Integrated methods for chemical synthesis

Patent metadata

Field	Value
Publication number	US-10597294-B2
Application number	US-201515314429-A
Country	US
Kind code	B2
Filing date	May 29, 2015
Priority date	May 30, 2014
Publication date	Mar 24, 2020
Grant date	Mar 24, 2020

Abstract

Among other things, the present invention encompasses the applicant's recognition that epoxide carbonylation can be performed industrially utilizing syngas streams containing hydrogen, carbon monoxide and varying amounts carbon dioxide. Contrary to expectation, the epoxide carbonylation reaction proceeds selectively in the presence of these mixed gas streams and incorporates excess CO in the syngas stream into valuable chemical precursors, resulting in hydrogen streams substantially free of CO. This is economically and environmentally preferable to performing WSGR which releases the excess carbon as CO2. The integrated processes herein therefore provide improved carbon efficiency for processes based on coal or biomass gasification or steam methane reforming.

First claim

What is claimed is:

1. A method for the integrated production of chemicals comprising:
a) in a first reaction zone, contacting an epoxide in the presence of a carbonylation catalyst with a syngas stream containing hydrogen and carbon monoxide to produce an epoxide carbonylation product, and
b) removing an upgraded gas stream from the first reaction zone, wherein the upgraded gas stream has a higher hydrogen to carbon monoxide ratio than the starting syngas stream.

2. The method of claim 1 , wherein the syngas stream has a molar hydrogen to carbon monoxide ratio between 0.5:1 and 1.2:1.

3. The method of claim 2 , wherein the upgraded gas stream has a hydrogen to carbon monoxide ratio of at least 1.9:1.

4. The method of claim 1 , wherein the syngas stream contains carbon dioxide.

5. The method of claim 1 , wherein the syngas stream is produced by biomass gasification.

6. The method of claim 1 , wherein the method further comprise, in a second reaction zone, utilizing the upgraded gas stream to conduct a second chemical process requiring a hydrogen to carbon monoxide ratio higher than the ratio in the syngas stream utilized in step a).

7. The method of claim 6 , wherein the second chemical process comprises Fischer Tropsch synthesis.

8. The method of claim 1 , wherein the epoxide carbonylation product is selected from the group consisting of: optionally substituted beta lactone, optionally substituted succinic anhydride, and a polyester resulting from alternating polymerization of carbon monoxide and the epoxide.

9. The method of claim 1 , wherein the epoxide is ethylene oxide.

10. The method of claim 1 , wherein the epoxide carbonylation product is beta propiolactone.

11. The method of claim 1 , wherein the epoxide carbonylation product is succinic anhydride.

12. The method of claim 11 , wherein the upgraded gas stream has a molar hydrogen to carbon monoxide ratio greater than 5:1.

13. The method claim 1 , wherein the upgraded gas stream has a hydrogen to carbon monoxide ratio greater than 10:1.

14. The method of claim 1 , wherein the upgraded gas stream is substantially free of carbon monoxide.

Assignees

• Novomer Inc

Inventors

• Sookraj Sadesh H
• Slowik Michael A

Classifications

• C07C51/09 Primary

  from carboxylic acid esters or lactones · CPC title

• B01J2531/822

  Rhodium · CPC title

• Y02P20/52

  using catalysts, e.g. selective catalysts · CPC title

• C10G2/30

  from carbon monoxide with hydrogen · CPC title

• B01J2531/025

  Ligands with a porphyrin ring system or analogues thereof, e.g. phthalocyanines, corroles · CPC title