Dielectric powder and multilayer capacitor using the same

Patent metadata

Field	Value
Publication number	US-10593482-B2
Application number	US-201715654249-A
Country	US
Kind code	B2
Filing date	Jul 19, 2017
Priority date	Dec 28, 2016
Publication date	Mar 17, 2020
Grant date	Mar 17, 2020

Abstract

A dielectric powder includes a core-shell structure including a core region formed in an inner portion thereof and a shell region covering the core region. The core region includes barium titanate (BaTiO 3 ) doped with a metal oxide, and the shell region is formed of a ferroelectric material.

First claim

What is claimed is:

1. A dielectric powder comprising a core-shell structure including a core region formed in an inner portion thereof and a shell region covering the core region,
wherein the core region includes barium titanate (BaTiO 3 ) doped with a metal oxide, wherein the metal oxide comprises at least one selected from the group consisting of Dy, Ce, Al, La, Bi and Cu, and
the shell region is formed of a ferroelectric material.

2. The dielectric powder of claim 1 , further comprising:
a coating layer including a heterogeneous element and covering a surface of the shell region,
wherein the heterogeneous element includes at least one of Sr, Sn, Dy, Mg, Mn, Na, and Si.

3. The dielectric powder of claim 2 , wherein the coating layer has a thickness within a range of 1 to 2 nm.

4. The dielectric powder of claim 2 , wherein the coating layer is formed by reacting a monomolecular adsorbent including an alkali metal comprising at least one selected from the group consisting of sodium (Na), potassium (K) and lithium (Li).

5. The dielectric powder of claim 1 , wherein the core region has a diameter larger than a thickness of the shell region.

6. The dielectric powder of claim 1 , wherein the core region has a diameter of 60 nm or less, and the shell region has a thickness within a range of 10 to 40 nm.

7. The dielectric powder of claim 1 , wherein a total diameter of the core region and the shell region is 100 nm or less.

8. The dielectric powder of claim 1 , wherein the core region is formed by grain growth of the barium titanate (BaTiO 3 ) doped with the metal oxide.

9. The dielectric powder of claim 1 , wherein the core region further includes at least one of lanthanum (La), strontium (Sr), or calcium (Ca).

10. The dielectric powder of claim 1 , wherein the core-shell structure is configured in a block shape.

11. The dielectric powder of claim 1 , wherein a content of the metal oxide included in the core region is 0.1 to 2.0 mol % based on TiO 2 added to the core region.

12. A multilayer capacitor comprising:
a body including a plurality of dielectric layers and first and second internal electrodes alternately disposed with the dielectric layer interposed therebetween; and
first and second external electrodes disposed to be electrically connected to exposed portions of the first and second internal electrodes in the body, respectively;
wherein the dielectric layer includes a dielectric powder having a core-shell structure including a core region formed in an inner portion thereof and a shell region covering the core region,
the core region includes barium titanate (BaTiO 3 ) doped with a metal oxide, wherein the metal oxide comprises at least one selected from the group consisting of Dy, Ce, Al, La, Bi and Cu, and
the shell region is formed of a ferroelectric material.

13. The multilayer capacitor of claim 12 , wherein the dielectric powder further includes a coating layer including a heterogeneous element and covering a surface of the shell region, and the heterogeneous element includes at least one of Sr, Mn, or Na.

14. The multilayer capacitor of claim 12 , wherein, in the dielectric powder, the core region has a diameter larger than a thickness of the shell region.

15. The multilayer capacitor of claim 12 , wherein, in the dielectric powder, the core region has a diameter of 60 nm or less, and the shell region has a thickness within a range of 10 to 40 nm.

16. The multilayer capacitor of claim 12 , wherein in the dielectric powder, a total diameter of the core region and the shell region is 100 nm or less.

Assignees

• Samsung Electro Mech

Inventors

• Park Chang Hwa
• Kim Jin Woo
• Sin Min Gi
• Park Byung Hyun
• Kim Chin Mo

Classifications

• C01P2004/84

  one phase coated with the other · CPC title

• C01F11/02

  Oxides or hydroxides (production of lime C04B2/00) · CPC title

• H01G4/1227 Primary

  based on alkaline earth titanates · CPC title

• C01G23/006

  Alkaline earth titanates · CPC title

• C01P2004/64

  Nanometer sized, i.e. from 1-100 nanometer · CPC title