IProton sponge as supplement to electrolytes for photocatalytic and electrochemical Co2 reduction

Patent metadata

Field	Value
Publication number	US-10604853-B2
Application number	US-201415039808-A
Country	US
Kind code	B2
Filing date	Nov 18, 2014
Priority date	Nov 26, 2013
Publication date	Mar 31, 2020
Grant date	Mar 31, 2020

Abstract

The invention relates to a method for converting carbon dioxide and water, wherein the electrolyte comprises a proton sponge which serves to accumulate CO2 in the electrolyte. The invention further relates to a corresponding use of a proton sponge and to an electrolyte comprising at least one proton sponge.

First claim

What is claimed is:

1. A method comprising:
reacting carbon dioxide and water in the presence of an electrolyte to form CO2, and
accumulating at least some of the formed CO2 in the electrolyte, the electrolyte comprising a liquid electrolyte or an electrolyte solution including a proton sponge, wherein the proton sponge comprises an aromatic diamine having the general formula:

where:
n is =0 or 1; A1 and A2 represent aromatic scaffolds linkable via a further ring A3, and
when n is =1, A3 is present and represents a substituted or unsubstituted cyclopentane ring which shares the bonding at positions 1 and 2 with the aromatic scaffold A1 and at positions 3 and 4 with the aromatic scaffold A2, and the carbon at position 5 is present between A1 and A2 at the bottom of the formula with two possible substituents Rd and Rd′;
Rd and Rd′ independently represent hydrogen and/or one or more substituted or unsubstituted linear, branched or cyclic alkyl moieties of 1 to 20 carbon atoms and/or substituted or unsubstituted aromatic and/or heteroaromatic moieties of 1 to 40 carbon atoms, wherein when Rd and Rd′ are present they are combinable to form an aliphatic or aromatic ring or polycycles; when n is =0, the ring A3 is absent and the rings A1 and A2 are fused; Rw, Rx, Ry, and Rz independently represent substituted or unsubstituted linear, branched or cyclic alkyl moieties of 1 to 50 carbon atoms and/or substituted or unsubstituted aromatic and/or heteroaromatic moieties of 1 to 100 carbon atoms and/or substituted or unsubstituted linear or branched sulfonylalkyl moieties of 1 to 50 carbon atoms, where 2 or more of Rx to Rz are combinable to form a ring or polycycles where not only Rw and Rx but also Ry and Rz are each replaceable by a single moiety Rw or Ry to form a double bond on the nitrogen; and Ra and Rb independently represent hydrogen and/or one or more substituted or unsubstituted linear, branched or cyclic alkyl moieties of 1 to 20 carbon atoms and/or substituted or unsubstituted aromatic and/or heteroaromatic moieties of 1 to 40 carbon atoms on a particular ring of a respective naphthalene skeleton, where when 2 or more of Ra and/or Rb are present, they are combinable to form an aliphatic or aromatic ring or polycycles.

2. The method of claim 1 , wherein the proton sponge in the liquid electrolyte or the electrolyte solution is present in dissolved or suspended form.

3. The method of claim 1 , wherein said reacting comprises photocatalysis.

4. The method of claim 3 , wherein the photocatalysis utilizes at least one ceramic photosemiconductor selected from the groups consisting of TiO2, ZnO, GaN, SrTiO3, BaTiO3, GaAs, MoS2, WSe2, MoSe2, and WO3.

5. The method of claim 1 , wherein said reacting comprises electrolysis.

6. The method of claim 5 , wherein the electrolysis is performed with at least one of: (a) a CO2 reduction catalyst as cathode or (b) an oxidation catalyst as anode.

7. The method of claim 6 , wherein the cathode contains at least one element selected from the group consisting of: Cu, Au, Ag, Zn, Pd, Bi, and Ga.

Assignees

• Siemens Ag

Inventors

• Fleischer Maximilian
• Groenninger Philipp
• Krause Ralf
• Matzas Mark
• Schmid Guenter
• Wiesner Kerstin

Classifications

• B01D2255/2096

  Bismuth · CPC title

• B01D2255/209

  Other metals · CPC title

• C10G2/50

  from carbon dioxide with hydrogen · CPC title

• B01D2252/103

  Water · CPC title

• B01D2252/30

  Ionic liquids and zwitter-ions · CPC title