Catalyst for preparing cumene and use thereof

Patent metadata

Field	Value
Publication number	US-10596552-B2
Application number	US-201816013553-A
Country	US
Kind code	B2
Filing date	Jun 20, 2018
Priority date	Jun 21, 2017
Publication date	Mar 24, 2020
Grant date	Mar 24, 2020

Abstract

Provided is a catalyst for preparing cumene and use thereof. The catalyst provided includes a carrier and an active ingredient. The active ingredient includes: ingredient (1), which is palladium element; and ingredient (2), which is one or more selected from a group consisting of alkali metal elements, alkaline earth metals and molybdenum element. When the catalyst is used for preparing cumene by α-methyl styrene hydrogenation, AMS conversion rate is high, and a product cumene has high selectivity.

First claim

The invention claimed is:

1. A catalyst for preparing cumene, comprising a carrier and an active ingredient, wherein the active ingredient comprises:
ingredient (1) that is palladium in elemental, salt, or oxide form, and
ingredient (2) comprising molybdenum and, optionally, an alkali metal, an alkaline earth metal, or both, wherein ingredient (2) is in salt or oxide form,
wherein, based on the weight of elemental metal, a content of palladium is 0.01-10 g/L and a mass ratio of ingredient (1) to ingredient (2) is in a range of (20-1):1, and wherein g/L is a unit representing a total mass of the active ingredient loaded on one liter of the carrier.

2. The catalyst according to claim 1 , wherein a content of ingredient (2) is in a range larger than 0 g/L and equal to or less than 60 g/L.

3. The catalyst according to claim 2 , wherein the content of ingredient (2) is 0.5-5 g/L.

4. The catalyst according to claim 3 , wherein the content of ingredient (2) is 1.0-3.5 g/L.

5. The catalyst according to claim 1 , wherein a mass ratio of ingredient (1) to ingredient (2) is (15-5):1.

6. The catalyst according to claim 5 , wherein the mass ratio of ingredient (1) to ingredient (2) is (12-8):1.

7. The catalyst according to claim 1 , wherein
ingredient (2) comprises an alkali metal and molybdenum, wherein, based on the weight of elemental metal, a mass ratio of the alkali metal to molybdenum is in a range of (0.1-10):1;
ingredient (2) comprises an alkaline earth metal and molybdenum; or
ingredient (2) comprises an alkali metal element, an alkaline earth metal element and molybdenum.

8. A method for preparing cumene, which comprises contacting a raw material containing α-methyl styrene and hydrogen with the catalyst according to claim 7 for reaction to generate cumene.

9. The catalyst according to claim 1 , wherein the alkaline earth metal element is at least one selected from the group consisting of Ca, Mg, Sr, and Ba, and the alkali metal element is at least one selected from the group consisting of Li, Na, and K.

10. The catalyst according to claim 1 , wherein the carrier comprises at least one selected from the group consisting of alumina, zirconia, silica, titania, and activated carbon.

11. The catalyst according to claim 1 , wherein the carrier has a BET specific surface area in a range of 60-200 m 2 /g, a pore volume in a range of 0.2-0.7 mL/g, and a most probable pore size in a range of 10-30 nm.

12. The catalyst according to claim 10 , wherein the alumina comprises δ-alumina, θ-alumina, or a mixture of the δ-alumina and the θ-alumina.

13. The catalyst according to claim 12 , wherein in the mixture of δ-alumina and θ-alumina, a mass ratio of δ-alumina to θ-alumina is in a range of (0.2-5.0):1.

14. A method for preparing cumene, comprising contacting a raw material containing α-methyl styrene and hydrogen with the catalyst according to claim 1 to generate cumene.

15. The method according to claim 14 , wherein the reaction is carried out under a pressure in a range of 0.2-3.0 MPa, at a temperature in a range of 30−100° C. at a ratio of liquid circulation of 1.0-10.0.

16. The method according to claim 14 , wherein a volume space velocity of the raw material containing α-methyl styrene is in a range of 0.3-3.0 h −1 , and a molar ratio of hydrogen to α-methyl styrene is in a range of (0.5-8):1.

17. The method according to claim 14 , wherein the raw material contains 1-25 wt % of α-methyl styrene and 75-99 wt % of a solvent.

18. The method according to claim 14 , wherein the raw material containing α-methyl styrene is from a device for producing phenol and acetone using cumene.

19. The catalyst according to claim 1 , wherein the content of ingredient (1) is 0.05-5 g/L.

20. The catalyst according to claim 1 , wherein the content of ingredient (1) is 0.1-4 g/L.

Assignees

• China Petroleum & Chem Corp
• Shanghai Res Inst Petrochemical Tech Sinopec

Inventors

• Liu Zhongneng
• Jiang Xinghua
• Gu Guoyao
• Li Zejun
• Yuan Dongping

Classifications

• B01J21/04

  Alumina · CPC title

• C07C15/085

  Isopropylbenzene · CPC title

• C07C2523/58

  with alkali- or alkaline earth metals or beryllium · CPC title

• B01J23/6525 Primary

  Molybdenum · CPC title

• C07C5/03

  of non-aromatic carbon-to-carbon double bonds · CPC title