Sinter-resistant stable catalyst systems by trapping of mobile platinum group metal (PGM) catalyst species

Patent metadata

Field	Value
Publication number	US-10596563-B2
Application number	US-201715418214-A
Country	US
Kind code	B2
Filing date	Jan 27, 2017
Priority date	Jan 27, 2017
Publication date	Mar 24, 2020
Grant date	Mar 24, 2020

Abstract

Methods of preparing a sinter-resistant catalyst include forming a dual coating system. A surface of a particulate catalyst support contacts a first liquid precursor including a metal salt with an element selected from the group consisting of: aluminum (Al), cerium (Ce), zirconium (Zr), titanium (Ti), silicon (Si), magnesium (Mg), zinc (Zn), and combinations thereof. The first liquid precursor precipitates or is adsorbed as an ion on a portion of the surface forming a first coating including a porous metal oxide on the surface. The surface may be contacted with a second liquid precursor including a metal oxide sol including a metal selected from the group consisting of: aluminum (Al), cerium (Ce), zirconium (Zr), iron (Fe), titanium (Ti), silicon (Si), and combinations thereof. A second coating is formed from the second liquid precursor on a portion of the surface to create the sinter-resistant catalyst system.

First claim

What is claimed is:

1. A method of preparing a sinter-resistant catalyst system, the method comprising:
contacting a surface of a catalyst support in a particulate form with a first liquid precursor comprising a metal salt comprising an element selected from the group consisting of: aluminum (Al), cerium (Ce), zirconium (Zr), titanium (Ti), silicon (Si), magnesium (Mg), zinc (Zn), and combinations thereof, wherein the surface of the catalyst support comprises at least one bound active catalyst particle disposed thereon prior to the contacting of the surface with the first liquid precursor;
precipitating or adsorbing the first liquid precursor on a portion of the surface of the catalyst support and calcining to form a first coating comprising a porous metal oxide on discrete regions of the surface;
contacting the surface having the first coating comprising the porous metal oxide on discrete regions with a second liquid precursor comprising a sol comprising a metal oxide selected from the group consisting of: aluminum (Al), cerium (Ce), zirconium (Zr), iron (Fe), titanium (Ti), silicon (Si), and combinations thereof, wherein the contacting the surface with the second liquid precursor occurs after the contacting the surface of a catalyst support in the particulate form with the first liquid precursor; and
forming a second coating comprising a porous metal oxide from the second liquid precursor on a portion of the surface of the catalyst support having the first coating comprising the porous metal oxide on discrete regions, so that the catalyst support comprises a dual coating comprising the first coating and the second coating to create the sinter-resistant catalyst system.

2. The method of claim 1 , further comprising applying the sinter-resistant catalyst system as a washcoat layer over a monolith substrate.

3. The method of claim 1 , wherein the active catalyst particle comprises a metal selected from the group consisting of: platinum (Pt), ruthenium (Ru), rhodium (Rh), palladium (Pd), osmium (Os), iridium (Ir), gold (Au), iron (Fe), nickel (Ni), manganese (Mn), and combinations thereof.

4. The method of claim 1 , wherein after the contacting of the surface of the catalyst support with a first liquid precursor, the method further comprises filtering the catalyst support in the particulate form from a liquid, drying the catalyst support, conducting the calcining, and then contacting of the surface with the second liquid precursor.

5. The method of claim 1 , wherein the calcining comprises heating to greater than or equal to about 300° C. to less than or equal to about 600° C. for greater than or equal to about 2 hours.

6. The method of claim 1 , wherein the catalyst support comprises a metal oxide selected from the group consisting of: aluminum oxide (Al 2 O 3 ), cerium oxide (CeO 2 ), zirconium oxide (ZrO 2 ), titanium dioxide (TiO 2 ), silicon dioxide (SiO 2 ), magnesium oxide (MgO), zinc oxide (ZnO), barium oxide (BaO), potassium oxide (K 2 O), sodium oxide (Na 2 O), calcium oxide (CaO), lanthanum oxide (La 2 O 3 ), and combinations thereof.

