Reversible fuel cell oxygen electrode, reversibli fuel cell including the same, and method for preparing the same

Patent metadata

Field	Value
Publication number	US-10601052-B2
Application number	US-201615360034-A
Country	US
Kind code	B2
Filing date	Nov 23, 2016
Priority date	Dec 24, 2015
Publication date	Mar 24, 2020
Grant date	Mar 24, 2020

Abstract

Disclosed are a reversible fuel cell oxygen electrode in which IrO2 is electrodeposited and formed on a porous carbon material and platinum is applied thereon to form a porous platinum layer, a reversible fuel cell including the same, and a method for preparing the same. According to the corresponding reversible fuel cell oxygen electrode, as the loading amounts of IrO2 and platinum used in the reversible fuel cell oxygen electrode can be lowered, it is possible to exhibit excellent reversible fuel cell performances (excellent fuel cell performance and water electrolysis performance) by improving the mass transport of water and oxygen while being capable of reducing the loading amounts of IrO2 and platinum. Further, it is possible to exhibit a good activity of a catalyst when the present disclosure is applied to a reversible fuel cell oxygen electrode and to reduce corrosion of carbon.

First claim

What is claimed is:

1. A reversible fuel cell oxygen electrode comprising:
a porous carbon material;
IrO 2 formed on a surface of the porous carbon material; and
platinum formed on the IrO 2 ,
wherein the IrO 2 formed on the surface of the porous carbon comprises an IrO 2 layer or an IrO 2 layer having IrO 2 particles attached,
the platinum comprises a porous platinum layer formed on the IrO 2 layer of the IrO 2 layer having the IrO 2 particles attached, and
the electrode has macropores due to the porous carbon material and micropores due to the porous platinum layer.

2. The reversible fuel cell oxygen electrode according to claim 1 , wherein the porous carbon material is a hydrophilic porous carbon material.

3. The reversible fuel cell oxygen electrode according to claim 1 , wherein the porous carbon material has macropores due to inter-carbon fiber spaces,
carbon fiber strands on the surface of the porous carbon material are covered with the IrO 2 layer or the IrO 2 layer having the IrO 2 particles attached, and
the porous platinum layer is formed on the IrO 2 layer or the IrO 2 layer having the IrO 2 particles attached.

4. The reversible fuel cell oxygen electrode according to claim 3 , wherein the porous carbon material is a carbon paper.

5. The reversible fuel cell oxygen electrode according to claim 1 , wherein the IrO 2 layer has a carbon exposure-free structure in which the porous carbon material is not exposed.

6. The reversible fuel cell oxygen electrode according to claim 1 , wherein the IrO 2 layer has a crack-free structure.

7. The reversible fuel cell oxygen electrode according to claim 1 , wherein the electrode has a structure in which the micropores are connected to the macropores, and the macropores are connected to an interface of a membrane.

8. The reversible fuel cell oxygen electrode according to claim 1 , wherein the IrO 2 layer has a thickness of 0.01 to 1 μm, and the IrO 2 particles, if present, have a size of 0.1 to 3 μm.

9. The reversible fuel cell oxygen electrode according to claim 1 , wherein the IrO 2 is disposed on the surface of the porous carbon material in a range of 0.01 to 1.00 mg cm −2 .

10. The reversible fuel cell oxygen electrode according to claim 1 , wherein the porous platinum layer has a thickness of 0.5 to 3 μm.

11. The reversible fuel cell oxygen electrode according to claim 1 , wherein the platinum is disposed on the IrO 2 in a range of 0.01 to 1 mg cm −2 .

12. A reversible fuel cell comprising the oxygen electrode according to claim 1 .

13. A method for preparing the reversible fuel cell oxygen electrode according to claim 1 , the method comprising:
electrodepositing the IrO 2 on the surface of the porous carbon material; and
applying the platinum onto the IrO 2 -electrodeposited porous carbon material to form the porous platinum layer.

14. The method according to 13 , wherein when electrodeposition is performed on the porous carbon material, one or more of a deposition voltage and a deposition time are such that the deposition voltage is 0.6 to 0.8 V, and the deposition time is 3 to 30 minutes.

15. The method according to 13 , wherein the applying comprises spraying the platinum onto the IrO 2 electrodeposited porous carbon material.

16. A reversible fuel cell oxygen electrode comprising:
a macro-porous structure comprising a carbon material that forms pores in the macro-porous structure in a range of 1 to 100 micrometers;
IrO 2 covering the carbon material such that the pores in the macro-porous structure are substantially in a range of 1 to 100 micrometers; and
a micro-porous structure comprising platinum that covers a surface of the IrO 2 opposite the carbon material.

17. The reversible fuel cell oxygen electrode of claim 16 , wherein the IrO 2 covers the carbon material such that the entire surface of the macro-porous structure is covered by the IrO 2 .

18. The reversible fuel cell oxygen electrode of claim 16 , wherein the IrO 2 comprises IrO 2 particles on a IrO 2 layer.

19. The reversible fuel cell oxygen electrode of claim 18 , wherein the micro-porous structure covers the IrO 2 particles and the IrO 2 layer.

Assignees

• Korea Inst Sci & Tech

Inventors

• Jang Jong Hyun
• Lee Byungseok
• Park Hee-Young
• Kim Hyoung-Juhn
• Henkensmeier Dirk
• Yoo Sung Jong
• Kim Jin Young
• Lee So Young
• Ryu Jaeyune
• Yoon Sung Pil
• Han Jonghee
• Nam Suk Woo

Classifications

• H01M4/8657 Primary

  layered · CPC title

• H01M4/886

  Powder spraying, e.g. wet or dry powder spraying, plasma spraying · CPC title

• H01M4/926

  on carbon or graphite · CPC title

• H01M8/186

  by electrolytic decomposition of the electrolytic solution or the formed water product · CPC title

• H01M4/8615

  Bifunctional electrodes for rechargeable cells · CPC title