Anaerobic aluminum-water electrochemical cell

Patent metadata

Field	Value
Publication number	US-10601095-B2
Application number	US-201815949563-A
Country	US
Kind code	B2
Filing date	Apr 10, 2018
Priority date	Dec 4, 2012
Publication date	Mar 24, 2020
Grant date	Mar 24, 2020

Abstract

An anaerobic aluminum-water electrochemical cell that includes: a plurality of electrode stacks, each electrode stack comprising an aluminum or aluminum alloy anode, and at least one solid cathode configured to be electrically coupled to the anode; a liquid electrolyte between the anode and the at least one cathode; one or more physical separators between each electrode stack adjacent to the cathode; a housing configured to hold the electrode stacks, the electrolyte, and the physical separators; and a water injection port, in the housing, configured to introduce water into the housing. The electrolyte includes a hydroxide base at a concentration of at least 0.05 M to at most 3 M.

First claim

What is claimed is:

1. An anaerobic aluminum-water electrochemical cell comprising:
a plurality of electrode stacks, each electrode stack comprising a solid aluminum or aluminum alloy anode, in the form of a plate, the plate having a first side and a second side opposite to the first side, and at least one solid cathode disposed directly next to the first side of the plate and at least one cathode disposed directly next to the second side of the plate, wherein the cathode on the first side and the cathode on the second side are configured to be electrically coupled to the anode;
a liquid electrolyte disposed between the anode and the at least one cathode on the first side and between the anode and the at least one cathode on the second side in each electrode stack;
one or more physical separators, between each one of the electrode stacks, positioned between the cathode on the first side of one electrode stack and the cathode on the second side of an adjacent electrode stack;
a housing configured to hold the electrode stacks, the electrolyte, and the physical separators; and
a water injection port, in the housing, configured to introduce water into the housing, so that the water flows though the physical separators,
wherein the electrolyte includes a hydroxide base at a concentration of 0.05 M to 3 M.

2. The electrochemical cell according to claim 1 , wherein the electrolyte includes the hydroxide base at a concentration of between about 0.1 M to about 2.5 M.

3. The electrochemical cell according to claim 1 , wherein the electrolyte includes the hydroxide base at a concentration of between about 0.25 M to about 2 M.

4. The electrochemical cell according to claim 1 , wherein the anode has a purity of at least 99.95 wt % of aluminum.

5. The electrochemical cell according to claim 1 , wherein the electrolyte includes sodium chloride.

6. The electrochemical cell according to claim 1 , wherein the one or more physical separators are formed from a mesh material having openings of about 100 μm or larger.

7. The electrochemical cell according to claim 1 , wherein the anode has a purity of at least 99.99 wt % of aluminum.

8. An aluminum-water electrochemical system comprising:
an aluminum-water electrochemical cell according to claim 1 ;
a waste separation system in fluid communication with the housing and configured to receive the electrolyte and aluminum hydroxide waste from the aluminum-water electrochemical cell and to separate the aluminum hydroxide waste from the electrolyte; and
a fuel injector, in fluid communication with the waste separation system and the water injection port, configured to receive the electrolyte from the waste separation system and to provide the electrolyte to the water injection port.

9. The electrochemical system according to claim 8 , wherein the fuel injector is further configured to receive the water from a water supply.

10. The electrochemical system according to claim 8 , wherein each electrode stack includes two cathodes on either side of the anode.

11. The electrochemical system according to claim 8 , wherein the electrolyte includes the hydroxide base at a concentration of between about 0.25 M to about 2 M.

12. The electrochemical system according to claim 8 , wherein the electrolyte includes sodium chloride.

13. The electrochemical system according to claim 8 , wherein the one or more physical separators are formed from a mesh material having openings of about 100 μm or larger.

14. The electrochemical system according to claim 8 , wherein the anode has a purity of at least 99.95 wt % of aluminum.

15. A method for generating an electrical current comprising introducing a liquid electrolyte into an electrochemical cell, the method comprising:
providing the electrochemical cell, the electrochemical cell comprising:
a plurality of electrode stacks, each electrode stack comprising a solid aluminum or aluminum alloy anode, in the form of a plate, the plate having a first side and a second side opposite to the first side, and at least one solid cathode disposed directly next to the first side of the plate and at least one cathode disposed directly next to the second side of the plate, wherein the cathode on the first side and the cathode on the second side are configured to be electrically coupled to the anode;
one or more physical separators between each one of the electrode stacks, positioned between the cathode on the first side of one electrode stack and the cathode on the second side of an adjacent electrode stack;
a housing configured to hold the electrode stacks, the electrolyte, and the physical separators; and
a water injection port, in the housing, configured to introduce the electrolyte into the housing, so that the electrolyte flows through the physical separators;

introducing the electrolyte between the anode and the at least one cathode on the first side and between the anode and the at least one cathode on the second side in each electrode stack;
wherein the electrolyte includes a hydroxide base at a concentration of 0.05 M to 3 M.

16. The method according to claim 15 , wherein the hydroxide base has a concentration of between about 0.1 M to about 2.5 M.

17. The method according to claim 15 , wherein the hydroxide base has a concentration of between about 0.25 M to about 2 M.

18. The method according to claim 15 , wherein the water includes sodium chloride.

Assignees

• Massachusetts Inst Technology

Inventors

• Mckay Ian Salmon
• Macdonald Ruaridh R
• Milnes Thomas B

Classifications

• H01M8/04186

  of liquid-charged or electrolyte-charged reactants · CPC title

• H01M2300/0057

  Chlorides · CPC title

• H01M4/463

  Aluminium based · CPC title

• H01M2004/027

  Negative electrodes · CPC title

• H01M8/04201

  Reactant storage and supply, e.g. means for feeding, pipes · CPC title