Perovskites as ultra-low work function electron emission materials
US-2017207055-A1 · Jul 20, 2017 · US
US10593505B1 · US · B1
| Field | Value |
|---|---|
| Publication number | US-10593505-B1 |
| Application number | US-201816203524-A |
| Country | US |
| Kind code | B1 |
| Filing date | Nov 28, 2018 |
| Priority date | Nov 28, 2018 |
| Publication date | Mar 17, 2020 |
| Grant date | Mar 17, 2020 |
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Thermionic cathodes and an electron emission apparatus are provided. The thermionic cathodes comprise perovskite material in crystal or sintered form. The thermionic cathodes provide strong electron emission at low operating temperatures.
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The invention claimed is: 1. A thermionic cathode, comprising: an emitter consisting of a perovskite material in crystal or sintered form, wherein an operating temperature of the thermionic cathode is in a range from 900° C. to 1500° C., wherein the perovskite material has a formula ABO3, where A is strontium and B is selected from vanadium (V), Niobium (Nb), and combinations thereof. 2. The thermionic cathode of claim 1 , wherein an emission current density of the emitter is 0.045 A/cm2 and the operating temperature is 1650 K. 3. The thermionic cathode of claim 1 , wherein the perovskite material exhibits a work function of less than 1.90 eV. 4. The thermionic cathode of claim 3 , wherein the perovskite material exhibits a work function in the range of 1.80 eV to 1.90 eV. 5. The thermionic cathode of claim 1 , wherein the perovskite material is strontium vanadate (SrVO3). 6. The thermionic cathode of claim 1 , wherein the perovskite material is strontium niobate (SrNbO3). 7. The thermionic cathode of claim 1 , wherein the emitter consists of a perovskite crystal and the crystal has a crystallographic orientation of (100). 8. The thermionic cathode of claim 1 , further comprising a non-emissive coating on an outer surface of sides of the emitter. 9. The thermionic cathode of claim 8 , wherein the non-emissive coating is a carbon coating. 10. The thermionic cathode of claim 1 , wherein the operating temperature of the thermionic cathode is in a range from 1000° C. to 1400° C. 11. The thermionic cathode of claim 1 , wherein the emitter has a cylindrical main body and the cylindrical main body has an upper section including an electron emitting surface. 12. The thermionic cathode of claim 11 , wherein the electron emitting surface is flat. 13. The thermionic cathode of claim 11 , wherein the upper section has a truncated conical shape. 14. The thermionic cathode of claim 12 , wherein the electron emitting surface has an area in a range from 30 μm to 250 μm. 15. An electron emission apparatus, comprising: a thermionic cathode, including an emitter consisting of perovskite material in crystal or sintered form; a heat source operably connected to the thermionic cathode and configured to provide heat to the emitter; and a support for the emitter, wherein the perovskite material has a formula ABO3, where A is strontium and B is selected from vanadium (V), Niobium (Nb), and combinations thereof. 16. The electron emission apparatus of claim 15 , further comprising: an anode disposed above the emitter. 17. A thermionic cathode, comprising: an emitter comprising a coating consisting of a sintered perovskite material, wherein an operating temperature of the thermionic cathode is in a range from 900° C. to 1500° C. and the sintered perovskite material has a formula ABO3, where A is strontium and B is selected from vanadium (V), Niobium (Nb), and combinations thereof. 18. The thermionic cathode of claim 17 , wherein the sintered perovskite material is strontium vanadate and the operating temperature is in a range from 150 K to 1310K.
Cathodes heated directly by an electric current · CPC title
characterised by the material · CPC title
Lithography · CPC title
Source emittance characteristics · CPC title
Thermionic sources · CPC title
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