Al—Zn alloy comprising precipitates with improved strength and elongation and method of manufacturing the same

Patent metadata

Field	Value
Publication number	US-10604828-B2
Application number	US-201715617152-A
Country	US
Kind code	B2
Filing date	Jun 8, 2017
Priority date	Jun 9, 2016
Publication date	Mar 31, 2020
Grant date	Mar 31, 2020

Abstract

The present invention relates to an Al—Zn alloy with improved strength and elongation comprising more than 20 parts by weight of zinc relative to the total weight of the alloy and comprising discontinuous precipitates or lamellar precipitates, formed forcibly in 5% or more per unit area. According to the present invention, the tensile strength and the elongation of an Al—Zn alloy are simultaneously improved.

First claim

What is claimed is:

1. An Al—Zn alloy comprising:
zinc, wherein an amount of zinc is more than 20 parts by weight and less than 50 parts by weight based on 100 parts by weight of the Al—Zn alloy;
aluminum; and
unavoidable impurities,
wherein
the Al—Zn alloy further comprises a precipitation accelerating metal,
the precipitation accelerating metal is at least one selected from the group consisting of 0.05 to 5 parts by weight of copper, 0.05 to 0.1 parts by weight of titanium, 0.1 to 0.3 parts by weight of silicon, 0.1 to 0.5 parts by weight of iron, 0.1 to 0.5 parts by weight of manganese, 0.1 to 5 parts by weight of magnesium, and 0.1 to 3 parts by weight of chromium,
the Al—Zn alloy comprises discontinuous precipitates or lamellar precipitates,
the discontinuous precipitates or lamellar precipitates are formed forcibly in 5% or more per unit area and are oriented,
an average spacing between the precipitates of the discontinuous precipitates or the lamellar precipitates is 105 nm or less, and
the Al—Zn alloy has improved strength and elongation.

2. The Al—Zn alloy of claim 1 , wherein an average thickness of the discontinuous precipitates or the lamellar precipitates is 55 nm or less.

3. The Al—Zn alloy of claim 1 , wherein the discontinuous precipitates or the lamellar precipitates are formed by heat treating the Al—Zn alloy to form solid solution and then aging the Al—Zn alloy.

4. The Al—Zn alloy of claim 1 , wherein the precipitation accelerating metal is copper, and the copper is included in an amount of 0.05 to 5 parts by weight based on the total weight of the alloy.

5. The Al—Zn alloy of claim 1 , wherein the elongation is at least 10% when the tensile strength is 300 MPa to 400 Mpa.

6. The Al—Zn alloy of claim 1 , wherein the elongation is at least 5% the tensile strength is 400 MPa to 500 MPa.

7. An Al—Zn alloy comprising:
zinc, wherein an amount of zinc is more than 20 parts by weight and less than 50 parts by weight based on 100 parts by weight of the Al—Zn alloy;
aluminum; and
unavoidable impurities,
wherein
the Al—Zn alloy further comprises a precipitation accelerating metal,
the precipitation accelerating metal is at least one selected from the group consisting of 0.05 to 5 parts by weight of copper, 0.05 to 0.1 parts by weight of titanium, 0.1 to 0.3 parts by weight of silicon, 0.1 to 0.5 parts by weight of iron, 0.1 to 0.5 parts by weight of manganese, 0.1 to 5 parts by weight of magnesium, and 0.1 to 3 parts by weight of chromium,
the Al—Zn alloy comprises discontinuous precipitates or lamellar precipitates,
the discontinuous precipitates or the lamellar precipitates have an average aspect ratio of at least 20 and are oriented precipitates,
an average spacing between the precipitates of the discontinuous precipitates or the lamellar precipitates is 105 nm or less, and
the Al—Zn alloy has improved strength and elongation.

8. An Al—Zn alloy comprising:
zinc, wherein an amount of zinc is more than 20 parts by weight and less than 50 parts by weight based on 100 parts by weight of the Al—Zn alloy;
aluminum; and
unavoidable impurities,
wherein
the Al—Zn alloy further comprises a precipitation accelerating metal,
the precipitation accelerating metal is at least one selected from the group consisting of 0.05 to 5 parts by weight of copper, 0.05 to 0.1 parts by weight of titanium, 0.1 to 0.3 parts by weight of silicon, 0.1 to 0.5 parts by weight of iron, 0.1 to 0.5 parts by weight of manganese, 0.1 to 5 parts by weight of magnesium, and 0.1 to 3 parts by weight of chromium,
the Al—Zn alloy comprises discontinuous precipitates or lamellar precipitates,
the discontinuous precipitates or the lamellar precipitates have an average length of at least 1.4 μm and are oriented precipitates,
an average spacing between the precipitates of the discontinuous precipitates or the lamellar precipitates is 105 nm or less, and
the Al—Zn alloy has improved strength and elongation.

9. A method for manufacturing an Al—Zn alloy with improved strength and elongation at the same time of claim 1 , the method comprising:
preparing an Al—Zn alloy having a composition of claim 1 ;
forming a solid solution by heat treating the Al—Zn alloy;
aging the Al—Zn alloy comprising the solid solution to force forming 5% or more of discontinuous precipitates or lamellar precipitates per unit area; and
orienting to form oriented precipitates by calcining the Al—Zn alloy comprising the precipitates.

10. The method of claim 9 , wherein the heat treating is performed by heating at a temperature range of 350 to 450° C. for 120 minutes or more.

11. The method of claim 9 , wherein the aging is performed at a temperature of 120 to 200° C. for 5 minutes to 400 minutes.

12. The method of claim 9 , wherein the precipitation accelerating metal is copper, and the copper is included in an amount of 0.05 to 5 parts by weight based on the total weight of the alloy.

13. The method of claim 9 , wherein the orienting is performed with a plastic working of 50% or more.

14. The method of claim 9 , wherein the orienting is performed in a liquid nitrogen atmosphere.

Assignees

• Korea Inst Mach & Materials

Inventors

• Han Seung-Zeon
• Ahn Jee-Hyuk
• Kim Min-Soo

Classifications

• C22F1/053 Primary

  of alloys with zinc as the next major constituent · CPC title

• C22C21/10 Primary

  with zinc as the next major constituent · CPC title

• C22F1/165

  of zinc or cadmium or alloys based thereon · CPC title

• C22C1/02

  by melting {(C22C1/1036 takes precedence)} · CPC title

• C22C21/02 Primary

  with silicon as the next major constituent · CPC title