Geopolymer foam formulation for a non-flammable, sound-absorbing, thermally insulating geopolymer foam element

Patent metadata

Field	Value
Publication number	US-10597326-B2
Application number	US-201816235006-A
Country	US
Kind code	B2
Filing date	Dec 28, 2018
Priority date	Oct 31, 2013
Publication date	Mar 24, 2020
Grant date	Mar 24, 2020

Abstract

A geopolymer foam formulation, comprising at least one inorganic binder comprising metakaolin; at least one alkaline activator selected from the group consisting of alkali metal hydroxides, alkali metal carbonates, alkali metal aluminates, alkali metal silicates and mixtures thereof; at least one alkyl-polyglucoside surfactant; a gas phase and water. This formulation can also comprise a cement, and also additives for foam stabilization, shrinkage reduction, flexibilization, hydrophobization, or dispersion, fibres and fillers or a mixture thereof, and can be a single-component or two-component formulation. An incombustible, sound-absorbing, thermally insulating geopolymer foam element.

First claim

We claim:

1. A geopolymer foam formulation comprising:
at least one inorganic binder comprising metakaolin;
at least one alkaline activator selected from the group consisting of alkali metal hydroxides, alkali metal carbonates, alkali metal aluminates, alkali metal silicates and mixtures thereof;
at least one alkyl polyglucoside surfactant;
a gas phase and
water.

2. The formulation according to claim 1 , wherein the inorganic binder comprises metakaolin and fly ash.

3. The formulation according to claim 1 , wherein the inorganic binder comprises metakaolin, blast furnace slag and microsilica.

4. The formulation according to claim 1 , wherein the alkaline activator is selected from alkali metal hydroxides of the formula MOH; alkali metal silicates of the formula m SiO 2 .n M 2 O; and a mixture of alkali metal hydroxides and of alkali metal silicates; where M is the alkali metal, Li, Na, or K or a mixture thereof, and the molar ratio m:n is ≤4.0.

5. The formulation according to claim 1 , wherein the alkyl polyglucoside has the formula H—(C 6 H 10 O 5 ) m —O—R 1 , where (C 6 H 10 O 5 ) is a glucose unit and R 1 is a C 8-12 -alkyl group, and m=from 1 to 5.

6. The formulation according to claim 1 , wherein the formulation comprises
from 20 to 75% by weight of inorganic binder,
from 1 to 55% by weight of alkaline activator (calculated as solids content),
from 20 to 60% by weight of water (total quantity),
and also surfactant, gas phase and optionally other additives.

7. The formulation according to claim 1 , wherein the formulation comprises at most 20% by weight of a cement, Portland cement, calcium aluminate cement or a mixture thereof.

8. The formulation according to claim 1 , wherein the gas phase is selected from the group consisting of air, nitrogen, noble gas, hydrocarbons and mixtures thereof.

9. The formulation according to claim 1 , wherein from 20 to 90 percent by volume of the formulation consists of the gas phase.

10. The formulation according to claim 1 , wherein either all of the constituents are present together as a single component or solid constituents are held in a first, solid component and the water is held in a second, liquid component.

11. The formulation according to claim 1 , wherein the formulation also comprises at least one additive for foam stabilization, shrinkage reduction, flexibilization, hydrophobization, or dispersion; fibres, fillers, or a mixture thereof.

12. The formulation according to claim 11 , wherein the additive for foam stabilization is selected from the group consisting of fumed silica, proteins, rheology-modifying agents, starches, modified starches, poly(meth)acrylates bearing sulpho and/or quaternized ammonium groups, poly-(meth)acrylamides bearing sulpho and/or quaternized ammonium groups, and mixtures thereof.

13. The formulation according to claim 11 , wherein the additive for shrinkage reduction is selected from the group consisting of amines, alkanolamines, betaine(s), glycols, polyols, hollow aluminosilicate beads, hollow glass beads, foamed glass and mixtures thereof.

14. The formulation according to claim 11 , wherein the additive for flexibilization is selected from the group consisting of redispersible polymer powders, polyisocyanates, polyisocyanate prepolymers, epoxy resins, epoxy compounds and mixtures thereof.

15. The formulation according to claim 11 , wherein the additive for hydrophobization is selected from the group consisting of triglycerides, paraffins, polysiloxanes, hydrosilanes, alkoxysilanes, sodium methylsiliconate and mixtures thereof.

16. The formulation according to claim 11 , wherein the additive for dispersion is selected from the group consisting of comb polymers, polycarboxylate ethers, comb-shaped polyaromatic ethers, comb-shaped cationic copolymers and mixtures thereof.

17. The formulation according to claim 11 , wherein the fibres are selected from the group consisting of rock fibres, glass fibres, carbon fibres, optionally modified organic fibres, cellulose fibres, lignocellulose fibres, metal fibres and mixtures thereof.

18. The formulation according to claim 11 , wherein the fillers are selected from the group consisting of quartz sand, calcium carbonate, rock flour, low-density fillers, pigments, high-density fillers, metal salts and mixtures thereof.

19. An incombustible, sound-absorbing, thermally insulating geopolymer foam comprising the geopolymer foam formulation according to claim 1 .

20. The geopolymer foam element according to claim 19 , wherein the geopolymer foam element is in sheet form.

Assignees

• Construction Research & Technology Gmbh

Inventors

• Turcinskas Sarunas
• Mönnig Sven
• Pulkin Maxim
• Herth Gregor
• Zhou Shengzhong

Classifications

• C04B38/10

  by using foaming agents (C04B38/02 takes precedence){or by using mechanical means, e.g. adding preformed foam} · CPC title

• C04B2201/50

  for the mechanical strength · CPC title

• C04B22/062

  of the alkali or alkaline-earth metals · CPC title

• C04B2201/20

  for the density · CPC title

• C04B2103/408

  Dispersants · CPC title