Quarternized titanium-nitride anti-bacterial coating for dental implants
US-2024041575-A1 · Feb 8, 2024 · US
US10603144B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10603144-B2 |
| Application number | US-201414338442-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jul 23, 2014 |
| Priority date | Nov 19, 2004 |
| Publication date | Mar 31, 2020 |
| Grant date | Mar 31, 2020 |
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A dental prosthesis, typically formed in a press to metal process, includes application of a porcelain composition sufficient to form a veneer on a dental prosthesis supporting metal structure, the composition having an integrated tooth-like translucency providing an aesthetic appearance. The composition is formed of a dentin frit and an enamel frit, typically sintered into a desired ingot shape including an amount of composition sufficient to veneer the prosthesis. The porcelain composition is a component of a kit that includes opaquers, other porcelains and stains useful in finishing to provide an aesthetic prosthesis.
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What is claimed is: 1. Method of making a porcelain veneered dental prosthesis comprising the steps of: providing a substructure for supporting and fitting a dental prosthesis onto tooth surfaces; forming an opaquing ceramic mixture, wherein the opaquing ceramic mixture in powder form has the following total composition of 100 wt. %: 53-56 wt % of SiO2, 10-14 wt % of Al2O3, 3-5 wt % of Na2O, 8-11 wt % of K2O, 0-2 wt % of Li20, 0-2 wt % of CaO, 0-1 wt % of BaO, 0-1.5 wt % of CeO2, and 0-3 wt % of Tb4O7, which is obtainable by mixing: (i) 40 to 60% by weight a first frit material, the first frit material being formed from a composition that includes a plurality of oxides; (ii) 20 to 45% by weight a second frit material, the second frit material being formed from a composition that includes a plurality of oxides, and (iii) 12-17 wt % ZrO2; wherein the composition that forms the second frit material is different from the composition that forms the first frit material; coating the substructure with the opaquing ceramic mixture; and firing the substructure with the opaquing ceramic mixture to form an opaque layer fused to the substructure. 2. The method of claim 1 , further comprising the step of providing in a hot press furnace for injecting a ceramic porcelain material into an investment mold. 3. The method of claim 1 , further comprising the step of investing the dental substructure in a mold forming an adjacent cavity for receiving a veneer to be fused to the opaque layer of the substructure. 4. The method of claim 3 , further comprising the step of injecting, under heat and pressure, into the veneer cavity a porcelain ceramic having an integrated tooth-like translucency wherein the porcelain ceramic forms a translucent layer that is fused to the opaque layer of the supporting structure or coping, thereby forming a finished prosthesis having a tooth-like appearance. 5. The method of claim 1 , wherein the substructure is a metal supporting structure or coping. 6. The method of claim 1 , wherein at least one of the composition of the first frit material and the second frit material further includes ZrO2. 7. The method of claim 4 , further comprising the step of forming the porcelain ceramic by blending dentin and enamel frit materials, in ratios of 70:30 to 85:15 percent by weight, respectively. 8. The method of claim 1 , wherein the opaque layer is in powder form or in paste form. 9. The method of claim 1 , wherein composition of the second frit material includes at least two of the following components: CaO, BaO, CeO 2 , and Tb 4 O 7 . 10. The method of claim 1 , wherein the composition of the second frit material includes at least two of the following components: CaO, BaO, CeO 2 , and Sb 2 O 3 . 11. The method of claim 4 , wherein the porcelain ceramic includes Sb 2 O 3 . 12. The method of claim 1 , wherein the opaquing ceramic is applied by hand application using a spatula and/or a brush, spraying, a slurry dip or electrodeposit. 13. The method of claim 7 , wherein the blend of the dentin frit material and the enamel frit material includes: 70 to 85% by weight the dentin frit material; and 15 to 30% by weight the enamel frit material, the enamel frit material being different than the dentin frit.
Glass · CPC title
{Composite teeth, e.g. front and back section (A61C13/0835, A61C13/1023 take precedence)}; Multilayer teeth · CPC title
Ceramic coating on metallic body · CPC title
comprising zirconium oxide · CPC title
Cosmetic aspects, e.g. inlays; Determination of the colour (A61C19/10 takes precedence) · CPC title
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