/113 Primary

  using electrical indications; using light radiations · CPC title