Co-precipitation reactor and method of manufacturing material precursor for secondary battery using the same

Patent metadata

Field	Value
Publication number	US-10593944-B2
Application number	US-201514816180-A
Country	US
Kind code	B2
Filing date	Aug 3, 2015
Priority date	Dec 24, 2014
Publication date	Mar 17, 2020
Grant date	Mar 17, 2020

Abstract

A co-precipitation reactor for manufacturing a positive electrode active material precursor for a secondary battery, the co-precipitation reactor including a reaction chamber having a plurality of suppliers configured to direct a reaction material and a pH adjusting material into the reaction chamber, a stirrer configured to be disposed in the reaction chamber, a drive motor configured to rotate the stirrer, a stirring shaft configured to receive power from the drive motor and rotate the stirrer, a first heater configured to heat an outside of the reaction chamber to heat the reaction material and the pH adjusting material, and a second heater configured to heat an inside of the reaction chamber to heat the reaction material and the pH adjusting material.

First claim

What is claimed is:

1. A co-precipitation reactor for manufacturing a positive electrode active material precursor for a secondary battery, the co-precipitation reactor comprising:
a reaction chamber having a plurality of suppliers configured to direct a reaction material and a pH adjusting material into the reaction chamber;
a stirrer configured to be disposed in the reaction chamber;
a drive motor configured to rotate the stirrer;
a stirring shaft configured to receive power from the drive motor and rotate the stirrer;
a first heater configured to heat an outside of the reaction chamber;
a first controller configured to control the first heater;
a second heater configured to heat an inside of the reaction chamber; and
a second controller configured to control the second heater,
wherein the second controller is configured to control the second heater to operate according to a temperature gradient of the reaction material and the pH adjusting material in a region adjacent to a center and adjacent to an exterior wall of the reaction chamber.

2. The co-precipitation reactor of claim 1 , wherein the second heater is disposed inside the stirring shaft and is further configured to heat an exterior surface of the stirring shaft to heat the reaction material and the pH adjusting material when present.

3. The co-precipitation reactor of claim 2 , wherein the second heater and the stirring shaft extend in a longitudinal direction of the reaction chamber and are disposed in a center portion of the reaction chamber.

4. The co-precipitation reactor of claim 2 , wherein the second heater is a heat pipe.

5. The co-precipitation reactor of claim 2 , wherein the second heater is a heat wire.

6. The co-precipitation reactor of claim 1 , wherein the stirring shaft is connected to an output portion of the drive motor at an angle of 90 degrees, and wherein the output portion is configured to transmit power to the stirring shaft.

7. The co-precipitation reactor of claim 1 , wherein the stirrer comprises a raising screw fixed to the stirring shaft and configured to make the reaction material and the pH adjusting material move upward, and a lowering impeller fixed to the stirring shaft and disposed in a lower portion of the raising screw and configured to make the reaction material and the pH adjusting material move downward.

8. The co-precipitation reactor of claim 1 , wherein the reaction material comprises a metal salt solution comprising nickel, cobalt, and manganese, and wherein the positive electrode active material precursor for the secondary battery is represented by Formula 1:
Li a Ni 1-x-y-z Co x Mn y M z O 2-δ X δ   Formula 1

wherein 0.95≤a≤1.2, 0.01≤x≤0.5, 0.01≤y≤0.5, 0.005≤z≤0.3, 0.05≤x+y+z≤0.6, 0≤δ≤0.1, M denotes at least one element selected from magnesium, aluminum, chromium, vanadium, titanium, iron, zirconium, zinc, silicon, yttrium, niobium, gallium, tin, molybdenum, and tungsten, and X denotes a halogen element and sulfur.

9. The co-precipitation reactor of claim 1 , wherein a pH of the positive electrode active material precursor for a secondary battery formed by adding a sodium hydroxide solution or an ammonia aqueous solution to the reaction material is 11 to 12, and
wherein the pH adjusting material is a sodium hydroxide solution.

Assignees

• Samsung Electronics Co Ltd
• Samsung Fine Chemicals Co Ltd
• Samsung Sdi Co Ltd

Inventors

• Son Youhwan
• Park Kwangjin
• Hong Jinseok

Classifications

• C01G53/00

  Compounds of nickel · CPC title

• B01J2219/00229

  of the reaction system · CPC title

• H01M4/582

  Halogenides · CPC title

• B01J2219/00078

  Fingers · CPC title

• H01M4/5815 Primary

  Sulfides · CPC title