Method and device to synthesize boron nitride nanotubes and related nanoparticles

Patent metadata

Field	Value
Publication number	US-10596542-B2
Application number	US-201615206143-A
Country	US
Kind code	B2
Filing date	Jul 8, 2016
Priority date	Mar 22, 2010
Publication date	Mar 24, 2020
Grant date	Mar 24, 2020

Abstract

Methods and apparatus for producing chemical nanostructures having multiple elements, such as boron and nitride, e.g. boron nitride nanotubes, are disclosed. The method comprises creating a plasma jet, or plume, such as by an arc discharge. The plasma plume is elongated and has a temperature gradient along its length. It extends along its length into a port connector area having ports for introduction of feed materials. The feed materials include the multiple elements, which are introduced separately as fluids or powders at multiple ports along the length of the plasma plume, said ports entering the plasma plume at different temperatures. The method further comprises modifying a temperature at a distal portion of or immediately downstream of said plasma plume; and collecting said chemical nanostructures after said modifying.

First claim

What is claimed is:

1. An apparatus comprising:
a plasma source configured to generate a plasma jet, the plasma source defining at least one port for the introduction of a first chemical-species proximate a region where the plasma jet is generated;
a port connector connected to the plasma source, the port connector configured to receive the plasma jet, the port connector defining at least one port along its length configured for the introduction of a second chemical-species to the plasma jet; and
a chamber connected to the port connector;
wherein the plasma source comprises a first and a second electrode;
wherein the second electrode is positioned distal to the first electrode and proximal to the port connector; and
wherein the first electrode is a conical tip electrode that extends towards an annular opening of the second electrode to form a nozzle.

2. The apparatus of claim 1 , wherein the plasma source further includes a source of electric potential connected to the two electrodes, wherein the source of electric potential is configured to generate an arc across the two electrodes.

3. The apparatus of claim 1 , further comprising:
a net positioned in the chamber configured to collect nanomaterials.

4. The apparatus of claim 1 , further comprising:
a quench moderator positioned in the chamber.

5. The apparatus of claim 4 , wherein the quench moderator is a cooled, inert member proximate the plasma jet and shaped as a linear rod, serpentine rod, or torus.

6. The apparatus of claim 4 , wherein the quench moderator is positioned in the plasma jet and configured to allow the plasma jet to pass by the quench moderator.

7. The apparatus of claim 1 , wherein the apparatus is configured to form nanostructures due to cooling of the plasma jet, and wherein the nanostructures comprise elements of the first and the second chemical-species introduced to the chamber.

8. An apparatus comprising:
a plasma source configured to generate a plasma jet, the plasma source defining a port for the introduction of a nitrogen-containing species proximate a region where the plasma jet is generated;
a port connector connected to the plasma source, the port connector configured to receive the plasma jet, the port connector defining a first port along its length, the first port configured for the introduction of a boron-containing species along the length of the plasma jet; and
a chamber connected to the port connector;
wherein the plasma source comprises a first and a second electrode;
wherein the second electrode is positioned distal to the first electrode and proximal to the port connector; and
wherein the first electrode is a conical tip electrode that extends towards an annular opening of the second electrode to form a nozzle.

9. The apparatus of claim 8 , wherein the plasma source further includes a source of electric potential connected to the two electrodes, wherein the source of electric potential is configured to generate an arc across the two electrodes to generate the plasma jet.

10. The apparatus of claim 8 , further comprising:
a net positioned in the chamber configured to collect nanomaterials.

11. The apparatus of claim 8 , further comprising:
a quench moderator positioned in the chamber.

12. The apparatus of claim 11 , wherein the quench moderator is a cooled, inert member proximate the plasma jet and shaped as a linear rod, serpentine rod, or torus.

13. The apparatus of claim 11 , wherein the quench moderator is positioned in the plasma jet and configured to allow the plasma jet to pass by the quench moderator.

14. The apparatus of claim 8 , wherein the apparatus is configured to form boron nitride nanostructures due to cooling of the plasma jet in the chamber.

15. The apparatus of claim 14 , wherein the boron nitride nanostructures are selected from a group consisting of boron nitride nanotubes, boron nitride spheres, and boron nitride sheets.

16. The apparatus of claim 8 , wherein the port connector defines a second port along its length, and wherein the second port is configured for the introduction of a carbon-containing species along the length of the plasma jet.

17. The apparatus of claim 8 , wherein the boron-containing species is selected from a group consisting of elemental born, a boron oxide, a boron sulfide, a boron nitride, and a boron halide.

18. The apparatus of claim 8 , wherein the nitrogen-containing species comprises nitrogen gas.

Assignees

• Univ California

Inventors

• Zettl Alexander K

Classifications

• B01J2219/0898

  Hot plasma · CPC title

• Y10S977/896

  Chemical synthesis, e.g. chemical bonding or breaking · CPC title

• B82Y40/00

  Manufacture or treatment of nanostructures · CPC title

• D01F9/08

  of inorganic material (working or processing of metal wire B21F; from softened glass, minerals or slags C03B37/00) · CPC title

• B01J19/088 Primary

  giving rise to electric discharges (for heating purposes H05B7/00; for the production of ozone C01B13/11, H01T19/00) · CPC title