7. The method of claim 1 , wherein the metal salt is selected from the group consisting of: aluminum chloride (AlCl 3 ), aluminum nitrate (Al(NO 3 ) 3 ), aluminum hydroxide (Al(OH) 3 ), aluminum sulfate (Al 2 (SO 4 ) 3 ), aluminum chlorate (Al(ClO 3 ) 3 ), aluminum phosphate (AlPO 4 ), aluminum metaphosphate (Al(PO 3 ) 3 ), and combinations thereof.

8. The method of claim 1 , wherein prior to the contacting of the surface of the catalyst support with a first liquid precursor, the method further comprises pretreating the catalyst support by hydrothermally treating the catalyst support to a temperature of greater than or equal to about 800° C. to less than or equal to about 1,200° C. in the presence of water and air; and binding an active catalyst particle with the surface of the catalyst support.

9. A method of preparing a sinter-resistant catalyst system, the method comprising:
contacting a surface of a catalyst support in a particulate form with a first liquid precursor comprising a metal salt comprising aluminum (Al), wherein the surface of the catalyst support comprises at least one bound active catalyst particle disposed thereon prior to the contacting of the surface with the first liquid precursor;
precipitating or adsorbing the first liquid precursor on a portion of the surface of the catalyst support and calcining to form a first coating comprising a porous aluminum oxide on discrete regions of the surface;
contacting the surface having the first coating comprising the porous metal oxide on discrete regions with a second liquid precursor comprising a sol comprising a metal oxide selected from the group consisting of: aluminum (Al), cerium (Ce), zirconium (Zr), iron (Fe), titanium (Ti), silicon (Si), and combinations thereof, wherein the contacting the surface with the second liquid precursor occurs after the contacting the surface of a catalyst support in a particulate form with the first liquid precursor; and
forming a second coating comprising a porous metal oxide from the second liquid precursor on a portion of the surface of the catalyst support having the first coating comprising the porous metal oxide on discrete regions, so that the catalyst support comprises a dual coating comprising the first coating and the second coating to create the sinter-resistant catalyst system.

10. A method of preparing a sinter-resistant catalyst system, the method comprising:
contacting a surface of a catalyst support in a particulate form with a first liquid precursor comprising a metal salt comprising an element selected from the group consisting of: aluminum (Al), cerium (Ce), zirconium (Zr), titanium (Ti), silicon (Si), magnesium (Mg), zinc (Zn), and combinations thereof, wherein the surface of the catalyst support comprises at least one bound active catalyst particle disposed thereon prior to the contacting of the surface with the first liquid precursor;
precipitating or adsorbing the first liquid precursor on a portion of the surface of the catalyst support and calcining to form a first coating comprising a porous metal oxide on discrete regions of the surface;
contacting the surface having the first coating comprising the porous metal oxide on discrete regions with a second liquid precursor comprising a sol comprising a metal oxide selected from the group consisting of: aluminum (Al), cerium (Ce), zirconium (Zr), iron (Fe), titanium (Ti), and combinations thereof, wherein the contacting the surface with the second liquid precursor occurs after the contacting the surface of a catalyst support in a particulate form with the first liquid precursor; and
forming a second coating comprising a porous metal oxide from the second liquid precursor on a portion of the surface of the catalyst support having the first coating comprising the porous metal oxide on discrete regions, so that the catalyst support comprises a dual coating system comprising the first coating and the second coating to create the sinter-resistant catalyst system.

Assignees

• Gm Global Tech Operations Llc

Inventors

• Qi Gongshin
• Yang Ming
• Day Ryan J
• Xiao Xingcheng
• Li Wei

Classifications

• B01J37/08

  Heat treatment {(B01J37/0009, B01J37/0018 take precedence)} · CPC title

• B01J23/63

  with rare earths or actinides · CPC title

• B01J37/0242

  Coating followed by impregnation · CPC title

• B01J23/44 Primary

  Palladium · CPC title

• B01J37/035

  Precipitation on carriers · CPC title