Catalytic body coated with metal oxide, method of manufacturing the same, and method of preparing 1,3-butadiene using the same

Patent metadata

Field	Value
Publication number	US-10604459-B2
Application number	US-201816029833-A
Country	US
Kind code	B2
Filing date	Jul 9, 2018
Priority date	Jul 13, 2017
Publication date	Mar 31, 2020
Grant date	Mar 31, 2020

Abstract

According to an embodiment of the present invention, there are provided a catalytic body, a method of manufacturing the same, and a method of preparing 1,3-butadiene using the same. The catalytic body includes an inactive support; an intermediate layer disposed on a surface of the inactive support; and an active layer disposed on a surface of the intermediate layer, wherein the active layer includes catalyst powder and a binder.

First claim

What is claimed is:

1. A catalytic body comprising:
an inactive support;
an intermediate layer disposed on a surface of the inactive support; and
an active layer disposed on a surface of the intermediate layer,

wherein:
the active layer includes catalyst powder and a binder;
the binder includes an inorganic binder;
the inorganic binder is included in an amount of 5 to 20 wt % with respect to a total weight of the catalyst powder and the inorganic binder; and
the catalyst powder has a weight of 200 to 500 g/L with respect to a volume of the inactive support.

2. The catalytic body of claim 1 , wherein the inactive support has a porosity of 70 vol % or less.

3. The catalytic body of claim 2 , wherein the inactive support is of one shape selected from the group consisting of a spherical shape, a cylindrical shape, a ring shape, a platy shape, and a combination of two or more thereof.

4. The catalytic body of claim 3 , wherein the inactive support is one selected from the group consisting of alumina, silica, zirconia, silicon carbide, cordierite, and a combination of two or more thereof.

5. The catalytic body of claim 1 , wherein the intermediate layer consists of one selected from the group consisting of alumina, silica, kaolin, TiO 2 , ZnO, bentonite, and a combination of two or more thereof.

6. The catalytic body of claim 1 , wherein the intermediate layer has a weight of 3 to 15 g/L with respect to a volume of the inactive support.

7. The catalytic body of claim 1 , wherein the catalyst powder is an oxide derived from one selected from the group consisting of iron, magnesium, manganese, zinc, bismuth, molybdenum, and a combination of two or more thereof.

8. The catalytic body of claim 1 , wherein the inorganic binder is one selected from the group consisting of alumina, silica, sodium silicate, aluminum silicate, calcium silicate, calcium carbonate, barium carbonate (BaCO 3 ), kaolin, mica, TiO 2 , ZnO, iron oxide, bentonite, and a mixture of two or more thereof.

9. A method of manufacturing a catalytic body, comprising:
(a) mixing an inactive support and an alumina sol, followed by drying and thermal treatment to form an intermediate layer on a surface of the inactive support;
(b) dissolving two or more metal salts in a first solvent to prepare a first solution, and preparing catalyst powder by pyrolyzing the first solution while spraying the first solution into a reactor using a carrier gas or by adding a co-precipitant to the first solution and then performing drying and thermal treatment;
(c) mixing the catalyst powder, a binder, and a second solvent to prepare a second solution; and
(d) mixing the inactive support having intermediate layer formed thereon of step (a) and the second solution, followed by drying and thermal treatment to form an active layer including the catalyst powder on a surface of the intermediate layer,
wherein:
the binder includes an inorganic binder;
the inorganic binder is included in an amount of 5 to 20 wt % with respect to a total weight of the catalyst powder and the inorganic binder; and
the catalyst powder has a weight of 200 to 500 g/L with respect to a volume of the inactive support.

10. The method of claim 9 , wherein the inactive support has a porosity of 70 vol % or less.

11. The method of claim 10 , wherein the inactive support is of one shape selected from the group consisting of a spherical shape, a cylindrical shape, a ring shape, a platy shape, and a combination of two or more thereof.

12. The method of claim 11 , wherein the inactive support is one selected from the group consisting of alumina, silica, zirconia, silicon carbide, cordierite, and a combination of two or more thereof.

13. The method of claim 9 , wherein the intermediate layer consists of one selected from the group consisting of alumina, silica, kaolin, TiO 2 , ZnO, bentonite, and a combination of two or more thereof.

14. The method of claim 9 , wherein the intermediate layer has a weight of 3 to 15 g/L with respect to a volume of the inactive support.

15. The method of claim 9 , wherein the metal salt is a nitrate derived from one selected from the group consisting of iron, magnesium, manganese, zinc, bismuth, molybdenum, and a combination of two or more thereof.

16. The method of claim 9 , wherein the co-precipitant is sodium hydroxide, ammonia, or a combination thereof.

17. The method of claim 9 , wherein the pyrolysis is carried out at 500 to 900° C.

18. The method of claim 9 , wherein the inorganic binder is one selected from the group consisting of alumina, silica, sodium silicate, aluminum silicate, calcium silicate, calcium carbonate, barium carbonate (BaCO 3 ), kaolin, mica, TiO 2 , ZnO, iron oxide, bentonite, and a mixture of two or more thereof.

19. A method of preparing 1,3-butadiene comprising oxidative dehydrogenation of n-butene in the presence of the catalytic body of claim 1 .

Assignees

• Korea Kumho Petrochemical Co Ltd

Inventors

• Kim Yun Jung
• Kim Jae Woo
• Yun Yong Hee
• Park Ji Won
• Row Kyoung Ho

Classifications

• B01J23/78 Primary

  with alkali- or alkaline earth metals · CPC title

• C07C2523/78

  with alkali- or alkaline earth metals or beryllium · CPC title

• C07C5/3332

  with metal oxides or metal sulfides · CPC title

• B01J37/088

  Decomposition of a metal salt · CPC title

• C07C11/167

  1, 3-Butadiene · CPC title