Polyarylene ether sulfone-polymers for membrane applications

Patent metadata

Field	Value
Publication number	US-10603640-B2
Application number	US-201815970249-A
Country	US
Kind code	B2
Filing date	May 3, 2018
Priority date	Sep 9, 2013
Publication date	Mar 31, 2020
Grant date	Mar 31, 2020

Abstract

The present invention relates to a method of forming a polyarylene ether sulfone polymer by converting a reaction mixture (R G ) comprising a dihalogen component (A1), a dihydroxy component (B1) and potassium carbonate (C1) having a volume-average particle size of <25 μm. The present invention further relates to the polyarylene ether sulfone polymers obtainable by said method, to products obtainable from said polyarylene ether sulfone polymer and to membranes formed from said polyarylene ether sulfone polymer.

First claim

We claim:

1. A polyarylene ether sulfone polymer, comprising in polymerized form:
(A1) a dihalogen component comprising not less than 50 wt % of at least one dihalogen compound selected from the group consisting of 4,4′-dichlorodiphenyl sulfone and 4,4′-difluorodiphenyl sulfone, based on the overall weight of component (A1); and
(B1) a dihydroxy component comprising not less than 80 wt % of at least one dihydroxy compound selected from the group consisting of bisphenol A and 4,4′-dihydroxybenzophenone, based on the overall weight of component (B1),
wherein the polyarylene ether sulfone polymer has a polydispersity (Q) from 2.0 to ≤4, wherein Q is defined as the quotient formed by dividing the number average molecular weight (M n ) into the weight average molecular weight (M w ) measured using gel permeation chromatography (GPC), using dimethylacetamide (DMAc) as solvent and narrowly distributed polymethyl methacrylate as standard.

2. The polyarylene ether sulfone polymer according to claim 1 , comprising repeat units of formula Ia:

3. The polyarylene ether sulfone polymer according to claim 1 , wherein terminal groups of the polyarylene ether sulfone polymer comprise halogen and alkoxy groups.

4. The polyarylene ether sulfone polymer according to claim 1 , wherein terminal groups of the polyarylene ether sulfone polymer comprise chlorine and alkoxy groups.

5. The polyarylene ether sulfone polymer according to claim 1 , wherein terminal groups of the polyarylene ether sulfone polymer comprise chlorine groups and at least one of methoxy groups and aryloxy groups.

6. A mixture, comprising:
I) the polyarylene ether sulfone polymer according to claim 1 ; and
II) a polyvinylpyrrolidone.

7. The mixture according to claim 6 , wherein the polyvinylpyrrolidone has a weight average molecular weight (M w ) ranging from 10,000 to 2,000,000 g/mol.

8. The mixture according to claim 6 , wherein the polyarylene ether sulfone polymer (I) comprises repeat units of formula Ia:

9. The mixture according to claim 6 , wherein terminal groups of the polyarylene ether sulfone polymer (I) comprise halogen and alkoxy groups.

10. A method of reducing the polydispersity (Q) of a polyarylene ether sulfone polymer, the method comprising forming the polyarylene ether sulfone polymer in the presence of potassium carbonate having a volume-weighted average particle size of from 20 nm to 25 μm,
wherein:
the polydispersity (Q) of the polyarylene ether sulfone is reduced to 4 or less; and
Q is defined as the quotient formed by dividing the number average molecular weight (M n ) into the weight average molecular weight (M w ), measured using gel permeation chromatography (GPC), using dimethylacetamide (DMAc) as solvent and narrowly distributed polymethyl methacrylate as standard.

11. The method according to claim 10 , wherein the polydispersity (Q) of the polyarylene ether sulfone polymer is reduced to 3.5 or less.

12. The polyarylene ether sulfone polymer according to claim 1 , which has a polydispersity (Q) from 2.0 to ≤3.5.

13. The polyarylene ether sulfone polymer according to claim 2 , wherein terminal groups of the polyarylene ether sulfone polymer comprise halogen and alkoxy groups.

14. The polyarylene ether sulfone polymer according to claim 2 , wherein terminal groups of the polyarylene ether sulfone polymer comprise chlorine and alkoxy groups.

15. The polyarylene ether sulfone polymer according to claim 2 , wherein terminal groups of the polyarylene ether sulfone polymer comprise chlorine groups and at least one of methoxy groups and aryloxy groups.

16. The method according to claim 10 , wherein the polyarylene ether sulfone polymer is formed by reaction over a time interval ranging from 2 to 12 hours.

17. The polyarylene ether sulfone polymer according to claim 1 , which has a polydispersity (Q) from 2.5 to ≤4.

18. The polyarylene ether sulfone polymer according to claim 1 , which has a polydispersity (Q) from 2.5 to ≤3.5.

Assignees

• Basf Se

Inventors

• Weber Martin
• Maletzko Christian
• Erbes Joerg
• Kortekamp Tobias
• Staal Bastiaan Bram Pieter
• Heil Thomas

Classifications

• B29C48/919

  using a bath, e.g. extruding into an open bath to coagulate or cool the material · CPC title

• B29C48/05

  Filamentary, e.g. strands · CPC title

• B29C48/04

  Particle-shaped (making granules B29B9/00) · CPC title

• B01D67/0006

  by chemical reactions (in-situ polymerisation, polycondensation, cross-linking or reaction for manufacturing composite membranes B01D69/125) · CPC title

• B01D71/68 Primary

  Polysulfones; Polyethersulfones · CPC title