Systems and methods related to the production of ethylene oxide, ethylene glycol, and/or ethanolamines

Patent metadata

Field	Value
Publication number	US-10604496-B2
Application number	US-201615554922-A
Country	US
Kind code	B2
Filing date	Mar 2, 2016
Priority date	Mar 5, 2015
Publication date	Mar 31, 2020
Grant date	Mar 31, 2020

Abstract

Disclosed herein is a method comprising the steps of: a) producing a hydrocarbon stream from syngas via a Fischer-Tropsch reaction, wherein the hydrocarbon stream comprises a first C2 hydrocarbon stream comprising ethane and a first ethylene product; b) separating at least a portion of the first C2 hydrocarbon stream from the hydrocarbon stream; c) separating at least a portion of the first ethylene product from the first C2 hydrocarbon stream, thereby producing a second C2 hydrocarbon stream; d) converting at least a portion of the ethane in the second C2 hydrocarbon stream to a second ethylene product; and e) producing ethylene oxide from at least a portion of the second ethylene product.

First claim

What is claimed is:

1. A method comprising the steps of:
producing a hydrocarbon stream from syngas via a Fischer-Tropsch reaction, wherein the hydrocarbon stream comprises a first C2 hydrocarbon stream comprising ethane and a first ethylene product;
separating at least a portion of the first C2 hydrocarbon stream from the hydrocarbon stream;
separating at least a portion of the first ethylene product from the first C2 hydrocarbon stream, thereby producing a second C2 hydrocarbon stream;
converting at least a portion of the ethane in the second C2 hydrocarbon stream to a second ethylene product;
combining the first ethylene product and the second ethylene product, thereby producing a third ethylene product; and
producing ethylene oxide from at least a portion of the third ethylene product.

2. The method of claim 1 , wherein the first C2 hydrocarbon stream comprises from about 30 wt % to about 70 wt % of ethane and from about 70 wt % to about 30 wt % of the first ethylene product.

3. The method of claim 1 , wherein the second C2 hydrocarbon stream comprises at least about 80 wt % of ethane.

4. The method of claim 1 , wherein the hydrocarbon stream further comprises from about 30 wt % to about 70 wt % of C3-C10 hydrocarbons.

5. The method of claim 1 , wherein the method further comprises the step of producing ethylene glycol from at least a portion of the ethylene oxide.

6. The method of claim 1 , wherein the method further comprises the step of producing one or more ethanolamines comprising monoethanolamine, diethanolamine, and/or triethanolamine from at least a portion of the ethylene oxide.

7. The method of claim 6 , wherein the method further comprises the step of separating monoethanolamine from the one or more ethanolamines.

8. The method of claim 6 , wherein the method further comprises the step of separating diethanolamine from the one or more ethanolamines.

9. The method of claim 6 , wherein the method further comprises the step of separating triethanolamine from the one or more ethanolamines.

10. The method of claim 1 , wherein the step of converting at least a portion of the ethane in the second C2 hydrocarbon stream to a second ethylene product comprises dehydrogenating the at least a portion of the ethane in the second C2 hydrocarbon stream.

11. The method of claim 1 , wherein the step of converting at least a portion of the ethane in the second C2 hydrocarbon stream to a second ethylene product comprises cracking the at least a portion of the ethane in the second C2 hydrocarbon stream.

12. The method of claim 1 , wherein the step of producing ethylene oxide from at least a portion of the third ethylene product comprises reacting the third ethylene product with an oxygenate.

13. The method of claim 1 , wherein the step of converting at least a portion of the ethane in the second C2 hydrocarbon stream to the second ethylene product consists of only producing the second ethylene product from the ethane in the second C2 hydrocarbon stream.

14. The method of claim 1 , wherein the step of separating at least a portion of the first C2 hydrocarbon stream from the hydrocarbon stream is performed in a deethanizer.

Assignees

• Sabic Global Technologies Bv

Inventors

• Al-Shammari Talal
• Karim Khalid
• Nawaz Zeeshan
• Al-Hammad Ali
• Khurram Shehzada
• Bashir Mubarik Ali
• Ahmed Labeeb Chaudhary
• Al-Jaloud Abdullah Turki
• Al-Khudeer Saud
• Al-Qahtani Thabet

Classifications

• C07D301/32

  Separation; Purification · CPC title

• C07D301/03 Primary

  by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds · CPC title

• C07C213/04

  by reaction of ammonia or amines with olefin oxides or halohydrins · CPC title

• C07C1/0485

  Set-up of reactors or accessories; Multi-step processes · CPC title

• C10G2/00

  Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon · CPC title