Anaerobic aluminum-water electrochemical cell

Patent metadata

Field	Value
Publication number	US-10594010-B2
Application number	US-201314096810-A
Country	US
Kind code	B2
Filing date	Dec 4, 2013
Priority date	Dec 4, 2012
Publication date	Mar 17, 2020
Grant date	Mar 17, 2020

Abstract

An anaerobic aluminum-water electrochemical cell includes electrode stacks, each electrode stack having an aluminum or aluminum alloy anode, and at least one solid cathode configured to be electrically coupled to the anode. The cell further includes a liquid electrolyte between the anode and the at least one cathode, one or more physical separators between each electrode stack adjacent to the cathode, a housing configured to hold the electrode stacks, the electrolyte, and the physical separators, and a water injection port, in the housing, configured to introduce water into the housing.

First claim

What is claimed is:

1. An anaerobic aluminum-water electrochemical cell comprising: a plurality of electrode stacks, each electrode stack comprising an aluminum alloy anode in the form of a plate, the plate having a first side and a second side opposite to the first side, the aluminum alloy anode comprising Ga, In, Sn, Mg, or combinations thereof, and at least one solid cathode disposed directly next to the first side of the plate and at least one cathode disposed directly next to the second side of the plate, wherein the cathode on the first side and the cathode on the second side are configured to be electrically coupled to the anode, the at least one cathode using water as an oxidant; a liquid electrolyte comprising 90 wt % of water or less between the anode and the at least one cathode, the liquid electrolyte including an alkaline solution of water or seawater comprising at least one added hydroxide base at a concentration of 0.5 M to 5 M; one or more physical separators separating each one of the electrode stacks, positioned between the cathode on the first side of one electrode stack and the cathode on the second side of an adjacent electrode stack; a housing configured to hold the electrode stacks, the electrolyte, and the physical separators; and an electrolyte injection port, in the housing, configured to introduce the electrolyte into the housing, so that the electrolyte flows through the physical separators.

2. The electrochemical cell according to claim 1 , wherein the anode is a solid plate of material.

3. The electrochemical cell according to claim 1 , wherein the electrolyte includes seawater.

4. The electrochemical cell according to claim 1 , wherein the one or more physical separators are formed from a mesh material having openings of about 100 μm or larger.

5. An aluminum-water electrochemical system comprising: an aluminum-water electrochemical cell according to claim 1 ; a waste separation system in fluid communication with the housing and configured to receive the electrolyte and aluminum hydroxide waste from the aluminum-water electrochemical cell and to separate the aluminum hydroxide waste from the electrolyte; and a fuel injector, in fluid communication with the waste separation system and the electrolyte injection port, configured to receive the electrolyte from the waste separation system and to provide the electrolyte to the electrolyte injection port.

6. The electrochemical system according to claim 5 , wherein the fuel injector is further configured to receive water from a water supply.

7. The electrochemical system according to claim 5 , wherein the electrolyte includes seawater.

8. The electrochemical system according to claim 5 , wherein the waste separation system is configured to remove the aluminum hydroxide waste from the electrolyte.

9. The electrochemical system according to claim 5 , wherein the one or more physical separators are formed from a mesh material having openings of about 100 μm or larger.

10. The electrochemical system according to claim 5 , wherein the anode is in a liquid phase and the housing includes an aluminum port configured to introduce the aluminum or aluminum alloy material in a solid phase into the housing.

11. The electrochemical system according to claim 5 , wherein the electrochemical cell is configured to allow the electrolyte, comprising the aluminum hydroxide waste, to be pumped from the housing to the waste separation system.

12. The electrochemical cell according to claim 1 , wherein the at least one hydroxide base includes one or more alkali hydroxides.

13. The electrochemical cell according to claim 12 , wherein the one or more alkali hydroxides are selected from the group consisting of NaOH, KOH, and combinations thereof.

14. The electrochemical cell according to claim 1 , wherein the liquid electrolyte has a hydroxide concentration of 1 M to 5 M.

15. A method for generating an electric current and producing hydrogen, comprising: introducing the electrolyte between the anode and the at least one cathode of the electrode stacks of the electrochemical cell of claim 1 ; anaerobically oxidizing the aluminum alloy of the electrode stacks; and electrochemically reducing water at the at least one cathode of the electrode stacks.

16. The method of claim 15 , wherein the cell generates at least 90% of the hydrogen it produces at the at least one cathode.

Assignees

• Massachusetts Inst Technology

Inventors

• Mckay Ian Salmon
• Macdonald Ruaridh R
• Milnes Thomas B

Classifications

• H01M4/463

  Aluminium based · CPC title

• H01M12/08 Primary

  composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type · CPC title

• H01M14/00

  Electrochemical current or voltage generators not provided for in groups H01M6/00 - H01M12/00; Manufacture thereof · CPC title

• H01M6/32

  activated through external addition of electrolyte or of electrolyte components · CPC title

• H01M6/34

  Immersion cells, e.g. sea-water cells · CPC title