Method for carrying out a heterogeneously catalysed reaction

Patent metadata

Field	Value
Publication number	US-10596539-B2
Application number	US-201716095065-A
Country	US
Kind code	B2
Filing date	Apr 13, 2017
Priority date	Apr 22, 2016
Publication date	Mar 24, 2020
Grant date	Mar 24, 2020

Abstract

A process for performing a heterogeneously catalysed reaction in a three-phase reactor, where there is at least one liquid phase, at least one gaseous phase and at least one solid phase in the reactor and the reactor has at least two zones, with the reaction mixture being conveyed downward in zone 1, the reaction mixture being conveyed upward in zone 2, zones 1 and 2 being separated from one another by a dividing wall, and in that the ratio between the average catalyst concentrations in zone 2 and in zone 1 is greater than 2.

First claim

The invention claimed is:

1. A process for performing a heterogeneously catalysed reaction in a three-phase reactor having at least one liquid phase, at least one gaseous phase and at least one solid phase, the process comprising:
conveying a reaction mixture downward in a first zone of the reactor; and then
conveying the reaction mixture upward in a second zone of the reactor,
wherein the first and second zones are separated from one another by a dividing wall,
the first zone is substantially free of undissolved gas, and
a ratio of an average catalyst concentration in the second zone to an average catalyst concentration in the first zone is greater than 2.

2. The process according to claim 1 , wherein the ratio of the average catalyst concentrations in the second to first zone is greater than 5.

3. The process according to claim 1 , wherein the gas required for the process, in the course of operation, is metered in in the finely dispersed state from a lower portion of the reactor.

4. The process according to claim 1 , wherein a ratio of a catalyst concentration in the second zone at 90% of a fill height of the reactor measured from a bottom of the reactor to a catalyst concentration at 20% of the fill height measured from the bottom is less than 0.3.

5. The process according to claim 1 , wherein a ratio of an average vertical flow rate in the first zone to an average vertical flow rate in the second zone is between 5 and 50.

6. The process according to claim 1 , wherein a ratio of a reactor diameter in an upper portion to a reactor diameter in a lower portion is between 1 and 2.

7. The process according to claim 1 , wherein a ratio of a diameter in an upper portion of the first zone to a diameter in a lower portion of the first zone is between 1 and 5.

8. The process according to claim 1 , wherein the reaction mixture is conveyed downward in the first zone by at least one pump or at least one stirrer.

9. The process according to claim 1 , wherein at least one liquid feed stream is introduced into an upper portion of the first zone.

10. The process according to claim 1 , wherein at least one continuously operable and back-washable filter is installed in an upper portion of the second zone.

11. The process according to claim 1 , wherein the reaction mixture is discharged continuously from the reactor and filtered through at least one external filter and the catalyst is passed back into the reactor after the filtration.

12. The process according to claim 1 , wherein the second zone is divided into at least two segments by dividing walls, and at least one gas is metered in and finely distributed in a lower portion of the second zone.

13. The process according to claim 1 , wherein the heterogeneously catalysed reaction is an oxidation reaction with an oxygen-containing gas.

14. The process according to claim 1 , wherein a ratio of an oxygen concentration in the gas phase of the second zone at 20% of a fill height of the reactor measured from a bottom of the reactor to an oxygen concentration in the gas phase of the second zone at 90% of the fill height measured from the bottom is greater than 2.

15. The process according to claim 1 , wherein the heterogeneously catalysed reaction is a continuous oxidative esterification of methacrolein with oxygen and methanol for preparation of methyl methacrylate.

16. A process for performing a continuous oxidative esterification of methacrolein with oxygen and methanol for preparation of methyl methacrylate in a three-phase reactor having at least one liquid phase, at least one gaseous phase and at least one solid phase, the process comprising:
conveying a reaction mixture downward in a first zone of the reactor; and
conveying the reaction mixture upward in a second zone of the reactor,
wherein the first and second zones are separated from one another by a dividing wall, and
a ratio of an average catalyst concentration in the second zone to an average catalyst concentration in the first zone is greater than 2.

Assignees

• Evonik Roehm Gmbh
• Roehm Gmbh

Inventors

• Lygin Alexander
• Groemping Matthias
• Krill Steffen

Classifications

• B01J2219/1943

  cylindrical · CPC title

• B01J2208/00867

  inside the bed, e.g. rotary mixer · CPC title

• B01J2208/00761

  Discharging · CPC title

• B01J8/006

  by filtration · CPC title

• B01J2208/00752

  Feeding · CPC title