Polymer product in particle form and its use

Patent metadata

Field	Value
Publication number	US-10590604-B2
Application number	US-201615546069-A
Country	US
Kind code	B2
Filing date	Jan 26, 2016
Priority date	Jan 27, 2015
Publication date	Mar 17, 2020
Grant date	Mar 17, 2020

Abstract

The invention relates to a water-soluble polymer product in particle form, comprising amphoteric polyacrylamide, which is obtained by gel polymerisation of acrylamide together with anionic and cationic monomers. The amphoteric polyacrylamide has a mass average molecular weight MW of 1 500 000-6 000 000 g/mol, and a total ionicity of 4-15 mol-%, whereby the polymer product has a polymer content of at least 60 weight-%. The invention relates also to uses of the polymer product in paper and board making.

First claim

The invention claimed is:

1. A water-soluble polymer product in a particle form, comprising: amphoteric polyacrylamide obtained by gel polymerisation of acrylamide together with anionic and cationic monomers, and which amphoteric polyacrylamide has:
a mass average molecular weight MW in a range of 2,500,000-4,500,000 g/mol, and
a total ionicity of 4-15 mol-%,
wherein the polymer product has a polymer content of at least 60 weight-%.

2. The polymer product according to claim 1 , wherein the amphoteric polyacrylamide is a linear polyacrylamide.

3. The polymer product according to claim 1 , wherein the polymer product has the polymer content in a range of 70-98 weight-%.

4. The polymer product according to claim 1 , wherein the amphoteric polyacrylamide has a net cationic charge.

5. The polymer product according to claim 1 , wherein 10-90% of the charged groups in the amphoteric polyacrylamide are cationic.

6. The polymer product according to claim 1 , wherein the total ionicity of the amphoteric polyacrylamide is in a range of 5-13 mol-%.

7. The polymer product according to claim 1 , wherein the cationic groups in the amphoteric polyacrylamide originate from monomers selected from 2-(dimethylamino)ethyl acrylate (ADAM), [2-(acryloyloxy)ethyl] trimethylammonium chloride (ADAM-Cl), 2-(dimethylamino)ethyl acrylate benzylchloride, 2-(dimethylamino)ethyl acrylate dimethylsulphate, 2-dimethylaminoethyl methacrylate (MADAM), [2-(methacryloyloxy)ethyl] trimethylammonium chloride (MADAM-Cl), 2-dimethylaminoethyl methacrylate dimethylsulphate, [3-(acryloylamino)propyl] trimethylammonium chloride (APTAC), [3-(methacryloylamino)propyl] trimethylammonium chloride (MAPTAC) or diallyldimethylammonium chloride (DADMAC), and/or the anionic groups in the amphoteric polyacrylamide originate from monomers selected from unsaturated mono- or dicarboxylic acids, being acrylic acid, maleic acid, fumaric acid, itaconic acid, aconitic acid, mesaconic acid, citraconic acid, crotonic acid, isocrotonic acid, angelic acid or tiglic acid.

8. The polymer product according to claim 1 , wherein the polymer product has a particle size <2.5 mm.

9. A method for treating a fibre stock in paper and/or board making, the method comprising:
dissolving the water-soluble polymer product in a particle form according to claim into water, whereby an aqueous treatment solution is obtained,
adding the obtained treatment solution to the fibre stock, and
forming a fibrous web.

10. The method according to claim 9 , wherein the treatment solution is added to the fibre stock comprising recycled fibres, or to a thick stock.

11. The polymer product according to claim 1 , wherein the mass average molecular weight of the amphoteric polyacrylamide is in a range of 2,700,000-4,300,000 g/mol.

12. The polymer product according to claim 1 , wherein the polymer product has the polymer content in a range of 75-95 weight-%.

13. The polymer product according to claim 1 , wherein the polymer product has the polymer content in a range of 80-95 weight-%.

14. The polymer product according to claim 1 , wherein the polymer product has the polymer content in a range of 85-93 weight-%.

15. The polymer product according to claim 1 , wherein 30-90% of the charged groups in the amphoteric polyacrylamide are cationic.

16. The polymer product according to claim 1 , wherein 50-85% of the charged groups in the amphoteric polyacrylamide are cationic.

17. The polymer product according to claim 1 , wherein 60-80% of the charged groups in the amphoteric polyacrylamide are cationic.

18. The polymer product according to claim 1 , wherein the total ionicity of the amphoteric polyacrylamide is in a range of 6-12 mol-%.

Assignees

• Kemira Oyj

Inventors

• Karppi Asko
• Hietaniemi Matti
• Lepo Anneli
• Strengell Kimmo

Classifications

• D21H17/42

  anionic · CPC title

• D21H17/375 Primary

  Poly(meth)acrylamide · CPC title

• D21H17/37 Primary

  Polymers of unsaturated acids or derivatives thereof, e.g. polyacrylates · CPC title

• D21H21/10

  Retention agents or drainage improvers · CPC title

• D21H17/44 Primary

  cationic · CPC title