Opacifiers for detergent compositions

Patent metadata

Field	Value
Publication number	US-10590366-B2
Application number	US-201615754669-A
Country	US
Kind code	B2
Filing date	Nov 14, 2016
Priority date	Dec 10, 2015
Publication date	Mar 17, 2020
Grant date	Mar 17, 2020

Abstract

Provided is a detergent composition that contains an opacifier with improved opacifying characteristics. The composition comprises an opacifier, a surfactant, a solvent, and optionally a builder, wherein the opacifier is an aqueous dispersion of voided latex particles have a composition as described herein.

First claim

What is claimed is:

1. A detergent composition comprising: an opacifier, a surfactant, a solvent, and optionally a builder, wherein the opacifier is an aqueous dispersion of voided latex particles comprising:
(i) at least one core polymer comprising polymerized units derived from
(a) 5 to 100 percent by weight, based on the weight of the core polymer, of at least one hydrophilic monoethylenically unsaturated monomer selected from the group consisting of acrylic acid, methacrylic acid, acryloxypropionic acid, (meth)acryloxypropionic acid, itaconic acid, aconitic acid, maleic acid or anhydride, fumaric acid, crotonic acid, monomethyl maleate, monomethyl fumarate, monomethyl itaconate and mixtures thereof, and
(b) from 0 to 95 percent by weight, based on the weight of the core polymer, of at least one nonionic monoethylenically unsaturated monomer selected from the group consisting of vinyl toluene, ethylene, vinyl acetate, vinyl chloride, vinylidene chloride, (meth)acrylonitrile, (meth)acrylamide, C 1-20 alkyl or C 3-20 alkenyl esters of (meth)acrylic acid and mixtures thereof; and

(ii) at least one shell polymer comprising polymerized units derived from at least 50 percent by weight, based on the total weight of the shell polymer, of at least one nonionic monoethylenically unsaturated monomer selected from the group consisting of styrene, α-methyl styrene, p-methyl styrene, t-butyl styrene, vinyl toluene, ethylene, vinyl acetate, vinyl chloride, vinylidene chloride, (meth)acrylonitrile, (meth)acrylamide and C 1-20 alkyl or C 3-20 alkenyl esters of (meth)acrylic acid,
wherein the voided latex particles contain a void with a void fraction of 25 to 50%; and wherein the voided latex particles have a particle size of from 50 nm to 1000 nm.

2. The detergent composition of claim 1 , wherein
the hydrophilic monoethylenically unsaturated monomer of the at least one core polymer is selected from the group consisting of acrylic acid, methacrylic acid and mixtures thereof, and
the nonionic monoethylenically unsaturated monomer of the at least one core polymer is selected from the group consisting of methyl (meth)acrylate, ethyl (meth)acrylate, butyl (meth)acrylate, 2-ethylhexyl (meth)acrylate, hydroxyethyl (meth)acrylate, hydroxypropyl (meth)acrylate, benzyl (meth)acrylate, lauryl (meth)acrylate, oleyl (meth)acrylate, palmityl (meth)acrylate, stearyl (meth)acrylate and mixtures thereof.

3. The detergent composition of claim 1 , wherein the voided latex particles further comprise an intermediate stage polymer.

4. The detergent composition of claim 3 , wherein the intermediate stage polymer comprises, as polymerized units, (a) from 0.3 to 20 percent by weight, based on the weight of the intermediate stage polymer, of at least one hydrophilic monoethylenically unsaturated monomer selected from the group consisting of acrylic acid, methacrylic acid, acryloxypropionic acid, (meth)acryloxypropionic acid, itaconic acid, aconitic acid, maleic acid or anhydride, fumaric acid, crotonic acid, monomethyl maleate, monomethyl fumarate, monomethyl itaconate and mixtures thereof, and (b) from 80 to 99.7 percent by weight, based on the weight of the intermediate stage polymer, of at least one nonionic monoethylenically unsaturated monomer selected from the group consisting of vinyl toluene, ethylene, vinyl acetate, vinyl chloride, vinylidene chloride, (meth)acrylonitrile, (meth)acrylamide and C 1-20 alkyl or C 3-20 alkenyl esters of (meth)acrylic acid.

5. The detergent composition of claim 1 wherein the voided latex particles are present in an amount of 0.02 to 1.5 wt % solids based on the total weight of the detergent composition.

6. The detergent composition of claim 1 , wherein the detergent composition is a unit dose laundry or unit dose dishwashing detergent, wherein the detergent composition comprises no more than 25 wt % water based on the total weight of the detergent composition and wherein the detergent composition is encased in a water soluble pouch or film.

7. The detergent composition of claim 1 that is an aqueous dishwashing or laundry detergent.

8. A detergent packet comprising the detergent composition of claim 1 encased in a water soluble pouch or film.

9. A method for providing opacity to a detergent composition containing a surfactant, a solvent, and optionally a builder, the method comprising including in the detergent composition an opacifier, wherein the opacifier is an aqueous dispersion of voided latex particles comprising:
(i) at least one core polymer comprising polymerized units derived from
(a) 5 to 100 percent by weight, based on the weight of the core polymer, of at least one hydrophilic monoethylenically unsaturated monomer selected from the group consisting of acrylic acid, methacrylic acid, acryloxypropionic acid, (meth)acryloxypropionic acid, itaconic acid, aconitic acid, maleic acid or anhydride, fumaric acid, crotonic acid, monomethyl maleate, monomethyl fumarate, monomethyl itaconate and mixtures thereof, and
(b) from 0 to 95 percent by weight, based on the weight of the core polymer, of at least one nonionic monoethylenically unsaturated monomer selected from the group consisting of vinyl toluene, ethylene, vinyl acetate, vinyl chloride, vinylidene chloride, (meth)acrylonitrile, (meth)acrylamide, C 1-20 alkyl or C 3-20 alkenyl esters of (meth)acrylic acid and mixtures thereof; and

(ii) at least one shell polymer comprising polymerized units derived from at least 50 percent by weight, based on the total weight of the shell polymer, of at least one nonionic monoethylenically unsaturated monomer selected from the group consisting of styrene, α-methyl styrene, p-methyl styrene, t-butyl styrene, vinyl toluene, ethylene, vinyl acetate, vinyl chloride, vinylidene chloride, (meth)acrylonitrile, (meth)acrylamide and C 1-20 alkyl or C 3-20 alkenyl esters of (meth)acrylic acid,
wherein the voided latex particles contain a void with a void fraction of 25 to 50%; and wherein the voided latex particles have a particle size of from 50 nm to 1000 nm.

Assignees

• Dow Global Technologies Llc
• Rohm & Haas

Inventors

• Peera Asghar A
• Oberlin Anne
• Karikari Afua Sarpong

Classifications

• C11D17/0013

  Liquid compositions with insoluble particles in suspension (C11D17/0021, C11D17/0026, C11D17/003 take precedence) · CPC title

• C11D17/043

  Liquid or thixotropic (gel) compositions · CPC title

• C11D3/3765

  in liquid compositions · CPC title

• C11D3/0089 Primary

  Pearlescent compositions; Opacifying agents · CPC title